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Received December 21, 2021
Accepted April 2, 2022
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Construction of superhydrophilic and underwater superoleophobic corn stalk/konjac glucomannan aerogel for high-efficiency oil/water emulsion separation
1School of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian, 116034, China 2Xiamen Institute of Rare Earth Materials, Haixi Institute, Chinese Academy of Sciences, Xiamen, 361026, China
Korean Journal of Chemical Engineering, October 2022, 39(10), 2664-2674(11), 10.1007/s11814-022-1133-0
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Abstract
An anti-fouling aerogel with superior separation performance for separation of oil/water emulsion is of great significance to industrial development due to continuously increasing oily industrial wastewater. Herein, a superhydrophilic/ underwater superoleophobic porous biobased aerogel with a three-dimensional network structure was prepared by the agricultural waste corn stalk (CS) incorporated with konjac glucomannan (KGM) through simple sol-gel and freeze-drying methods. The oil/water separation mechanisms and the effect of aerogel structural changes on the separation performance of CS/KGM aerogel for oil-in-water emulsions are discussed in detail. Using toluene as an oil phase, CS3.50K1.25 exhibited outstanding separation performance with an excellent separation efficiency above 96.26% and a high permeate flux above 2,381 L m-2 h-1 for oil-in-water emulsions. As expected, the separation efficiency and permeation flux can be wholly recovered after washing, indicating the aerogel possesses good sustainability. Moreover, CS/KGM aerogel has the advantages of low cost, simple preparation, eco-friendly and anti-fouling, revealing a promising candidate for the treatment of oily wastewater pollution.
Keywords
References
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Xu C, Yan F, Wang M, Yan H, Cui Z, Li J, He B, J. Membr. Sci., 602, 117974 (2020)
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Shen X, Liu P, He C, Xia S, Liu J, Cheng F, Suo H, Zhao Y, Chen L, Sep. Purif. Technol., 255, 117418 (2021)
Wang W, Fang Y, Ni X, Wu K, Wang Y, Jiang F, Riffat SB, Carbohydr. Polym., 224, 115129 (2019)
Zhang R, Liu Y, He M, Su Y, Zhao X, Elimelech M, Jiang Z, Chem. Soc. Rev., 45, 5888 (2016)
Chaudhary JP, Vadodariya N, Nataraj SK, Meena R, ACS Appl. Mater. Interfaces, 7, 24957 (2015)
Zarghami S, Mohammadi T, Sadrzadeh M, J. Membr. Sci., 582, 402 (2019)
Liu Y, Su Y, Guan J, Cao J, Zhang R, He M, Jiang Z, ACS Appl. Mater. Interfaces, 10, 26546 (2018)
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Deng Y, Zhang G, Bai R, Shen S, Zhou X, Wyman I, J. Membr. Sci., 569, 60 (2019)
Gao S, Zhu Y, Wang J, Zhang F, Li J, Jin J, Adv. Funct. Mater., 28, 1801944 (2018)
Wang Y, He Y, Yan S, Yin X, Chen J, Colloids Surf. A: Physicochem. Eng. Asp., 582, 123891 (2019)
Venkatesh K, Arthanareeswaran G, Bose AC, Kumar PS, Sep. Purif. Technol., 241, 116709 (2020)
Du Y, Li Y, Wu T, RSC Adv., 7, 41838 (2017)
