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Received November 16, 2020
Accepted February 8, 2021
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Reactivity of sulfur compounds in FCC decant oils for hydrodesulfurization over CoMoS2/Al2O3 catalysts
Laboratory of Advanced Catalysis for Energy and Environment, Department of Chemical Engineering, Dankook University, 152 Jukjeonro, Yongin 16890, Korea
Korean Journal of Chemical Engineering, June 2021, 38(6), 1179-1187(9), 10.1007/s11814-021-0763-y
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Abstract
CoMoS2/Al2O3 catalysts prepared by adding citric acid (CA) were synthesized and applied tor hydrodesulfurization (HDS) of fluid-catalytic cracking decant-oils (FCC-DO). The HDS of FCC-DO was carried out in an autoclave batch reactor at 653 K and 9.4MPa H2. The structural properties of the catalysts were characterized by N2 physisorption, X-ray absorption fine structure spectroscopy (XAFS), and transmission electron microscopy (TEM). The S compounds in FCC-DO have been classified into three groups in terms of the reactivity of HDS. The Co K-edge XANES analysis confirmed the formation of the Co-Mo-S phase with the addition of CA, contributing to better activity in the HDS of FCC-DO.
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References
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Gonzalez-Cortes SL, Qian Y, Almegren HA, Xiao T, Kuznetsov VL, Edwards PP, Appl. Petrochem. Res., 5, 181 (2015)
Budukva SV, Klimov OV, Uvarkina DD, Chesalov YA, Prosvirin IP, Larina TV, Noskov AS, Catal. Today, 329, 35 (2019)
Pashigreva AV, Bukhtiyarova GA, Klimov OV, Chesalov YA, Litvak GS, Noskov AS, Catal. Today, 149(1-2), 19 (2010)
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Valencia D, Garcia-Cruz I, Klimova T, Stud. Surf. Sci. Catal., 175, 529 (2010)
Filley RM, Eser S, Energy Fuels, 11(3), 623 (1997)
Eser S, Wang GH, Energy Fuels, 21(6), 3573 (2007)
Ma XL, Sakanishi K, Mochida I, Ind. Eng. Chem. Res., 35(8), 2487 (1996)
Okamoto Y, Hioka K, Arakawa K, Fujikawa T, Ebihara T, Kubota T, J. Catal., 268(1), 49 (2009)
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Van Haandel L, Smolentsev G, Van Bokhoven JA, Hensen EJM, Weber T, ACS Catal., 10, 10978 (2020)
Lauritsen JV, Bollinger MV, Laegsgaard E, Jacobsen KW, Norskov JK, Clausen BS, Topsoe H, Besenbacher F, J. Catal., 221(2), 510 (2004)
