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Received December 8, 2020
Accepted April 29, 2021
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Optimization of basic magenta adsorption onto Fe/Cu nanocomposites synthesized by sweet potato leaf extract using response surface methodology
1School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China 2Henan Center for Outstanding Overseas Scientists, Zhengzhou 450001, China
xlhan@zzu.edu.cn
Korean Journal of Chemical Engineering, August 2021, 38(8), 1556-1563(8), 10.1007/s11814-021-0828-y
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Abstract
Green synthesis of metal nanoparticles using plant extracts as an effective bio-reducing reagent has attracted considerable attention. Fe/Cu nanocomposites synthesized by extracts of sweet potato leaves served to remove basic magenta (BM) from aqueous solution. The adsorption operation conditions of BM on Fe/Cu nanocomposites were optimum by Box-Behnken design (BBD) model of response surface methodology (RSM). The adsorption equilibrium data were well described by the Sips and Redlich-Peterson models. The thermodynamic studies showed that the adsorption process was endothermic and spontaneous. The maximum adsorption capacity from the Sips model was 235.92mg/g at 298 K, which indicated that Fe/Cu nanocomposites had potential application in wastewater treatment. As indicated by pseudo-second order kinetics model, the adsorption of BM onto Fe/Cu nanocomposites could be achieved through the complexation, H-bonding, π-π adsorbate-adsorbent interaction, and electrostatic interaction at different pH values.
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References
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Huang LH, Kong JJ, Wang WL, Zhang CL, Niu SF, Gao BY, Desalination, 286, 268 (2012)
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Wang L, Wu XL, Xu WH, Huang XJ, Liu JH, Xu AW, Appl. Mater. Inter., 4, 2686 (2012)
Prasad AS, Mater. Sci. Semicond. Process, 53, 79 (2016)
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Zhou T, Fang L, Wang X, Han M, Zhang S, Han R, Desalin. Water Treat., 70, 294 (2017)
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Li SF, Tao M, Xie YD, Desalin. Water. Treat., 57, 1 (2015)
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Lara-Vasquez EJ, Solache-Rios M, Gutierrez-Segura E, J. Environ. Chem. Eng., 4, 1594 (2016)
