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Received November 14, 2020
Accepted January 26, 2021
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Cascade conversion of glucose to 5-hydroxymethylfurfuralover Bronsted-Lewis bi-acidic SnAl-beta zeolites
Department of Energy and Chemical Engineering, Incheon National University, Incheon 22012, Korea 1Department of Chemical Engineering, Chungbuk National University, Cheongju, Chungbuk 28644, Korea 2LOTTE Chemical Research Institute, Daejeon 34110, Korea
mbpark@inu.ac.kr
Korean Journal of Chemical Engineering, June 2021, 38(6), 1161-1169(9), 10.1007/s11814-021-0752-1
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Abstract
The control of acidic properties in a catalyst is one of the key features of technology utilizing biomass for chemical production. In this study, the Bronsted and Lewis bi-acidic SnAl-beta zeolites with controllable acidity were successfully prepared by acid dealumination and isomorphic substitution of Al by Sn, and applied for the cascade conversion of glucose to 5-hydroxymethylfurfural (5-HMF). The Lewis acidity of the catalysts was increased as the higher concentration of nitric acid used for the dealumination process. The optimum portion of Lewis/(Bronsted+Lewis) ratio was investigated to maximize the yield of 5-HMF, which is converted from the glucose via fructose by the cascade reaction. The conversion of glucose was increased until the L/(B+L) ratio reached 0.89 and the selectivity to 5-HMF reached its maximum at the Lewis acid portion of 0.76 among the total acid sites.
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References
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Kumar S, Nepak D, Kansal SK, Elumalai S, RSC Adv., 8, 30106 (2018)
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