Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received November 30, 2020
Accepted February 23, 2021
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Selective hydrogen combustion over Rh-Sn/Al2O3 catalysts during propane dehydrogenation
Department of Chemical Engineering, RCCT, Hankyong National University, Anseong 17579, Korea 1Chemical and Environmental Technology Department, Inha Technical College, Inha-ro 100, Michuhol-gu, Incheon 22212, Korea 2Clean Energy Research Center, Korean Institute of Science and Technology, P. O. Box 131, Cheongryang, Seoul 02792, Korea 3R&D Business Lab., Hyosung Co., 74 Simin-daero, Dongan-gu, Anyang, Gyeounggi 14080, Korea
jkdcat@kist.re.kr
Korean Journal of Chemical Engineering, June 2021, 38(6), 1197-1204(8), 10.1007/s11814-021-0769-5
Download PDF
Abstract
A series of Rh-Sn/Al2O3 catalysts were prepared by 0.5 wt% of Rh and varied amounts of Sn from 0 to 3.0 wt%. Rh-Sn catalysts were evaluated to determine if selective hydrogen combustion(SHC) can be effectively applicable to propane dehydrogenation (PDH). PDH is an endothermic reaction and SHC can generate partial heat energy. In this study, two separate SHC reactions were examined. One was to look into the quantification of competitive combustion states over Rh-Sn catalysts in the presence of hydrogen, propylene, oxygen, and nitrogen. The other was to evaluate SHC with Rh-Sn catalysts in the presence of hydrogen, propane, oxygen, and nitrogen. The factor that we entitled A factor, was employed to analyze the effect of Sn amount. The result showed that the best performance was achieved by 0.5Rh-1.5Sn/Al2O3 catalyst for both SHC reactions. Characteristics of catalysts were analyzed by CO chemisorption, XPS, TEM-EDX and TPR.
Keywords
References
Kung HH, Adv. Catal., 40, 1 (1994)
Bhasin MM, McCain JH, Vora BV, Imai T, Pujado PR, Appl. Catal. A: Gen., 221(1-2), 397 (2001)
Madeira LM, Portela MF, Catal. Rev.-Sci. Eng., 44(2), 247 (2002)
Bocanegra S, Ballarini A, Zgolicz P, Scelza O, de Miguel S, Catal. Today, 143, 334 (2009)
Sahebdelfar S, Ravanchi MT, Zangeneh FT, Mehrazma S, Rajabi S, Chem. Eng. Res. Des., 90(8), 1090 (2012)
Vora BV, Top. Catal., 55, 1297 (2012)
Lin CH, Lee KC, Wan BZ, Appl. Catal. A: Gen., 164(1-2), 59 (1997)
Late L, Rundereim JI, Blekkan EA, Appl. Catal. A: Gen., 262(1), 53 (2004)
Czuprat O, Caro J, Kondratenko VA, Kondratenko EV, Catal. Commun., 11, 1211 (2010)
Creaser D, Andersson B, Hudgins RR, Silveston PL, Appl. Catal. A: Gen., 187(1), 147 (1999)
Liu RD, Zhu Y, Sui ZJ, Wang H, Li P, Zhou XG, Fuel Process. Technol., 108, 82 (2013)
Late L, Thelin W, Blekkan EA, Appl. Catal. A: Gen., 262(1), 63 (2004)
Grasselli RK, Stern DL, Tsikoyiannis JG, Appl. Catal. A: Gen., 189(1), 1 (1999)
Shelepova EJ, Vedyagin AA, Mishakov IV, Noskov AS, Chem. Eng. J., 176-177, 151 (2011)
Lee H, Kim WI, Jung KD, Koh HL, Korean J. Chem. Eng., 34(5), 1337 (2017)
Hu R, Li X, Sui Z, Ye G, Zhou X, Chem. Eng. Process. - Process Intensif., 143, 107608 (2019).
Grasselli RK, Stern DL, Tsikoyiannis JG, Appl. Catal. A: Gen., 189(1), 1 (1999)
Tsikoyiannis JG, Stern DL, Grasselli RK, J. Catal., 184(1), 77 (1999)
Dyrbeck H, Hammer N, Rønning M, Blekkan EA, Top. Catal., 45, 21 (2007)
O’Hara MJ, Imai T, Bricker JC, Mackowiak DE, US Patent, 4,565,898 (1986).
Kaneko S, Arakawa T, Ohshima M, Kurokawa H, Miura H, Appl. Catal. A: Gen., 356(1), 80 (2009)
Blank JH, Beckers J, Collignon PF, Clerc F, Rothenberg G, Chem. - A Eur. J., 13, 5121 (2007)
Liu SQ, Gong S, Feng H, Ma ZJ, Yang L, Li P, Int. J. Hydrog. Energy, 45(22), 12347 (2020)
Montemore MM, van Spronsen MA, Madix RJ, Friend CM, Chem. Rev., 118(5), 2816 (2018)
Kim GH, Jung KD, Kim WI, Um BH, Shin CH, Oh K, Koh HL, Res. Chem. Intermed., 42, 351 (2016)
Choi YS, Oh K, Jung KD, Kim WI, Koh HL, Catalysts, 10, 898 (2020)
Barias OA, Holmen A, Blekkan EA, J. Catal., 158(1), 1 (1996)
Kim MJ, Kim YJ, Lee SJ, Ryu IS, Kim HJ, Kim Y, Ko CH, Jeon SG, Chem. Eng. Re. Des., 141, 455 (2019)
Charisiou ND, Italiano C, Pino L, Sebastian V, Vita A, Goula MA, Renew. Energy, 162, 908 (2020)
Bhasin MM, McCain JH, Vora BV, Imai T, Pujado PR, Appl. Catal. A: Gen., 221(1-2), 397 (2001)
Madeira LM, Portela MF, Catal. Rev.-Sci. Eng., 44(2), 247 (2002)
Bocanegra S, Ballarini A, Zgolicz P, Scelza O, de Miguel S, Catal. Today, 143, 334 (2009)
Sahebdelfar S, Ravanchi MT, Zangeneh FT, Mehrazma S, Rajabi S, Chem. Eng. Res. Des., 90(8), 1090 (2012)
Vora BV, Top. Catal., 55, 1297 (2012)
Lin CH, Lee KC, Wan BZ, Appl. Catal. A: Gen., 164(1-2), 59 (1997)
Late L, Rundereim JI, Blekkan EA, Appl. Catal. A: Gen., 262(1), 53 (2004)
Czuprat O, Caro J, Kondratenko VA, Kondratenko EV, Catal. Commun., 11, 1211 (2010)
Creaser D, Andersson B, Hudgins RR, Silveston PL, Appl. Catal. A: Gen., 187(1), 147 (1999)
Liu RD, Zhu Y, Sui ZJ, Wang H, Li P, Zhou XG, Fuel Process. Technol., 108, 82 (2013)
Late L, Thelin W, Blekkan EA, Appl. Catal. A: Gen., 262(1), 63 (2004)
Grasselli RK, Stern DL, Tsikoyiannis JG, Appl. Catal. A: Gen., 189(1), 1 (1999)
Shelepova EJ, Vedyagin AA, Mishakov IV, Noskov AS, Chem. Eng. J., 176-177, 151 (2011)
Lee H, Kim WI, Jung KD, Koh HL, Korean J. Chem. Eng., 34(5), 1337 (2017)
Hu R, Li X, Sui Z, Ye G, Zhou X, Chem. Eng. Process. - Process Intensif., 143, 107608 (2019).
Grasselli RK, Stern DL, Tsikoyiannis JG, Appl. Catal. A: Gen., 189(1), 1 (1999)
Tsikoyiannis JG, Stern DL, Grasselli RK, J. Catal., 184(1), 77 (1999)
Dyrbeck H, Hammer N, Rønning M, Blekkan EA, Top. Catal., 45, 21 (2007)
O’Hara MJ, Imai T, Bricker JC, Mackowiak DE, US Patent, 4,565,898 (1986).
Kaneko S, Arakawa T, Ohshima M, Kurokawa H, Miura H, Appl. Catal. A: Gen., 356(1), 80 (2009)
Blank JH, Beckers J, Collignon PF, Clerc F, Rothenberg G, Chem. - A Eur. J., 13, 5121 (2007)
Liu SQ, Gong S, Feng H, Ma ZJ, Yang L, Li P, Int. J. Hydrog. Energy, 45(22), 12347 (2020)
Montemore MM, van Spronsen MA, Madix RJ, Friend CM, Chem. Rev., 118(5), 2816 (2018)
Kim GH, Jung KD, Kim WI, Um BH, Shin CH, Oh K, Koh HL, Res. Chem. Intermed., 42, 351 (2016)
Choi YS, Oh K, Jung KD, Kim WI, Koh HL, Catalysts, 10, 898 (2020)
Barias OA, Holmen A, Blekkan EA, J. Catal., 158(1), 1 (1996)
Kim MJ, Kim YJ, Lee SJ, Ryu IS, Kim HJ, Kim Y, Ko CH, Jeon SG, Chem. Eng. Re. Des., 141, 455 (2019)
Charisiou ND, Italiano C, Pino L, Sebastian V, Vita A, Goula MA, Renew. Energy, 162, 908 (2020)
