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Received February 4, 2021
Accepted April 11, 2021
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Contributions of post-synthesized mesopore structures of ferrierite zeolite for gas-phase dimethyl ether carbonylation activity
School of Chemical Engineering, Sungkyunkwan University (SKKU), 2066 Seobu-ro, Suwon, Gyeonggi-do 16419, Korea
Korean Journal of Chemical Engineering, June 2021, 38(6), 1231-1239(9), 10.1007/s11814-021-0806-4
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Abstract
Mesoporous ferrierite zeolite (FER) synthesized by a post-desilication method was applied for a gas-phase dimethyl ether (DME) carbonylation to confirm the contributions of the newly formed mesoporous structures above 10 nm in size. The distribution of surface acidic sites and extent of coke deposition was significantly altered, resulting in showing different catalytic activity and stability, which were mainly caused by the post-synthesized larger mesopores on the FER. The newly formed mesoporous structures in the range of 5-40 nm on the pristine seed-derived FER (SFER) with a Si/Al molar ratio of 10.4 were largely changed by a desilication/recrystallization duration, and the mesopores significantly increased the surface acidic sites with similar extent of crystallinity even with a lower Si/Al ratio of 6.7-8.6. The increased strong acidic sites corresponding to Brønsted acid sites after an optimal desilication duration for ~3 h on the mesoporous SFER (m-SFER(3)) were mainly responsible for an increased DME carbonylation activity with smaller formation of coke precursors due to facile mass transport phenomena through its lager mesopores.
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References
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Sarv P, Wichterlova B, Cejka J, J. Phys. Chem. B, 102(8), 1372 (1998)
Kim JH, Ham H, Jung HS, Wang Y, He Y, Tsubaki N, Cho SJ, Han GY, Bae JW, Catal. Sci. Technol., 8, 3060 (2018)
Li B, Xu J, Han B, Wang X, Qi G, Zhan Z, Wang C, Deng F, J. Phys. Chem. C, 117, 5840 (2013)
Bhan A, Allian AD, Sunley GJ, Law DJ, Iglesia E, J. Am. Chem. Soc., 129(16), 4919 (2007)
Cheung P, Bhan A, Sunley GJ, Iglesia E, Angew. Chem.-Int. Edit., 45, 1617 (2006)
Li J, Qiu J, Sun Y, Long Y, Microporous Mesoporous Mater., 37, 365 (2000)
Cheng X, Cacciaguerra T, Minoux D, Dath JP, Fajula F, Gerardin C, Microporous Mesoporous Mater., 2260, 132 (2018)
Groen JC, Brouwer S, Peffer LAA, Perez-Ramirez J, Part. Part. Syst. Charact., 23, 101 (2006)
Li X, Wu D, Korean J. Chem. Eng., 37(2), 216 (2020)
van Donk S, Janssen AH, Bitter JH, de Jong KP, Catal. Rev.-Sci. Eng., 45(2), 297 (2003)
Serrano DP, Escola JM, Pizarro P, Chem. Soc. Rev., 42, 4004 (2013)
Li K, Valla J, Garcia-Martinez J, ChemCatChem, 6, 46 (2014)
Ogura M, Shinomiya SY, Tateno J, Nara Y, Kikuchi E, Matsukata H, Chem. Lett., 29(8), 882 (2000)
Jeong MH, Park KS, Shen DM, Moon JW, Bae JW, Korean J. Chem. Eng., DOI:10.1007/s11814-020-0709-9.
Groen JC, Jansen JC, Moulijn JA, Perez-Ramirez J, J. Phys. Chem. B, 108(35), 13062 (2004)
Groen JC, Sano T, Moulijn JA, Perez-Ramirez J, J. Catal., 251(1), 21 (2007)
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Bonilla A, Baudouin D, Perez-Ramirez J, J. Catal., 265(2), 170 (2009)
Moller K, Bein T, Chem. Soc. Rev., 42, 3689 (2013)
Verboekend D, Mitchell S, Milina M, Groen JC, Perez-Ramirez J, J. Phys. Chem. C, 115, 14193 (2011)
Cheng XW, Long YC, Adv. Porous Mater., 1, 136 (2013)
Khitev YP, Kolyagin YG, Ivanova II, Ponomareva OA, Thibault-Starzyk F, Gilson JP, Fernandez C, Fajula F, Microporous Mesoporous Mater., 146, 201 (2011)
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Chal R, Cacciaguerra T, van Donk S, Gerardin C, Chem. Commun., 46, 7840 (2010)
Chal R, Gerardin C, Bulut M, van Donk S, ChemCatChem, 3, 67 (2011)
Garcia-Martinez J, Johnson M, Valla J, Li K, Ying JY, Catal. Sci. Technol., 2, 987 (2012)
Manko M, Chal R, Trens P, Minoux D, Gerardin C, Makowski W, Microporous Mesoporous Mater., 170, 243 (2013)
Bertrand-Drira C, Cheng XW, Cacciaguerra T, Trens P, Melinte G, Ersen O, Minoux D, Finiels Z, Fajula F, Gerardin C, Microporous Mesoporous Mater., 213, 142 (2015)
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Gott T, Oyama ST, J. Catal., 263(2), 359 (2009)
Rasmussen DB, Christensen JM, Temel B, Studt F, Moses PG, Rossmeisl J, Riisager A, Jensen AD, Angew. Chem.-Int. Edit., 54, 1 (2015)
Pieterse JAZ, Veefkind-Reyes S, Seshan K, Domokos L, Lercher JA, J. Catal., 187(2), 518 (1999)
Saravanan K, Park KS, Jeon S, Bae JW, ACS Omega, 3, 808 (2018)
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Li H, Fang Z, Luo J, Yang S, Appl. Catal. B: Environ., 200, 182 (2017)
Auroux A, Top. Catal., 19(3-4), 205 (2002)
Jung HS, Xuan NT, Bae JW, Microporous Mesoporous Mater., 310, 110669 (2021)
Reule AAC, Semagina N, ACS Catal., 6, 4972 (2016)
Xu J, Zhou W, Wang J, Li Z, Ma J, Chin. J. Catal., 30, 1076 (2009)
Goodarzia F, Herrerob IP, Kalantzopoulosb GN, Svelleb S, Lazzarinib A, Beatoc P, Olsbyeb U, Kegnæs S, Microporous Mesoporous Mater., 292, 109730 (2020)
Morales MV, Gora-Marek K, Musch H, Pineda A, Murray B, Stefanidis S, Falco L, Tarach K, Ponomareva E, Marsman JH, Melian-Cabrera I, Appl. Catal. A: Gen., 562, 215 (2018)
