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Received February 27, 2021
Accepted July 4, 2021
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Kinetics, isothermal and mechanistic insight into the adsorption of eosin yellow and malachite green from water via tri-metallic layered double hydroxide nanosheets
Muhammad Altaf Nazir1
Tayyaba Najam2
Muhammad Sohail Bashir3
Muhammad Sufyan Javed4
Muhammad Aswad Bashir1
Muhammad Imran5
Umair Azhar6†
Syed Shoaib Ahmad Shah1 3†
Aziz ur Rehman1†
1Institute of Chemistry, The Islamia University of Bahawalpur, Bahawalpur 63100, I. R. Pakistan 2Institute for Advanced Study, Shenzhen University, Shenzhen 518060, P. R. China 3Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China 4School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, P. R. China 5Department of Chemistry, Faculty of Science, King Khalid University, P.O. Box 9004, Abha 61413, Saudi Arabia 6Department of Polymer Engineering, National Textile University Karachi Campus, Karachi 74900, I. R. Pakistan
umair.azhar9922@gmail.com
Korean Journal of Chemical Engineering, January 2022, 39(1), 216-226(11), 10.1007/s11814-021-0892-3
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Abstract
The use of highly efficient, environment-friendly and economically inexpensive materials for the adsorption removal of contaminants from water has always been considered as emerging task. In this study, we synthesized hybrid tri-metallic nickel cobalt layered double hydroxide (NiCoAl-LDH) porous material for the adsorption removal of Eosin yellow (EY) and Malachite green (MG) from water. The characterization results disclosed that tri-metallic LDH has been synthesized with extraordinary purity, identical morphology and high surface area (134.21 m2ㆍg-1). The NiCoAl-LDH performs the best for adsorption of EY (qe=37.30mgㆍg-1 at pH=2) and MG (qe=39.61 mgㆍg-1 at pH= 10). The Langmuir and Freundlich isotherm models were applied to explain the adsorption process of dyes on the surface of LDH. The Langmuir model (R2=0.991 and 0.999 for Eosin Y and Malachite G, respectively) was very appropriate to explain the process of adsorption on NiCoAl-LDH as homogeneous (monolayer). The maximum adsorption capacity of EY and MG calculated with Langmuir model was 78.74 and 110.13mgㆍg-1 at 30 °C, respectively. Also with 240 minutes contact time 94.8% EY and 89.9% MG was adsorbed by as synthesized NiCoAl-LDH nanosheets. The NiCoAl-LDH nanosheets showed excellent performance of reusability of up to five regeneration cycles. The results showed that the adsorption capacity of NiCoAl-LDH nanosheets after five regeneration cycles, to adsorb EY, decreased only from 40.80 to 36.93mgㆍg-1 and that of MG from 79.21 to 75.42mgㆍg-1, which is acceptable. The overall results Suggest that the fabricated NiCoAl-LDH is favorable for the purification of dye contaminated water.
Keywords
References
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Oliveira EHCD, Fraga DMDSM, da Silva MP, et al., J. Environ. Chem. Eng., 7(2), 103001 (2019)
Thabet MS, Ismaiel AM, J. Encapsulation Adsorpt. Sci., 6(03), 70 (2016)
Li C, Xiong ZH, Zhang JM, Wu CS, J. Chem. Eng. Data, 60(11), 3414 (2015)
Mohammadi A, Daemi H, Barikani M, Int. J. Biol. Macromol., 69, 447 (2014)
Nethaji S, Sivasamy A, Thennarasu G, Saravanan S, J. Hazard. Mater., 181(1-3), 271 (2010)
Sekhar CP, Kalidhasan S, Rajesh V, Rajesh N, Chemosphere, 77(6), 842 (2009)
Janos P, Environ. Sci. Technol., 37(24), 5792 (2003)
Jiang F, Dinh DM, Hsieh YL, Carbohydr. Polym., 173, 286 (2017)
Shi Z, Xu C, Guan H, Li L, Fan L, Wang Y, Liu L, Meng Q, Zhang R, Colloids Surf. A: Physicochem. Eng. Asp., 539, 382 (2018)
Lu H, Zhang L, Wang B, Long Y, Zhang M, Ma J, Khan A, Chowdhury SP, Zhou X, Ni Y, Cellulose, 26(8), 4909 (2019)
Michael I, Rizzo L, McArdell C, Manaia C, Merlin C, Schwartz T, Dagot C, Fatta-Kassinos D, Water Res., 47(3), 957 (2013)
Gunduz F, Bayrak B, J. Mol. Liq., 243, 790 (2017)
Daud M, Hai A, Banat F, Wazir MB, Habib M, Bharath G, Al-Harthi MA, J. Mol. Liq., 288, 110989 (2019)
Ferreira FJL, Silva LS, da Silva MS, et al., Carbohydr. Polym., 225, 115246 (2019)
Nazir MA, Bashir MA, Najam T, et al., Microchem. J., 164, 105973 (2021)
Shahzad K, Najam T, Bashir MS, Nazir MA, Rehman AU, Bashir MA, Shah SSA, Inorg. Chem. Commun., 123, 108357 (2021)
Shahzad K, Khan MI, Elboughdiri N, Ghernaout D, Rehman AU, Water Environ. Res., 93, 1116 (2021)
Zhang H, Guan W, Zhang L, Guan X, Wang S, ACS Omega., 5(29), 18007 (2020)
Zhao X, Niu C, Zhang L, Guo H, Wen X, Liang C, Zeng G, Chemosphere, 204, 11 (2018)
Jamshaid M, Rehman AU, Kumar OP, Iqbal S, Nazir MA, Anum A, Khan HM, J. Mater. Sci. Mater. Electron. (2021).
Nazir MA, Khan NA, Cheng C, Shah SSA, Najam T, Arshad M, Sharif A, Akhtar S, Rehman AU, Appl. Clay Sci., 190, 105564 (2020)
Khan NA, Shaheen S, Najam T, et al., Toxin Rev., (2020).
Najam T, Ibraheem S, Nazir MA, Shaheen A, Waseem A, Javed MS, Shah SSA, Cai X, Int. J. Hydrog. Energy, 46(13), 8864 (2021)
Bashir MS, Jiang X, Kong XZ, Eur. Polym. J., 129, 109652 (2020)
Bashir MS, Jiang X, Li S, Kong XZ, Front. Chem., 7, 314 (2019)
Xu X, Zou J, Zhao XR, Jiang XY, Jiao FP, Yu JG, Liu Q, Teng J, Colloids Surf. A: Physicochem. Eng. Asp., 570, 127 (2019)
Oyelude EO, Awudza JA, Twumasi SK, Sci. Rep., 7(1), 1 (2017)
Ugbe FA, Anebi PO, Ikudayisi VA, Int. Ann. Sci., 4(1), 14 (2018)
Jeyapragasam T, Mater Today: Proceedings., 3(6), 2146 (2016)
Okey-Onyesolu C, Okoye C, Chime D, Int. J. Sci. Eng. Res., 9(3), 140 (2018)
Borah L, Goswami M, Phukan P, J. Environ. Chem. Eng., 3(2), 1018 (2015)
Zeng H, Gao M, Shen T, Ding F, Colloids Surf. A: Physicochem. Eng. Asp., 555, 746 (2018)
Liu Y, Chen Y, Shi Y, Wan D, Chen J, Xiao S, Water Environ. Res., 93, 159 (2021)
Zhang MM, Yu ZH, Yu HC, Polym. Bull., 77(2), 1049 (2020)
Cheng ZL, Li YX, Liu Z, Ecotoxicol. Environ. Saf., 148, 585 (2018)
Ghoreishi SM, Haghighi R, Chem. Eng. J., 95(1-3), 163 (2003)
Almoisheer N, Alseroury F, Kumar R, Aslam M, Barakat M, RSC Adv., 9(1), 560 (2019)
Scarpellini D, Falconi C, Gaudio P, Mattoccia A, Medaglia P, Orsini A, Pizzoferrato R, Richetta M, Microelectron. Eng., 126, 129 (2014)
Kumar OP, Ashiq MN, Shah SSA, Akhtar S, Obaidi MMA, Mujtaba IM, Rehman AU, Mater. Sci. Semicond. Process., 128, 105748 (2021)
Sajid M, Basheer C, Trends Analyt. Chem., 75, 174 (2016)
Li C, Wei M, Evans DG, Duan X, Small, 10(22), 4469 (2014)
Cuautli C, Valente JS, Conesa J, Ganduglia-Pirovano MVN, Ireta J, J. Phys. Chem. C., 123(14), 8777 (2019)
Torres-Rodriguez DA, Lima E, Valente JS, Pfeiffer H, J. Phys. Chem. A, 115(44), 12243 (2011)
Nicotera I, Angjeli K, Coppola L, Enotiadis A, Pedicini R, Carbone A, Gournis D, Solid State Ion., 276, 40 (2015)
Han J, Dou Y, Zhao J, Wei M, Evans DG, Duan X, Small, 9(1), 98 (2013)
Najam T, Shah SSA, Ding W, Deng J, Wei Z, J. Power Sources, 438, 226919 (2019)
Li L, Gu W, Chen J, Chen W, Xu ZP, Biomaterials, 35(10), 3331 (2014)
Zubair M, Jarrah N, Manzar MS, Al-Harthi M, Daud M, Mu’azu ND, Haladu SA, J. Mol. Liq., 230, 344 (2017)
Khodam F, Rezvani Z, Amani-Ghadim AR, J. Ind. Eng. Chem., 21, 1286 (2015)
Clark I, Smith J, Gomes RL, Lester E, J. Environ. Chem. Eng., 7(3), 103175 (2019)
Guo X, Yin P, Yang H, Microporous Mesoporous Mater., 259, 123 (2018)
Hu HJ, Liu JY, Xu ZH, Zhang LY, Cheng B, Ho WK, Appl. Surf. Sci., 478, 981 (2019)
Sun YY, Zhou JB, Cai WQ, Zhao RS, Yuan JP, Appl. Surf. Sci., 349, 897 (2015)
Khajeh RT, Aber S, Zarei M, Renew. Energy, 154, 1263 (2020)
Jiang DB, Jing C, Yuan YS, Feng L, Liu XY, Dong F, Dong BQ, Zhang YX, J. Colloid Interface Sci., 540, 398 (2019)
Richa, Choudhury AR, Carbohydr. Polym., 227, 115291 (2020)
Gupta K, Khatri OP, J. Colloid Interface Sci., 501, 11 (2017)
Chaukura N, Murimba EC, Gwenzi W, Appl. Water Sci., 7(5), 2175 (2017)
Sepehr MN, Al-Musawi TJ, Ghahramani E, Kazemian H, Zarrabi M, Arab. J. Chem., 10(5), 611 (2017)
Anita T, Kumar PS, Kumar KS, J. Water Process. Eng., 13, 127 (2016)
Oliveira EHCD, Fraga DMDSM, da Silva MP, et al., J. Environ. Chem. Eng., 7(2), 103001 (2019)
Thabet MS, Ismaiel AM, J. Encapsulation Adsorpt. Sci., 6(03), 70 (2016)
Li C, Xiong ZH, Zhang JM, Wu CS, J. Chem. Eng. Data, 60(11), 3414 (2015)
Mohammadi A, Daemi H, Barikani M, Int. J. Biol. Macromol., 69, 447 (2014)
Nethaji S, Sivasamy A, Thennarasu G, Saravanan S, J. Hazard. Mater., 181(1-3), 271 (2010)
Sekhar CP, Kalidhasan S, Rajesh V, Rajesh N, Chemosphere, 77(6), 842 (2009)
Janos P, Environ. Sci. Technol., 37(24), 5792 (2003)
Jiang F, Dinh DM, Hsieh YL, Carbohydr. Polym., 173, 286 (2017)
Shi Z, Xu C, Guan H, Li L, Fan L, Wang Y, Liu L, Meng Q, Zhang R, Colloids Surf. A: Physicochem. Eng. Asp., 539, 382 (2018)
