Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received November 13, 2020
Accepted April 29, 2021
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Effective pore control and enhanced strength of cellulose acetate using polyethylene glycol for improved battery stability
1Department of Chemistry and Energy Engineering, Sangmyung University, Seoul 03016, Korea 2Department of Computer Science, Sangmyung University, Seoul 03016, Korea 3Department of Chemistry, Sangmyung University, Seoul 03016, Korea
swkang@smu.ac.kr
Korean Journal of Chemical Engineering, August 2021, 38(8), 1715-1719(5), 10.1007/s11814-021-0826-0
Download PDF
Abstract
Water-channels were generated into cellulose acetate (CA) via the addition of polyethylene glycol (PEG) and water-assisted pressures. It was found that the PEG used as the plasticizer could enable pores in CA to be controlled. Since the PEG had a relatively small molecular weight, it easily penetrated into polymer chains and formed abundant free volumes in the CA, enabling the pore control. In addition, the PEG enhanced the thermal stability of CA by forming new bipolar interactions and hydrogen bonding between the CA chains and the hydroxyl groups of PEG. From these result, it could be expected that due to the low cost and eco-friendliness of PEG and CA, they could be widely used to manufacture separators used in batteries.
Keywords
References
Lizundia E, Costa CM, Alves R, Menedez SL, Carbohydr. Polym. Technol. Appl., 1, 100001 (2020)
Ou S, Lin Z, He X, Przesmitzki S, Bouchard J, Trans. Res. Part D, 81, 102248 (2020)
Dong T, Atifeen WU, Choi J, Yoo K, Ko T, Chem. Eng. J., 398, 125646 (2020)
Han X, Lu L, Zheng Y, Feng X, Li Z, Li J, Ouyang M, eTransportation, 1, 100005 (2019)
Zhu C, Zhang J, Xu J, Yin X, Wu J, Chen S, Zhu Z, Wang L, Wang H, Carbohydr. Polym., 248, 116753 (2020)
Huang XS, J. Power Sources, 323, 17 (2016)
Arifeen WU, Kim MC, Ting D, Kurniawan R, Choi JW, Yoo KW, Ko TJ, Mater. Chem. Phys., 245, 122780 (2020)
Liang X, Yang Y, Jin X, Cheng J, J. Mater. Sci. Technol., 32(3), 200 (2016)
Shao YB, Xu LF, Zhao XW, Li JQ, Hu ZY, Fang C, Hu JM, Guo D, Ouyang MG, Int. J. Hydrog. Energy, 45(4), 3108 (2020)
Lee CS, Lee JH, Park MS, Kim JH, Korean Chem. Eng. Res., 57(3), 392 (2019)
Miao L, Huan H, Wang Z, Lv Y, Xiong W, Zhu D, Gan L, Li L, Chem. Eng., 382, 122945 (2020)
Bakangura E, Cheng CL, Wu L, Ge XL, Ran J, Khan MI, Kamana E, Afsar N, Irfan M, Shehzad A, Xu TW, J. Membr. Sci., 537, 32 (2017)
Wang J, Xia Y, Liu Y, Li W, Zhao D, Energy Storage Mater., 22, 147 (2019)
Xu W, Wang Z, Shi L, Ma Y, Yuan S, Sun L, Zhao Y, Zhang M, Zhu J, ACS Appl. Mater. Interfaces, 7, 20678 (2015)
Lee YM, Choi NS, Lee JA, Seol WH, Cho KY, Jung HY, Kim JW, Park JK, J. Power Sources, 146(1-2), 431 (2005)
Lee YM, Kim JW, Choi NS, Lee JA, Seol WH, Park JK, J. Power Sources, 139(1-2), 235 (2005)
Sheng L, Xu R, Zhang H, Bai Y, Song S, Liu G, Wang T, Huang X, He J, J. Electroanal. Chem., 873, 114391 (2020)
Lyu P, Liu X, Qu J, Zhao J, Huo Y, Qu Z, Rao Z, Energy Storage Mater., 31, 195 (2020)
Liu B, Jia Y, Yuan C, Wang L, Gao X, Yin S, Xu J, Energy Storage Mater., 24, 85 (2020)
Lee WG, Kim DH, Jeon WC, Kwak SK, Kang SJ, Kang SW, Sci. Rep., 7(1), 1287 (2017)
Meng Y, Shu L, Liu L, Wu Y, Xie LH, Zhao MJ, Li JR, J. Membr. Sci., 591, 117360 (2019)
Qiu WJ, An CH, Yan YW, Xu J, Zhang ZJ, Guo W, Wang Z, Zheng ZJ, Wang ZB, Deng QB, Li JS, J. Power Sources, 423, 98 (2019)
Li JM, Hu CS, Shao JM, Li HJ, Li PY, Li XC, He WD, Polymer, 119, 152 (2017)
Kim HY, Cho YH, Kang SW, J. Ind. Eng. Chem., 78, 421 (2019)
Lee WG, Kang SW, J. Ind. Eng. Chem., 70, 103 (2019)
Hwang J, Choi J, Kim JM, Kang SW, Macromol. Res., 24(11), 1020 (2016)
Ou S, Lin Z, He X, Przesmitzki S, Bouchard J, Trans. Res. Part D, 81, 102248 (2020)
Dong T, Atifeen WU, Choi J, Yoo K, Ko T, Chem. Eng. J., 398, 125646 (2020)
Han X, Lu L, Zheng Y, Feng X, Li Z, Li J, Ouyang M, eTransportation, 1, 100005 (2019)
Zhu C, Zhang J, Xu J, Yin X, Wu J, Chen S, Zhu Z, Wang L, Wang H, Carbohydr. Polym., 248, 116753 (2020)
Huang XS, J. Power Sources, 323, 17 (2016)
Arifeen WU, Kim MC, Ting D, Kurniawan R, Choi JW, Yoo KW, Ko TJ, Mater. Chem. Phys., 245, 122780 (2020)
Liang X, Yang Y, Jin X, Cheng J, J. Mater. Sci. Technol., 32(3), 200 (2016)
Shao YB, Xu LF, Zhao XW, Li JQ, Hu ZY, Fang C, Hu JM, Guo D, Ouyang MG, Int. J. Hydrog. Energy, 45(4), 3108 (2020)
Lee CS, Lee JH, Park MS, Kim JH, Korean Chem. Eng. Res., 57(3), 392 (2019)
Miao L, Huan H, Wang Z, Lv Y, Xiong W, Zhu D, Gan L, Li L, Chem. Eng., 382, 122945 (2020)
Bakangura E, Cheng CL, Wu L, Ge XL, Ran J, Khan MI, Kamana E, Afsar N, Irfan M, Shehzad A, Xu TW, J. Membr. Sci., 537, 32 (2017)
Wang J, Xia Y, Liu Y, Li W, Zhao D, Energy Storage Mater., 22, 147 (2019)
Xu W, Wang Z, Shi L, Ma Y, Yuan S, Sun L, Zhao Y, Zhang M, Zhu J, ACS Appl. Mater. Interfaces, 7, 20678 (2015)
Lee YM, Choi NS, Lee JA, Seol WH, Cho KY, Jung HY, Kim JW, Park JK, J. Power Sources, 146(1-2), 431 (2005)
Lee YM, Kim JW, Choi NS, Lee JA, Seol WH, Park JK, J. Power Sources, 139(1-2), 235 (2005)
Sheng L, Xu R, Zhang H, Bai Y, Song S, Liu G, Wang T, Huang X, He J, J. Electroanal. Chem., 873, 114391 (2020)
Lyu P, Liu X, Qu J, Zhao J, Huo Y, Qu Z, Rao Z, Energy Storage Mater., 31, 195 (2020)
Liu B, Jia Y, Yuan C, Wang L, Gao X, Yin S, Xu J, Energy Storage Mater., 24, 85 (2020)
Lee WG, Kim DH, Jeon WC, Kwak SK, Kang SJ, Kang SW, Sci. Rep., 7(1), 1287 (2017)
Meng Y, Shu L, Liu L, Wu Y, Xie LH, Zhao MJ, Li JR, J. Membr. Sci., 591, 117360 (2019)
Qiu WJ, An CH, Yan YW, Xu J, Zhang ZJ, Guo W, Wang Z, Zheng ZJ, Wang ZB, Deng QB, Li JS, J. Power Sources, 423, 98 (2019)
Li JM, Hu CS, Shao JM, Li HJ, Li PY, Li XC, He WD, Polymer, 119, 152 (2017)
Kim HY, Cho YH, Kang SW, J. Ind. Eng. Chem., 78, 421 (2019)
Lee WG, Kang SW, J. Ind. Eng. Chem., 70, 103 (2019)
Hwang J, Choi J, Kim JM, Kang SW, Macromol. Res., 24(11), 1020 (2016)
