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Received December 25, 2020
Accepted April 29, 2021
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Cationic surfactant templated synthesis of magnetic mesoporous nanocomposites for efficient removal of Light Green
Department of Chemistry, Faculty of Science and Arts, Bursa Uludag University, 16059, Bursa, Turkey 1Department of Physics, Faculty of Science and Arts, Bursa Uludag University, 16059, Bursa, Turkey 2Department of Chemistry, Faculty of Science and Arts, Kocaeli University, 41380, Kocaeli, Turkey
Korean Journal of Chemical Engineering, July 2021, 38(7), 1425-1437(13), 10.1007/s11814-021-0829-x
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Abstract
Fe3O4-SiO2-NH2, Fe3O4-CTABSiO2-NH2 and Fe3O4-SiO2-CTABSiO2-NH2 magnetic adsorbents were successfully prepared and could be used effectively for the adsorption of Light Green from aqueous solutions. Unlike the first sample, mesoporous silica coatings were created using cetyltrimethylammoniumbromide micelles as molecular templates on superparamagnetic iron oxide in one sample, and on silica-coated iron oxide in the other sample to improve the adsorptive properties of the nanocomposites. The characterization by FT-IR, SEM/EDX, Zeta-potential, XRD, VSM, and N2-adsorption/desorption confirmed the production of mesoporous silica layer. Although coating processes with both silica and mesoporous silica layers led to a vaguely decrease in saturation magnetization of the Fe3O4- SiO2-CTABSiO2-NH2, the nanoparticles were protected with silica coatings for environment conditions and made more suitable for subsequent amino functionalization. The results determined from Batch adsorption experiments fitted to Langmuir isotherm model with maximum adsorption capacity (qmax) equal to 56.18, 196.08 and 227.27mg g-1, for Fe3O4-SiO2-NH2, Fe3O4-CTABSiO2-NH2 and Fe3O4-SiO2-CTABSiO2-NH2, respectively, and it was seen from the kinetic results, the LG adsorption was identified by pseudo-second-order kinetics, revealing that LG adsorption process is homogeneous, monolayer and based on chemical interactions. According to the results, both silica and mesoporous silica coating strategy can play crucial role in improving the adsorptive properties of nanocomposites.
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Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK, J. Colloid Interface Sci., 342(2), 518 (2010)
Li K, Zeng Z, Xiong J, Yan L, Guo H, Liu S, Dai Y, Chen T, Colloids Surf. A: Physicochem. Eng. Asp., 465, 113 (2015)
Nicola R, Muntean SG, Nistor MA, Putz AM, Almasy L, Sacarescu L, Chemosphere, 261, 127737 (2020)
Jin S, Park BC, Ham WS, Pan L, Kim YK, Colloids Surf. A: Physicochem. Eng. Asp., 531, 133 (2017)
Nicola R, Costisor O, Muntean SG, Nistor MA, Putz AM, Lanasi C, Lazau R, Almasy L, Sacarescu L, J. Porous Mater., 27, 413 (2020)
Ianasi C, Piciorus M, Nicola R, Cipec M, Negrea A, Niznansky D, Len A, Almasy L, Putz AM, Korean J. Chem. Eng., 36(5), 688 (2019)
Wang JH, Zheng SR, Shao Y, Liu JL, Xu ZY, Zhu DQ, J. Colloid Interface Sci., 349(1), 293 (2010)
Nicola R, Costisor O, Ciopec M, Negrea A, Lazau R, Ianasi C, Piciorus EM, Len A, Almasy L, Szerb EII, Putz AM, Appl. Sci., 10, 2726 (2020)
Deng Y, Qi D, Deng C, Zhang X, Zhao D, J. Am. Chem. Soc., 130(1), 28 (2008)
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Erdem B, Avsar SB, Erdem S, Tekin N, J. Dispersion Sci. Technol., 40, 1227 (2019)
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Zhao B, Xiao W, Zhang Y, Zhu H, Han R, Arabian J. Chem., 10, S3595 (2017)
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Betiha MA, Moustafa YM, El-Shahat MF, Rafik E, J. Hazard. Mater., 397, 122675 (2020)
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Sing KSW, Pure Appl. Chem., 54, 2201 (1982)
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Kheshti Z, Hassanajili S, J. Inorg. Organomet. Polym., 27, 1613 (2017)
Pasandideh EK, Kakavandi B, Nasseri S, Mahvi AH, Nabizadeh R, Esrafili A, Kalantary RR, J. Environ. Health Sci. Eng., 14, 21 (2016)
Ayar N, Bilgin B, Atun G, Chem. Eng. J., 138(1-3), 239 (2008)
Salman JM, Al-Saad KA, Int. J. Chem. Sci., 10, 677 (2012)
Solener M, Tunali S, Ozcanc AS, Ozean A, Gedikbey T, Desalination, 223(1-3), 308 (2008)
Zandipak R, Sobhanardakani S, Clean Technol. Environ. Policy, 20, 871 (2018)
Ain QU, Rasheed U, Yaseen M, Zhang H, Tong Z, J. Hazard. Mater., 397, 122758 (2020)
