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Received November 15, 2020
Accepted February 8, 2021
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Fabrication of hydrophobic ZIFs based composite membrane with high CO2 absorption performance
Beijing Key Laboratory of Membrane Science and Technology, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
dingzw@mail.buct.edu.cn
Korean Journal of Chemical Engineering, May 2021, 38(5), 1032-1042(11), 10.1007/s11814-021-0762-z
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Abstract
The membrane contactor has been considered an effective device to capture CO2, but its performance is limited by membrane wetting phenomena. In this work, the ZIF-8/ZIF-L (zeolitic imidazolate framework) based composite membrane with excellent hydrophobic stability and CO2 permeability was successfully fabricated by coating the dense layer on the porous PVDF (polyvinylidene fluoride) substrate. The dense layer was developed by evenly incorporating ZIF-8 nanocrystals and ZIF-L nanosheets into the polydimethylsiloxane (PDMS) polymer. The as-prepared membrane possessed competitive hydrophobicity with a water contact angle (WCA) of 131.8o. And after a ten-day immersion test in CO2 absorbent, the WCA only declined by 9.8%, exhibiting excellent hydrophobic stability. Besides, the CO2 permeability of the composite membrane was 61.8 X10-8ㆍmolㆍm-2ㆍs-1ㆍPa-1 with an ideal CO2/N2 separation factor of ~20, which was effectively improved in comparison with the control membrane. In the CO2 absorption experiment, the prepared membrane achieved the competitive CO2 flux of 3.02X10-3ㆍmolㆍm-2ㆍs-1 when the liquid velocity was 0.25mㆍs-1 and displayed robust long-term operating stability. Finally, the AC impedance technique was applied to continuously monitor the wetting state of composite membranes, which further investigated their anti-wetting ability.
Keywords
References
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Xu YL, Lin YQ, Lee M, Malde C, Wang R, J. Membr. Sci., 552, 253 (2018)
Hashemifard SA, Ismail AF, Matsuura T, DashtArzhandi MR, RSC Adv., 5, 48442 (2015)
Mansourizadeh A, Mousavian S, J. Polym. Res., 20, 99 (2013)
Qi Z, Cussler EL, J. Membr. Sci., 23, 321 (1985)
Nii S, Takeuchi H, Takahashi K, J. Chem. Eng. Jpn., 25, 67 (1992)
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Demontigny D, Tontiwachwuthikul P, Chakma A, J. Membr. Sci., 277(1-2), 99 (2006)
Sedghi SM, Brisson J, Rodrigue D, Iliuta MC, Sep. Purif. Technol., 80(2), 338 (2011)
Keshavarz R, Fathikalajahi J, Ayatollahi S, J. Hazard. Mater., 152(3), 1237 (2008)
Khaisri S, Demontigny D, Tontiwachwuthikul P, Jiraratananon R, Sep. Purif. Technol., 65(3), 290 (2009)
Rajabzadeh S, Yoshimoto S, Teramoto M, Al-Marzouqi M, Matsuyama H, Sep. Purif. Technol., 68, 210 (2009)
Zhang HY, Wang R, Liang DT, Tay JH, J. Membr. Sci., 308(1-2), 162 (2008)
Mosadegh-Sedghi S, Rodrigue D, Brisson J, Iliuta MC, J. Membr. Sci., 452, 332 (2014)
Dai ZD, Ansaloni L, Deng LY, Ind. Eng. Chem. Res., 55(20), 5983 (2016)
Scholes CA, Kentish SE, Stevens GW, deMontigny D, Int. J. Greenh. Gas Control., 42, 66 (2015)
Li K, Zeng X, Li H, Lai X, Ye C, Xie H, Appl. Surf. Sci., 279, 458 (2013)
Rosli A, Ahmad AL, Low SC, Sep. Purif. Technol., 221, 275 (2019)
Yao J, Wang H, Chem. Soc. Rev., 43, 4470 (2014)
Song Q, Nataraj SK, Roussenova MV, Tan JC, Hughes DJ, et al., Energy Environ. Sci., 5, 8359 (2012)
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Mao H, Zhen HG, Ahmad A, Li SH, Liang Y, Ding JF, Wu Y, Li LZ, Zhao ZP, J. Membr. Sci., 582, 307 (2019)
Li H, Han L, Hou JW, Liu JD, Zhang YT, J. Membr. Sci., 572, 82 (2019)
Bannwarth S, Darestani M, Coster H, Wessling M, J. Membr. Sci., 473, 318 (2015)
Xiao J, Sun Q, Liu L, Ding Z, Chin. J. Chem. Eng., In press (2020).
Cravillon J, Munzer S, Lohmeier SJ, Feldhoff A, Huber K, Wiebcke M, Chem. Mater., 21, 1410 (2009)
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Khan IU, Othman MHD, Ismail AF, Ismail N, Jaafar J, Hashim H, Rahman MA, Jilani A, Mater. Charact., 136, 407 (2018)
Low ZX, Yao J, Liu Q, He M, Wang Z, Suresh AK, Bellare J, Wang H, Cryst. Growth Des., 14, 6589 (2014)
Liu GH, Jiang ZY, Cao KT, Nair S, Cheng XX, Zhao J, Gomaa H, Wu H, Pan FS, J. Membr. Sci., 523, 185 (2017)
Wu XN, Zhao B, Wang L, Zhang ZH, Zhang HW, Zhao XH, Guo XF, J. Membr. Sci., 520, 120 (2016)
Pan Y, Hang YT, Zhao XH, Liu GP, Jin WQ, J. Membr. Sci., 579, 210 (2019)
Li H, Chen YM, Ma XT, Shi JL, Zhu BK, Zhu LP, J. Membr. Sci., 379(1-2), 397 (2011)
Rezakazemi M, Vatani A, Mohammadi T, RSC Adv., 5, 82460 (2015)
Low ZX, Razmjou A, Wang K, Gray S, Duke M, Wang HT, J. Membr. Sci., 460, 9 (2014)
Vatanpour V, Madaeni SS, Khataee AR, Salehi E, Zinadini S, Monfared HA, Desalination, 292, 19 (2012)
Zhang XP, He XZ, Gundersen T, Energy Fuels, 27(8), 4137 (2013)
Banerjee R, Furukawa H, Britt D, Knobler C, O'Keeffe M, Yaghi OM, J. Am. Chem. Soc., 131(11), 3875 (2009)
Hu Y, Liu ZX, Xu J, Huang YN, Song Y, J. Am. Chem. Soc., 135(25), 9287 (2013)
Qiang W, Hu DD, Liu T, Zhao L, J. Supercrit. Fluids, 147, 329 (2019)
Barillas MK, Enick RM, O'Brien M, Perry R, Luebke DR, Morreale BD, J. Membr. Sci., 372(1-2), 29 (2011)
Lin YQ, Xu YL, Loh CH, Wang R, Appl. Surf. Sci., 436, 670 (2018)
Zhang HY, Wang R, Liang DT, Tay JH, J. Membr. Sci., 279(1-2), 301 (2006)
Li JL, Chen BH, Sep. Purif. Technol., 41(2), 109 (2005)
Xu YL, Lin YQ, Lee M, Malde C, Wang R, J. Membr. Sci., 552, 253 (2018)
Hashemifard SA, Ismail AF, Matsuura T, DashtArzhandi MR, RSC Adv., 5, 48442 (2015)
Mansourizadeh A, Mousavian S, J. Polym. Res., 20, 99 (2013)
