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Received October 9, 2020
Accepted May 12, 2021
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Preparation of N-TiO2/RGO nanocomposites through sol-gel method
College of Chemical Engineering, China University of Petroleum Huadong, Qingdao 266580, Shandong Prov., China
liuhuie@upc.edu.cn
Korean Journal of Chemical Engineering, September 2021, 38(9), 1913-1922(10), 10.1007/s11814-021-0843-z
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Abstract
Nitrogen-doped TiO2 and reduced graphene oxide (RGO) nanocomposites (NTG) were prepared by solgel method followed by annealing treatment process under N2 atmosphere. The as-prepared NTG nanocomposite were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FT-IR) and ultraviolet-visible diffuse reflectance spectroscopy (DRS). The results indicate that the incorporation of nitrogen onto both RGO and TiO2 was accomplished simultaneously in the facile process. Nitrogen doping makes the light excitation range red shift and can enhance the electron-hole separation effectively. The photocatalytic activity of the as-prepared samples was evaluated through the degradation of methyl orange (MO) under visible light irradiation. The introduction of nitrogen increased the photodegradation activity, which can be indicated by the fitted apparent first-order kinetics rate constant k, increasing about four times from 0-NTG-450 to 15-NTG-450. The annealing treatment further increased the photodegradation activity about 1.5 times of 15NTG-450 for 15NTG-800.
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References
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Zhao YX, Qiu XF, Burda C, Chem. Mater., 20, 2629 (2008)
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Hao YN, Guo HL, Tian L, Kang XF, RSC Adv., 5, 43750 (2015)
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Zhao D, Sheng G, Chen C, Wang X, Appl. Catal. B: Environ., 303, 111 (2012)
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Hao YN, Guo HL, Tian L, Kang XF, RSC Adv., 5, 43750 (2015)
Liu YJ, Zhao JX, Caiab QH, Phys. Chem. Chem. Phys., 18, 5491 (2016)
