Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received December 15, 2020
Accepted March 28, 2021
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Template-assisted preparation of metal-modified SAPO-34 molecular sieves for the catalysis of methanol-to-olefins
Jihui Yao1
Jiapeng Jiao1
Ruiqiang Liu*1
Fei Zha1†
Xiaojun Guo1
Xiaohua Tang1
Haifeng Tian1
Yue Chang1 2
1College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, Gansu, China 2Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education, Lanzhou 730070, Gansu, China
zhafei@nwnu.edu.cn
Korean Journal of Chemical Engineering, July 2021, 38(7), 1381-1393(13), 10.1007/s11814-021-0793-5
Download PDF
Abstract
To improve the dispersion of metals and to enhance the catalytic performance of SAPO-34 molecular sieves, the template-assisted method was applied to synthesize Co, Ni and Zn modified SAPO-34 molecular sieves by using palygorskite as silicon source and tetraethylammonium hydroxide as template. The metal modified SAPO-34 molecular sieves were characterized by XRD, SEM, XPS, N2-adsorption-desorption, NH3-TPD, FTIR, ICP-AES and TG. The N atoms of tetraethylammonium hydroxide exhibited the different forces to three metal ions, thus the acidity of the molecular sieves was further regulated. Compared with metal modified SAPO-34 molecular sieves prepared by impregnation, metal modified SAPO-34 molecular sieves prepared by template-assisted maintained higher surface area, bigger pore volume and better dispersion of metals. The catalytic performance of metal modified SAPO-34 molecular sieves prepared by template-assisted method in the reaction of methanol-to-olefins (MTO) was investigated in the fixed bed reactor. Under the reaction conditions that the reaction temperature was 400 °C, the reaction pressure was 0.1 MPa, the feed WHSV was 2.0 h-1 and the mass of catalyst was 0.5 g, Ni modified SAPO-34 molecular sieves exhibited great methanol conversion and high selectivity to light olefins. The selectivity of light olefins reached 95.7%.
Keywords
References
Dai WL, Wang X, Wu GJ, Guan NJ, Hunger M, Li LD, ACS Catal., 1, 292 (2011)
Hu XQ, Yuan L, Cheng SM, Luo JL, Sun HP, Li SP, Li L, Wang C, Catal. Commun., 123, 38 (2019)
Lee SU, Lee YJ, Kim JR, Jeong KE, Jeong SY, J. Ind. Eng. Chem., 79, 443 (2019)
Huang HW, Wang HR, Zhu H, Zhang SH, Zhang Q, Li CY, Catal. Sci. Technol., 9, 2203 (2019)
Yang M, Fan D, Wei YX, Tian P, Liu ZM, Adv. Mater., 31, 190218 (2019)
Xi DY, Sun QM, Chen XX, Wang N, Yu JH, Chem. Commun., 51, 11987 (2015)
Zheng JW, Ding JJ, Jin DL, Ye GH, Zhu KK, Zhou XG, Yang WM, Yuan WK, Chem. Commun, 53, 6132 (2017)
Zhong JW, Han JF, Wei YX, Xu ST, Sun TT, Guo XW, Song CS, Liu ZM, Chin. J. Catal., 39, 1821 (2018)
Sun QM, Xie ZK, Yu JH, Natl. Sci. Rev., 5, 542 (2018)
Zhong JW, Han JF, Wei YX, Tian P, Guo XW, Song CS, Liu ZM, Catal. Sci. Technol., 7, 4905 (2017)
Chen D, Moljord K, Holmen A, Microporous Mesoporous Mater., 164, 239 (2012)
Dai WL, Wu GJ, Li LD, Guan NJ, Hunger M, ACS Catal., 3, 588 (2013)
Nishiyama N, Kawaguchi M, Hirota Y, Van Vu D, Egashira Y, Ueyama K, Appl. Catal. A: Gen., 362(1-2), 193 (2009)
Wang C, Yang M, Tian P, Xu ST, Yang Y, Wang DH, Yuan YY, Liu ZM, J. Mater. Chem., 3, 5608 (2015)
Sun QM, Wang NG, Guo QX, Chen X, Yu JH, J. Mater. Chem., 3, 19783 (2015)
Aghaei E, Haghighi M, Pazhohniya Z, Aghamohammadi S, Microporous Mesoporous Mater., 226, 331 (2016)
Xu L, Liu ZM, Du AP, Wei YX, Sun ZG, Stud. Surf. Sci. Catal., 147, 445 (2004)
Aghamohammadi S, Haghighi M, Charghand M, Mater. Res. Bull., 50, 462 (2014)
Chae HJ, Park SS, Shin YH, Park MB, Microporous Mesoporous Mater., 259, 60 (2018)
Liu YW, Li Z, Yu QY, Chen YF, Chai ZW, Zhao GF, et al., J. Am. Chem. Soc., 141, 9305 (2019)
Turrina A, Eschenroeder ECV, Bode BE, Collier JE, Apperley DC, Cox PA, Casci JL, Wright PC, Microporous Mesoporous Mater., 215, 154 (2015)
Zhong JW, Han JF, Wei YX, Xu ST, Sun TT, Guo XW, Song CS, Liu ZM, J. Energy Chem., 32, 174 (2019)
Xiang X, Yang M, Gao BB, Qiao YY, Tian P, Xu ST, Liu ZM, RSC Adv., 12544, 6 (2016)
Liu ZM, Yang LX, Xu L, Sun CL, Xiong YJ, US Patent, 6,448,191 (2012).
Tian HF, Yao JH, Zha F, Yao L, Chang Y, Appl. Clay Sci., 184, 105392 (2020)
Dai WL, Wang CM, Dyballa M, Wu GJ, Guan NJ, Li LD, Xie ZK, Hunger M, ACS Catal., 5, 317 (2015)
Wang X, Chen WX, Zhang L, Yao T, Liu W, Lin Y, Ju HX, Dong JC, Zheng LR, Yan WS, Zheng XS, Li ZJ, Wang XQ, Yang J, He DS, Wang Y, Deng ZX, Wu YE, Li YD, J. Am. Chem. Soc., 139(28), 9419 (2017)
Shi W, Zhang BS, Lin YM, Wang Q, Zhang Q, Su DS, ACS Catal., 6, 7844 (2016)
Kamarudin NHN, Jalil AA, Triwahyono S, Mukti RR, Ab Aziz MA, Setiabudi HD, Muhid MNM, Hamdan H, Appl. Catal. A: Gen., 431, 104 (2012)
Tamiyakul S, Ubolcharoen W, Tungasmita DN, Jongpatiwut S, Catal. Today, 256, 325 (2015)
Li XY, Yang JX, Xu R, Lu LF, Kong FG, Liang M, Jiang LJ, Nie SX, Si CL, Ind. Crop. Prod., 135, 196 (2019)
Yang H, Liu XH, Lu GZ, Wang YQ, Microporous Mesoporous Mater., 225, 144 (2015)
Singh AK, Yadav R, Sakthivel A, Microporous Mesoporous Mater., 181, 166 (2013)
Salmasi M, Fatemi S, Najafabadi AT, J. Ind. Eng. Chem., 17(4), 755 (2011)
Alvaro-Munoz T, Marquez-Alvarez C, Sastre E, Catal. Today, 179(1), 27 (2012)
Gao MB, Li H, Yang M, Zhou JB, Yuan XS, Tian P, Ye M, Liu ZM, Chem. Eng. J., 337, 119668 (2019)
Wang PF, Zha F, Yao L, Chang Y, Appl. Clay Sci., 163, 249 (2018)
Yang ST, Kim JY, Chae HJ, Kim M, Jeong SY, Ahn WS, Mater. Res. Bull., 47, 3888 (2012)
Salih HA, Muraza O, Abussaud B, Al-Shammari TK, Yokoi T, Ind. Eng. Chem. Res., 57(19), 6639 (2018)
Zhang DZ, Wei YX, Xu L, Chang FX, Liu ZY, Meng SH, Su BL, Liu ZM, Microporous Mesoporous Mater., 116, 684 (2008)
Firoozi M, Baghalha M, Asadi M, Catal. Commun., 10, 1582 (2009)
Othman I, Mohamed RM, Ibrahim IA, Mohamed MM, Appl. Catal. A: Gen., 299, 95 (2006)
Chen D, Moljord K, Holme A, Microporous Mesoporous Mater., 164, 239 (2012)
Din IU, Shaharun MS, Naeem A, Tasleem S, Johan MR, Chem. Eng. J., 334, 619 (2018)
Jing BQ, Li JF, Chemistry Select, 4, 7634 (2019)
Song WG, Haw JF, Nicholas JB, Heneghan CS, J. Am. Chem. Soc., 122(43), 10726 (2000)
Haw JF, Marcus DM, Top Catal., 34, 41 (2005)
Olsbye U, Svelle S, Bjorgen M, Beato P, Janssens TVW, Bordiga FS, Lillerud KP, Angew. Chem.-Int. Edit., 51, 5810 (2012)
Dai WL, Cao G, Yang L, Wu GJ, Dyballa M, Hunger M, Guan NJ, Li LD, Catal. Sci. Technol., 7, 607 (2017)
Nawaz Z, Tang XP, Zhu J, Wei F, Naveed S, Chin. J. Catal., 30, 1049 (2009)
Kim HJ, Kim JW, Kim N, Kim TW, Jhung SH, Kim CU, Mol. Catal., 438, 86 (2017)
Hu XQ, Yuan L, Cheng SM, Luo JL, Sun HP, Li SP, Li L, Wang C, Catal. Commun., 123, 38 (2019)
Lee SU, Lee YJ, Kim JR, Jeong KE, Jeong SY, J. Ind. Eng. Chem., 79, 443 (2019)
Huang HW, Wang HR, Zhu H, Zhang SH, Zhang Q, Li CY, Catal. Sci. Technol., 9, 2203 (2019)
Yang M, Fan D, Wei YX, Tian P, Liu ZM, Adv. Mater., 31, 190218 (2019)
Xi DY, Sun QM, Chen XX, Wang N, Yu JH, Chem. Commun., 51, 11987 (2015)
Zheng JW, Ding JJ, Jin DL, Ye GH, Zhu KK, Zhou XG, Yang WM, Yuan WK, Chem. Commun, 53, 6132 (2017)
Zhong JW, Han JF, Wei YX, Xu ST, Sun TT, Guo XW, Song CS, Liu ZM, Chin. J. Catal., 39, 1821 (2018)
Sun QM, Xie ZK, Yu JH, Natl. Sci. Rev., 5, 542 (2018)
Zhong JW, Han JF, Wei YX, Tian P, Guo XW, Song CS, Liu ZM, Catal. Sci. Technol., 7, 4905 (2017)
Chen D, Moljord K, Holmen A, Microporous Mesoporous Mater., 164, 239 (2012)
Dai WL, Wu GJ, Li LD, Guan NJ, Hunger M, ACS Catal., 3, 588 (2013)
Nishiyama N, Kawaguchi M, Hirota Y, Van Vu D, Egashira Y, Ueyama K, Appl. Catal. A: Gen., 362(1-2), 193 (2009)
Wang C, Yang M, Tian P, Xu ST, Yang Y, Wang DH, Yuan YY, Liu ZM, J. Mater. Chem., 3, 5608 (2015)
Sun QM, Wang NG, Guo QX, Chen X, Yu JH, J. Mater. Chem., 3, 19783 (2015)
Aghaei E, Haghighi M, Pazhohniya Z, Aghamohammadi S, Microporous Mesoporous Mater., 226, 331 (2016)
Xu L, Liu ZM, Du AP, Wei YX, Sun ZG, Stud. Surf. Sci. Catal., 147, 445 (2004)
Aghamohammadi S, Haghighi M, Charghand M, Mater. Res. Bull., 50, 462 (2014)
Chae HJ, Park SS, Shin YH, Park MB, Microporous Mesoporous Mater., 259, 60 (2018)
Liu YW, Li Z, Yu QY, Chen YF, Chai ZW, Zhao GF, et al., J. Am. Chem. Soc., 141, 9305 (2019)
Turrina A, Eschenroeder ECV, Bode BE, Collier JE, Apperley DC, Cox PA, Casci JL, Wright PC, Microporous Mesoporous Mater., 215, 154 (2015)
Zhong JW, Han JF, Wei YX, Xu ST, Sun TT, Guo XW, Song CS, Liu ZM, J. Energy Chem., 32, 174 (2019)
Xiang X, Yang M, Gao BB, Qiao YY, Tian P, Xu ST, Liu ZM, RSC Adv., 12544, 6 (2016)
Liu ZM, Yang LX, Xu L, Sun CL, Xiong YJ, US Patent, 6,448,191 (2012).
Tian HF, Yao JH, Zha F, Yao L, Chang Y, Appl. Clay Sci., 184, 105392 (2020)
Dai WL, Wang CM, Dyballa M, Wu GJ, Guan NJ, Li LD, Xie ZK, Hunger M, ACS Catal., 5, 317 (2015)
Wang X, Chen WX, Zhang L, Yao T, Liu W, Lin Y, Ju HX, Dong JC, Zheng LR, Yan WS, Zheng XS, Li ZJ, Wang XQ, Yang J, He DS, Wang Y, Deng ZX, Wu YE, Li YD, J. Am. Chem. Soc., 139(28), 9419 (2017)
Shi W, Zhang BS, Lin YM, Wang Q, Zhang Q, Su DS, ACS Catal., 6, 7844 (2016)
Kamarudin NHN, Jalil AA, Triwahyono S, Mukti RR, Ab Aziz MA, Setiabudi HD, Muhid MNM, Hamdan H, Appl. Catal. A: Gen., 431, 104 (2012)
Tamiyakul S, Ubolcharoen W, Tungasmita DN, Jongpatiwut S, Catal. Today, 256, 325 (2015)
Li XY, Yang JX, Xu R, Lu LF, Kong FG, Liang M, Jiang LJ, Nie SX, Si CL, Ind. Crop. Prod., 135, 196 (2019)
Yang H, Liu XH, Lu GZ, Wang YQ, Microporous Mesoporous Mater., 225, 144 (2015)
Singh AK, Yadav R, Sakthivel A, Microporous Mesoporous Mater., 181, 166 (2013)
Salmasi M, Fatemi S, Najafabadi AT, J. Ind. Eng. Chem., 17(4), 755 (2011)
Alvaro-Munoz T, Marquez-Alvarez C, Sastre E, Catal. Today, 179(1), 27 (2012)
Gao MB, Li H, Yang M, Zhou JB, Yuan XS, Tian P, Ye M, Liu ZM, Chem. Eng. J., 337, 119668 (2019)
Wang PF, Zha F, Yao L, Chang Y, Appl. Clay Sci., 163, 249 (2018)
Yang ST, Kim JY, Chae HJ, Kim M, Jeong SY, Ahn WS, Mater. Res. Bull., 47, 3888 (2012)
Salih HA, Muraza O, Abussaud B, Al-Shammari TK, Yokoi T, Ind. Eng. Chem. Res., 57(19), 6639 (2018)
Zhang DZ, Wei YX, Xu L, Chang FX, Liu ZY, Meng SH, Su BL, Liu ZM, Microporous Mesoporous Mater., 116, 684 (2008)
Firoozi M, Baghalha M, Asadi M, Catal. Commun., 10, 1582 (2009)
Othman I, Mohamed RM, Ibrahim IA, Mohamed MM, Appl. Catal. A: Gen., 299, 95 (2006)
Chen D, Moljord K, Holme A, Microporous Mesoporous Mater., 164, 239 (2012)
Din IU, Shaharun MS, Naeem A, Tasleem S, Johan MR, Chem. Eng. J., 334, 619 (2018)
Jing BQ, Li JF, Chemistry Select, 4, 7634 (2019)
Song WG, Haw JF, Nicholas JB, Heneghan CS, J. Am. Chem. Soc., 122(43), 10726 (2000)
Haw JF, Marcus DM, Top Catal., 34, 41 (2005)
Olsbye U, Svelle S, Bjorgen M, Beato P, Janssens TVW, Bordiga FS, Lillerud KP, Angew. Chem.-Int. Edit., 51, 5810 (2012)
Dai WL, Cao G, Yang L, Wu GJ, Dyballa M, Hunger M, Guan NJ, Li LD, Catal. Sci. Technol., 7, 607 (2017)
Nawaz Z, Tang XP, Zhu J, Wei F, Naveed S, Chin. J. Catal., 30, 1049 (2009)
Kim HJ, Kim JW, Kim N, Kim TW, Jhung SH, Kim CU, Mol. Catal., 438, 86 (2017)
