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Received September 1, 2020
Accepted February 23, 2021
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Enhancing the separation and antifouling properties of PES nanofiltration membrane by use of chitosan functionalized magnetic nanoparticles
Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran
s-hosseini@araku.ac.ir
Korean Journal of Chemical Engineering, May 2021, 38(5), 1014-1022(9), 10.1007/s11814-021-0765-9
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Abstract
Chitosan functionalized (CoFe2O4-CuO) composite nanoparticles were synthesized and then used in fabrication of PES-based nanofiltration membranes. X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy were used for the characterization of synthesized nanoparticles. The fabricated membranes were also characterized by scanning electron microscopy, 3D surface images, water contact angle, membrane porosity, pure water flux, salt rejection and fouling resistance consideration. Obtained results revealed that water contact angle was reduced significantly from 65° for the neat membrane to 36° for M5 with 1.0 wt% composite nanoparticles. All modified membranes also showed higher water flux and salt rejection than virgin PES membrane. The highest pure water flux measured 45.2 L/m2h and the highest salt rejection measured 88% for the modified membranes containing of composite nanoparticles. The modified membranes showed outstanding antifouling ability. The flux recovery ratio enhanced from 40% for pristine membrane to 93% for the modified ones with 0.5wt% of Cs-functionalized (CoFe2O4/CuO) composite nanoparticles.
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References
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Madaeni SS, Zinadini S, Vatanpour V, Sep. Purif. Technol., 111, 98 (2013)
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Arthanareeswaran G, Thanikaivelan P, Srinivasn K, Mohan D, Rajendran M, Eur. Polym. J., 40, 2153 (2004)
Kiamehr Z, Farokhi B, Hosseini SM, Korean J. Chem. Eng., 38, 1114 (2021)
Shi Q, Su YL, Zhu SP, Li C, Zhao YY, Jiang ZY, J. Membr. Sci., 303(1-2), 204 (2007)
Mo H, Tay KG, Ng HY, J. Membr. Sci., 315(1-2), 28 (2008)
Jonsson C, Jonsson AS, J. Membr. Sci., 108(1-2), 79 (1995)
Shon HK, Vigneswaran S, Kim IS, Cho J, Ngo HH, J. Membr. Sci., 234(1-2), 111 (2004)
Lin CJ, Shirazi S, Rao P, Agarwal S, Water Res., 40, 806 (2006)
Ma HM, Hakim LF, Bowman CN, Davis RH, J. Membr. Sci., 189(2), 255 (2001)
Rana D, Matsuura T, Chem. Rev., 110(4), 2448 (2010)
Committee MTR, Recent advances and research need in membrane fouling, in AWWA, 79 (2005).
Li JB, Zhu JW, Zheng MS, J. Appl. Polym. Sci., 103(6), 3623 (2007)
Li JF, Xu ZL, Yang H, Yu LY, Liu M, Appl. Surf. Sci., 255(9), 4725 (2009)
Kim J Van der Bruggen B, Environ. Pollut., 158, 2335 (2010)
Ansari S, Moghadassi A, Hosseini SM, Korean J. Chem. Eng., 37(11), 2011 (2020)
Bandehali S, Parvizian F, Moghadassi AR, Hosseini SM, Nanomaterials for the detection and removal of wastewater pollutants, Elsevier, Amsterdam, Netherlands (2020).
Bandehali S, Moghadassi A, Parvizian F, Shen J, Hosseini SM, Korean J. Chem. Eng., 37(2), 263 (2020)
Bandehali S, Parvizian F, Moghadassi A, Shen J, Hosseini SM, Korean J. Chem. Eng., 37(9), 1552 (2020)
Rahimpour A, Madaeni SS, Taheri AH, Mansourpanah Y, J. Membr. Sci., 313(1-2), 158 (2008)
Hosseini SM, Karami F, Farahani SK, Bandehali S, Shen J, Bagheripour E, Seidypoor A, Korean J. Chem. Eng., 37(5), 866 (2020)
Taurozzi JS, Arul H, Bosak VZ, Burban AF, Voice TC, Bruening ML, Tarabara VV, J. Membr. Sci., 325(1), 58 (2008)
Zangeneh H, Zinatizadeh AA, Zinadini S, Feyzi M, Bahnemann DW, Sep. Purif. Technol., 209, 764 (2019)
Zhang G, Qu J, Liu H, Cooper AT, Wu R, Chemosphere, 68, 1058 (2007)
Shao LN, Ren ZM, Zhang GS, Chen LL, Mater. Chem. Phys., 135(1), 16 (2012)
Salehi E, Daraei P, Shamsabadi AA, Carbohydr. Polym., 152, 419 (2016)
Kumar MNR, React. Funct. Polym., 46, 1 (2000)
Rinaudo M, Prog. Polym. Sci, 31, 603 (2006)
Fu F, Wang Q, J. Environ. Manage., 92, 407 (2011)
Krajewska B, Sep. Purif. Technol., 41(3), 305 (2005)
Ngah WW, Teong L, Hanafiah M, Carbohydr. Polym., 83, 1446 (2011)
Daraei P, Madaeni SS, Ghaemi N, Khadivi MA, Astinchap B, Moradian R, J. Membr. Sci., 444, 184 (2013)
Wang Z, Wang Z, Lin S, Jin H, Gao S, Zhu Y, Jin J, Nat. Commun., 9, 2004 (2018)
Bagheripour E, Moghadassi AR, Hosseini SM, Van der Bruggen B, Parvizian F, J. Ind. Eng. Chem., 62, 311 (2018)
Bagheripour E, Moghadassi AR, Hosseini SM, Ray MB, Parvizian F, Van der Bruggen B, Chem. Eng. Res. Des., 132, 812 (2018)
Eckertova L, Physics of thin films, 2nd Ed., Plenum Press, Berlin, Springer (1986).
Vatanpour V, Madaeni SS, Moradian R, Zinadini S, Astinchap B, Sep. Purif. Technol., 90, 69 (2012)
Hosseini SM, Afshari M, Fazlali AR, Farahani SK, Bandehali S, Van der Bruggen B, Bagheripour E, Chem. Eng. Res. Des., 147, 390 (2019)
Bandehali S, Parvizian F, Moghadassi AR, Hosseini SM, J. Polym. Res., 26, 211 (2019)
Bandehali S, Moghadassi A, Parvizian F, Hosseini S, Korean J. Chem. Eng., 36(10), 1657 (2019)
Zareei F, Hosseini SM, Sep. Purif. Technol., 226, 48 (2019)
Ebrahimi M, Van der Bruggen B, Hosseini SM, Askari M, Nemati M, IONICS, 25, 1199 (2019)
Vatanpour V, Madaeni SS, Rajabi L, Zinadini S, Derakhshan AA, J. Membr. Sci., 401, 132 (2012)
Ghaemi N, Madaeni SS, Alizadeh A, Daraei P, Badieh MMS, Falsafi M, Vatanpour V, Sep. Purif. Technol., 96, 214 (2012)
Yin J, Zhu GC, Deng BL, Desalination, 379, 93 (2016)
Xia SJ, Yao LJ, Zhao Y, Li NN, Zheng Y, Chem. Eng. J., 280, 720 (2015)
Daraei P, Madaeni SS, Ghaemi N, Salehi E, Khadivi MA, Moradian R, Astinchap B, J. Membr. Sci., 415, 250 (2012)
Madaeni SS, Zinadini S, Vatanpour V, Sep. Purif. Technol., 111, 98 (2013)
Zhao C, Xu X, Chen J, Yang F, J. Environ. Chem. Eng., 1, 349 (2013)
Yu HJ, Cao YM, Kang GD, Liu JH, Li M, Yuan Q, J. Membr. Sci., 342(1-2), 6 (2009)
