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Received January 13, 2021
Accepted April 4, 2021
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Construction of OH sites within MIL-101(Cr)-NH2 framework for enhanced CO2 adsorption and CO2/N2 selectivity
Department of Chemical Engineering, Industrial University of Ho Chi Minh City, 12 Nguyen Van Bao, Go Vap, Ho Chi Minh City, Vietnam 1Department of Chemical Engineering (Integrated Engineering), Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do 17104, Korea
Korean Journal of Chemical Engineering, August 2021, 38(8), 1676-1685(10), 10.1007/s11814-021-0799-z
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Abstract
The MIL-101(Cr)-NH2 framework was effectively modified by 2,5-dihydroxyterephthalic acid ((HO)2BDC) guest molecules to obtain (HO)2BDC-incorporated MIL-101(Cr)-NH2 adsorbent, namely (HO)2BDC@CrN. The CO2- temperature programmed-desorption (TPD) analysis indicated that the incorporation of (HO)2BDC into the MIL- 101(Cr)-NH2 framework generated new OH sites besides unsaturated Cr- metal sites and NH2 sites. The formed OH sites improved CO2 adsorption and separation on the prepared adsorbent. The highest CO2 uptake capacity of ~3.58mmol g-1 obtained over the novel (HO)2BDC@CrN adsorbent was higher 40% than that of the parent MOF, and also surpasses that of other previously reported adsorbents, including activated carbon, nitrogen-doped hollow carbon, zeolite, ZIF-68, MOF-5, ZIF-8, UiO-66(Zr), and MIL-100(Cr). The highest ideal adsorbed solution theory (IAST) CO2/ N2 selectivity of ~67 was obtained over the (HO)2BDC@CrN adsorbent at 100 kPa. The achieved selectivity was six times greater than that of pure MIL-101(Cr)-NH2. In addition, the synthesized (HO)2BDC@CrN adsorbent displayed good regenerability after six consecutive adsorption-desorption cycles.
Keywords
References
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Simmons JM, Wu H, Zhou W, Yildirim T, Energy Environ. Sci., 4, 2177 (2011)
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Tran NT, Vo TK, Kim J, Othman MR, Colloids Surf. A: Physicochem. Eng. Asp., 615, 126242 (2021)
Vaidhyanathan R, Iremonger SS, Dawson KW, Shimizu GKH, Chem. Commun., 35, 5230 (2009)
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Vo TK, Le VN, Nguyen VC, Song M, Kim DK, Yoo KS, Park BJ, Kim JS, J. Ind. Eng. Chem., 86, 178 (2020)
Vo TK, Le VN, Quang DT, Song M, Kim D, Kim J, Microporous Mesoporous Mater., 306, 110405 (2020)
Vo TK, Le VN, Yoo KS, Song M, Kim D, Kim J, Cryst. Growth Des., 19, 4949 (2019)
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Vo TK, Trinh TP, Nguyen VC, Kim J, J. Ind. Eng. Chem., 95, 224 (2020)
Wang D, Ke Y, Guo D, Guo H, Chen J, Weng W, Sens. Actuators B-Chem., 216, 504 (2015)
Xian SK, Wu Y, Wu JL, Wang X, Xiao J, Ind. Eng. Chem. Res., 54(44), 11151 (2015)
Yan Q, Lin Y, Kong C, Chen L, Chem. Commun., 49, 6873 (2013)
Yu J, Wang S, Low J, Xiao W, Phys. Chem. Chem. Phys., 15, 16883 (2013)
Zhang Z, Li X, Liu B, Zhao Q, Chen G, RSC Adv., 6, 4289 (2016)
Zhao ZX, Li Z, Lin YS, Ind. Eng. Chem. Res., 48(22), 10015 (2009)
Zheng XX, Shen LJ, Chen XP, Zheng XH, Au CT, Jiang LL, Inorg. Chem., 57(16), 10081 (2018)
Zhong R, Yu X, Meng W, Liu J, Zhi C, Zou R, ACS Sustain. Chem. Eng., 6, 16493 (2018)
Zhou J, Zhao H, Li J, Zhu Y, Hu J, Liu H, Hu Y, Solid State Sci., 24, 107 (2013)
Zhou X, Huang W, Liu J, Wang H, Li Z, Chem. Eng. Sci., 167, 98 (2017)
Zhou X, Huang WY, Miao JP, Xia QB, Zhang ZJ, Wang HH, Li Z, Chem. Eng. J., 266, 339 (2015)
Zhou Z, Cheng B, Ma C, Xu F, Xiao J, Xia Q, Li Z, RSC Adv., 5, 94276 (2015)
Zhou ZY, Mei L, Ma C, Xu F, Xiao J, Xia QB, Li Z, Chem. Eng. Sci., 147, 109 (2016)
Zou R, Abdel-Fattah AI, Xu H, Zhao Y, Hickmott DD, CrystEngComm., 12, 1337 (2010)
