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Received March 11, 2021
Accepted July 12, 2021
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Experimental investigation of polysulfone modified cellulose acetate membrane for CO2/H2 gas separation
Inamullah Douna
Sarah Farrukh†
Arshad Hussain1
Zarrar Salahuddin
Tayyaba Noor
Erum Pervaiz
Mohammad Younas2
Xian Feng Fan3
School of Chemical and Material Engineering, National University of Science and Technology, Islamabad, Pakistan 1Pak-Austria Fachhochschule, Institute of Applied Science and Technology, Haripur-KPK, Pakistan 2Department of Chemical Engineering, University of Engineering and Technology, Peshawar, Pakistan 3Department of Chemical Engineering, University of Edinburgh, Edinburgh, UK
sarah.farrukh@scme.nust.edu.pk
Korean Journal of Chemical Engineering, January 2022, 39(1), 189-197(9), 10.1007/s11814-021-0900-7
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Abstract
Processed gas streams from the water gas shift reactor (WGSR) are enriched with CO2 and H2. Purification of H2 from CO2 for different applications is required because of its environmental and economic benefits. Among different separation technologies, membrane technology gets much attention due to its various advantages. In this work, cellulose acetate/polysulfone blended membranes were fabricated via solution casting method for CO2/H2 separation. The separation performance of pure CA membrane was enhanced by addition of PSF. The fabricated membranes were analyzed through various characterization techniques, such as FTIR, SEM, DSC, and XRD. Gas permeation results show that permeability of CO2 increased with increasing concentration of PSF. Notable permeability (P=80.51 Barrer) of CO2 and selectivity of CO2/H2=1.83 of CA/PSF 2wt% were achieved at 25 °C and 2.5 bar compared to pure CA membrane. To the best of our knowledge, this blend has been studied for the first time for gas separation, prepared through the solution casting method.
Keywords
References
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Rafiq S, Man Z, Maulud A, Muhammad N, Maitra S, Sep. Purif. Technol., 90, 162 (2012)
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Kallel T, Massardier-Nageotte V, Jaziri M, Gerard JF, Elleuch B, J. Appl. Polym. Sci., 90(9), 2475 (2003)
Codou A, Anstey A, Misra M, Mohanty AK, RSC Adv., 8, 15709 (2018)
Moon JD, Bridge AT, D'Ambra C, Freeman BD, Paul DR, J. Membr. Sci., 582, 182 (2019)
Miyashita Y, Suzuki T, Nishio Y, Cellulose, 9, 215 (2002)
Mubashir M, Fong YY, Keong LK, Leng CT, Jusoh N, Sep. Purif. Technol., 199, 140 (2018)
Saljoughi E, Amirilargani M, Mohammadi T, Desalination, 262(1-3), 72 (2010)
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Wu H, Fang X, Zhang XF, Jiang ZY, Li B, Ma XC, Sep. Purif. Technol., 64(2), 183 (2008)
Thanakkasaranee S, Kim D, Seo J, Polymers, 10, 225 (2018)
Vinodhini PA, Sangeetha K, Thandapani G, Sudha P, Jayachandran V, Sukumaran A, Int. J. Biol. Macromol., 104, 1721 (2017)
Gaur M, Singh PK, Chauhan RS, J. Therm. Anal. Calorim., 111, 743 (2013)
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Shakeel I, Hussain A, Farrukh S, J. Polym. Environ., 27, 1449 (2019)
Gaur M, Singh PK, Chauhan R, J. Therm. Anal. Calorim., 111, 743 (2013)
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Raouf M, Abedini R, Omidkhah M, Nezhadmoghadam E, Process Saf. Environ. Protect., 133, 394 (2020)
Mondal A, Mandal B, J. Membr. Sci., 446, 383 (2013)
Klepic M, Setnickova K, Lanc M, Zak M, Izak P, Dendisova M, Fuoco A, Jansen JC, Friess K, J. Membr. Sci., 597, 117623 (2020)
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Hosseini SE, Wahid MA, Renew. Sust. Energ. Rev., 57, 850 (2016)
Cao X, Xu H, Dong S, Xu J, Qiao Z, Zhao S, Wang J, Wang Z, J. Membr. Sci., 601, 117882 (2020)
Hosseini SE, Wahid MA, Renew. Sust. Energ. Rev., 57, 850 (2016)
Chen WH, Chen CY, Appl. Energy, 258, 114078 (2020)
Yang SI, Choi DY, Jang SC, Kim SH, Choi DK, Adsorption, 14, 583 (2008)
Hinchliffe AB, Porter KE, Chem. Eng. Res. Des., 78(2), 255 (2000)
Aksu GO, Daglar H, Altintas C, Keskin S, J. Phys. Chem., 124, 22577 (2020)
Kenarsari SD, Yang D, Jiang G, Zhang S, Wang J, Russell AG, Wei Q, Fan M, RSC Adv., 3, 22739 (2013)
Merkel TC, Zhou MJ, Baker RW, J. Membr. Sci., 389, 441 (2012)
Figueroa JD, Fout T, Plasynski S, McIlvried H, Srivastava RD, Int. J. Grnhouse Gas Control, 2, 9 (2008)
Nabais AR, Martins APS, Alves VD, Crespo JG, Marrucho IM, Tome LC, Neves LA, Sep. Purif. Technol., 222, 168 (2019)
Li PY, Wang Z, Qiao ZH, Liu YN, Cao XC, Li W, Wang JX, Wang SC, J. Membr. Sci., 495, 130 (2015)
Kang Z, Peng Y, Qian Y, Yuan D, Addicoat MA, Heine T, Hu Z, Tee L, Guo Z, Zhao D, Chem. Mater., 28, 1277 (2016)
Japip S, Liao KS, Chung TS, Adv. Mater., 29, 160383 (2017)
Lin HQ, He ZJ, Sun Z, Kniep J, Ng A, Baker RW, Merkel TC, J. Membr. Sci., 493, 794 (2015)
Vakharia V, Ramasubramanian K, Ho WSW, J. Membr. Sci., 488, 56 (2015)
Alcheikhhamdon Y, Hoorfar M, Chem. Eng. Process., 120, 105 (2017)
Raza A, Farrukh S, Hussain A, J. Polym. Environ., 25, 46 (2017)
Torstensen JO, Helberg RM, Deng L, Gregersen OW, Syverud K, Int. J. Grnhouse Gas Control, 81, 93 (2019)
Lam B, Wei M, Zhu LX, Luo SJ, Guo RL, Morisato A, Alexandridis P, Lin HQ, Polymer, 89, 1 (2016)
Isfahani AP, Sadeghi M, Dehaghani AHS, Aravand MA, J. Ind. Eng. Chem., 44, 67 (2016)
Kalantari K, Moradihamedani P, Ibrahim NA, Bin Abdullah AH, Afifi ABM, Polym. Bull., 75(8), 3723 (2018)
Lee WG, Kang SW, Chem. Eng. J., 356, 312 (2019)
Sanaeepur H, Amooghin AE, Bandehali S, Moghadassi A, Matsuura T, Van der Bruggen B, Prog. Polym. Sci, 91, 80 (2019)
Tyan N, Polotskaya G, Meleshko T, Yakimansky A, Pientka Z, Russian J. Appl. Chem., 92, 360 (2019)
Vanherck K, Koeckelberghs G, Vankelecom IF, Prog. Polym. Sci, 38, 874 (2013)
Puspasari T, Chakrabarty T, Genduso G, Peinemann KVJJOMCA, J. Mater. Chem., 6, 13685 (2018)
Mannan HA, Mukhtar H, Shaharun MS, Othman MR, Murugesan T, J. Appl. Polym. Sci., 133, 42946 (2016)
Rezakazemi M, Amooghin AE, Montazer-Rahmati MM, Ismail AF, Matsuura T, Prog. Polym. Sci, 39, 817 (2014)
Yong WF, Zhang H, Prog. Mater. Sci., 116, 100713 (2020)
Bai H, Ho WSW, Ind. Eng. Chem. Res., 48(5), 2344 (2009)
Klepic M, Setnickova K, Lanc M, Zak M, Izak P, Dendisova M, Fuoco A, Jansen JC, Friess K, J. Membr. Sci., 597, 117623 (2020)
Rabiee H, Soltanieh M, Mousavi SA, Ghadimi A, J. Membr. Sci., 469, 43 (2014)
Reijerkerk SR, Knoef MH, Nijmeijer K, Wessling M, J. Membr. Sci., 352(1-2), 126 (2010)
Sanaeepur H, Ahmadi R, Sinaei M, Kargari A, J. Membr. Sci. Res., 5, 25 (2019)
Abd Hamid MA, Chung YT, Rohani R, Junaidi MUM, Sep. Purif. Technol., 209, 598 (2019)
Salahuddin Z, Farrukh S, Hussain A, Int. J. Polym. Anal. Charact., 23, 483 (2018)
Li JT, Nagai K, Nakagawa T, Wang S, J. Appl. Polym. Sci., 58(9), 1455 (1995)
Minhas FT, Farrukh S, Hussain A, Mujahid M, J. Polym. Res., 22, 63 (2015)
Khan AL, Li XF, Vankelecom IFJ, J. Membr. Sci., 380(1-2), 55 (2011)
Scandola M, Ceccorulli G, Polymer, 26, 1953 (1985)
Farrukh S, Javed S, Hussain A, Mujahid M, Asia.Pacific J. Chem. Eng., 9, 543 (2014)
Kulprathipanja S, Ann. N. Y. Acad. Sci., 984, 361 (2003)
Rafiq S, Man Z, Maulud A, Muhammad N, Maitra S, Sep. Purif. Technol., 90, 162 (2012)
Dorosti F, Omidkhah MR, Pedram MZ, Moghadam F, Chem. Eng. J., 171(3), 1469 (2011)
Salahshoori I, Nasirian D, Rashidi N, Hossain MK, Hatami A, Hassanzadeganroudsari M, Polym. Bull., 78, 3227 (2020)
Benosmane N, Guedioura B, Hamdi SM, Hamdi M, Boutemeur B, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 30, 860 (2010)
Rashid MH, Farrukh S, Javed S, Hussain A, Fan X, Ali S, Ayoub M, Chem. Pap., 74, 821 (2020)
Sutrisna PD, Savitri E, Gunawan MA, Putri IHF, de Rozari SG, Polym.-Plast. Technol. Mater., 59, 1300 (2020)
Kallel T, Massardier-Nageotte V, Jaziri M, Gerard JF, Elleuch B, J. Appl. Polym. Sci., 90(9), 2475 (2003)
Codou A, Anstey A, Misra M, Mohanty AK, RSC Adv., 8, 15709 (2018)
Moon JD, Bridge AT, D'Ambra C, Freeman BD, Paul DR, J. Membr. Sci., 582, 182 (2019)
Miyashita Y, Suzuki T, Nishio Y, Cellulose, 9, 215 (2002)
Mubashir M, Fong YY, Keong LK, Leng CT, Jusoh N, Sep. Purif. Technol., 199, 140 (2018)
Saljoughi E, Amirilargani M, Mohammadi T, Desalination, 262(1-3), 72 (2010)
Vinodhini PA, Sangeetha K, Thandapani G, Sudha P, Jayachandran V, Sukumaran A, Int. J. Biol. Macromol., 104, 1721 (2017)
Wu H, Fang X, Zhang XF, Jiang ZY, Li B, Ma XC, Sep. Purif. Technol., 64(2), 183 (2008)
Thanakkasaranee S, Kim D, Seo J, Polymers, 10, 225 (2018)
Vinodhini PA, Sangeetha K, Thandapani G, Sudha P, Jayachandran V, Sukumaran A, Int. J. Biol. Macromol., 104, 1721 (2017)
Gaur M, Singh PK, Chauhan RS, J. Therm. Anal. Calorim., 111, 743 (2013)
Sajjan P, Nayak V, Padaki M, Zadorozhnyy VY, Klyamkin SN, Konik PJE, Fuels, 34, 11699 (2020)
Shakeel I, Hussain A, Farrukh S, J. Polym. Environ., 27, 1449 (2019)
Gaur M, Singh PK, Chauhan R, J. Therm. Anal. Calorim., 111, 743 (2013)
Vetrivel S, Saraswathi MSA, Rana D, Nagendran A, Int. J. Biol. Macromol., 107, 1607 (2018)
Makhloufi C, Roizard D, Favre E, J. Membr. Sci., 441, 63 (2013)
Chen YP, et al., Nanostructured materials for next generation energy storage and conversion, Springer, Heidelberg (2017).
Abd Hamid MA, Chung YT, Rohani R, Junaidi MUM, Sep. Purif. Technol., 209, 598 (2019)
Khanh PN, Trung NT, Srour H, Carbon dioxide chemistry, capture and oil recovery, intechopen, London (2018).
Raouf M, Abedini R, Omidkhah M, Nezhadmoghadam E, Process Saf. Environ. Protect., 133, 394 (2020)
Mondal A, Mandal B, J. Membr. Sci., 446, 383 (2013)
Klepic M, Setnickova K, Lanc M, Zak M, Izak P, Dendisova M, Fuoco A, Jansen JC, Friess K, J. Membr. Sci., 597, 117623 (2020)
Yousef S, Sereika J, Tonkonogovas A, Hashem T, Mohamed A, J. Environ. Technol. Innovation, 21, 101339 (2021)
Giel V, Kredatusova J, Trchova M, Brus J, Zitka J, Peter J, Eur. Polym. J., 77, 98 (2016)
Yong WF, Li FY, Chung TS, Tong YW, J. Membr. Sci., 462, 119 (2014)