Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received January 24, 2022
Accepted April 6, 2022
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Novel heterojunction magnetic composite MIL-53 (Fe)/ZnFe2O4: Synthesis and photocatalytic pollutant degradation
1Department of Environmental Research, Institute for Color Science and Technology, Tehran, Iran 2Department of Chemical and Petroleum Engineering, Sharif University of Technology, Tehran, Iran 3, Iran
nm_mahmoodi@aut.ac.ir
Korean Journal of Chemical Engineering, October 2022, 39(10), 2713-2724(12), 10.1007/s11814-022-1140-1
Download PDF
Abstract
A new magnetic composite was synthesized by integration of ZnFe2O4 and MIL-53(Fe) micro-rods by a solvothermal method. This composite served as a heterogeneous catalyst to overcome the high electron-hole recombination rates of ZnFe2O4 and to enhance the degradation of Direct Red 23 under visible light irradiation. Different analytical techniques, including XRD, FTIR, SEM, DRS, VSM, and PL, were employed to characterize the synthesized heterojunction nanocomposite and to evaluate its photocatalytic activity. The ZnFe2O4/MIL-53(Fe)/Vis-light system resulted in significantly higher dye degradation as compared with pristine ZnFe2O4 and MIL-53(Fe) semiconductors at the optimum pH of 3.1 and irradiation time of 120 minutes. Moreover, the composite exhibited high magnetization property that led to easy collection and recovery from effluent solution. It also retained its durability and stability after five cycles. The photo-generated hole was found to be the primary dye destruction agent as specified by the scavenger test.
Keywords
References
Mahmoodi NM, Soltani-Gordefaramarzi S, Prog. Color Colorants Coat., 9, 85 (2016)
Asefi D, Mahmoodi NM, Arami M, Colloids Surf. A: Physicochem. Eng. Asp., 355, 183 (2010)
Mahmoodi NM, Arami M, J. Appl. Polym. Sci., 109, 4043 (2008)
Mahmoodi NM, J. Ind. Eng. Chem., 20, 2050 (2014)
Davarpanah S, Mahmoodi NM, Arami M, Bahrami H, Mazaheri F, Appl. Surf. Sci., 255, 4171 (2009)
Mahmoodi NM, J. Taiwan Instit. Chem. Eng., 45, 2008 (2014)
Mahmoodi NM, Najafi F, Microporous Mesoporous Mater., 156, 153 (2012)
Mahmoodi NM, Arabloo M, Abdi J, Water Res., 67, 216 (2014)
Mahmoodi NM, J. Mol. Catal. A-Chem., 366, 254 (2013)
Mahmoodi NM, Arami M, Zhang J, J. Alloy. Compd., 509, 4754 (2011)
Mahmoodi NM, Arami M, Limaee NY, Gharanjig K, Nourmohammadian F, Mater. Res. Bull., 42, 797 (2007)
Zhang Q, Jiang L, Wang J, Zhu Y, Pu Y, Dai W, Appl. Catal. B: Environ., 277, 119122 (2020)
Mamba G, Mishra AK, Appl. Catal. B: Environ., 198, 347 (2016)
Zhao W, Liang C, Wang B, Xing S, ACS Appl. Mater. Interface, 9, 41927 (2017)
Chen M, Dai Y, Guo J, Yang H, Liu D, Zhai Y, Appl. Surf. Sci., 493, 1361 (2019)
Sambathkumar C, Arasi SE, Natarajan B, Arivarasan A, Devendran P, Int. J. Eng. Adv. Technol., 9, 1085 (2019)
Kuang M, Zhang J, Wang W, Chen J, Liu R, Xie S, Wang J, Ji Z, Solid State Sci., 96, 105901 (2019)
Su J, Shang Q, Guo T, Yang S, Wang X, Ma Q, Guan H, Xu F, Tsang SC, Mater. Chem. Phys., 219, 22 (2018)
Xie T, Xu L, Liu C, Wang Y, Appl. Surf. Sci., 273, 684 (2013)
Erusappan E, Thiripuranthagan S, Durai M, Kumaravel S, Vembuli T, New J. Chem., 44, 7758 (2020)
Yao Y, Cai Y, Lu F, Qin J, Wei F, Xu C, Wang S, Ind. Eng. Chem. Res., 493, 17294 (2014)
Dhal JP, Mishra BG, Hota G, RSC Adv., 5, 58072 (2015)
Wang Z, Lai C, Qin L, Fu Y, He J, Huang D, Chem. Eng. J., 392, 124851 (2020)
Zhang S, Xu Y, Zhao D, Chen W, Li H, Hou C, Molecules, 25, 124 (2020)
Gao Y, Li S, Li Y, Yao L, Zhang H, Appl. Catal. B: Environ., 202, 165 (2017)
Lin KYA, Chang HA, Hsu CJ, RSC Adv., 5, 32520 (2015)
Du JJ, Yuan YP, Sun JX, Peng FM, Jiang X, Qiu LG, Xie AJ, Shen YH, Zhu JF, J. Hazard. Mater., 190, 945 (2011)
Liu Q, Zeng C, Ai L, Hao Z, Jiang J, Appl. Catal. B: Environ., 224, 38 (2018)
Su J, Yuan S, Wang HY, Huang L, Ge JY, Joseph E, Qin J, Cagin T, Zuo JL, Zhou HC, Nat. Commun., 8, 1 (2017)
Carrington EJ, McAnally CA, Fletcher AJ, Thompson SP, Warren M, Brammer L, Nat. Chem., 9, 882 (2017)
Millange F, Guillou N, Medina ME, Férey G, Carlin-Sinclair A, Golden KM, Walton RI, Chem. Mater., 22, 4237 (2010)
Du J, Yuan Y, Sun J, Peng F, Jiang X, Qiu L, J. Hazard. Mater., 190, 945 (2011)
Panda R, Rahut S, Basu JK, RSC Adv., 6, 80981 (2016)
Abida O, Kolar M, Jirkovsky J, Mailhot G, Photochem. Photobiol. Sci., 11, 794 (2012)
Wang Z, Chen X, Ji H, Ma W, Chen C, Zhao J, Environ. Sci. Technol., 44, 263 (2010)
Park H, Kim HI, Moon GH, Choi W, Energy Environ. Sci., 9, 411 (2016)
Hu P, Chen C, Song J, Tang Z, Mater. Sci. Semicond. Process, 77, 40 (2018)
Zhang C, Ai L, Jiang J, J. Mater. Chem. A, 3, 3074 (2015)
Xiao J, Yang W, Gao S, Sun C, Li Q, J. Mater. Sci. Technol., 34, 2331 (2018)
Ghimire S, Flury M, Scheenstra EJ, Miles CA, Sci. Total Environ., 703, 135577 (2019)
Hu L, Deng G, Lu W, Pang S, Hu X, Appl. Surf. Sci., 410, 401 (2017)
Bayat R, Derakhshi P, Rahimi R, Safekordi AA, Rabbani M, Solid State Sci., 89, 167 (2019)
Araya T, Jia M, Yang J, Zhao P, Cai K, Ma W, Huang Y, Appl. Catal. B: Environ., 203, 768 (2017)
Liang R, Jing F, Shen L, Qin N, Wu L, J. Hazard. Mater., 287, 364 (2015)
Kulkarni SD, Kumbar S, Menon SG, Choudhari KS, Santhosh C, Mater. Res. Bull., 77, 70 (2016)
Munn AS, Ramirez-Cuesta AJ, Millange F, Walton RI, Chem. Phys., 427, 30 (2013)
Chen H, Liu Y, Cai T, Dong W, Tang L, Xia X, Wang L, Li T, ACS Appl. Mater. Interface, 11, 28791 (2019)
Behera A, Kandi D, Majhi SM, Martha S, Parida K, Beilstein J. Nanotechnol., 9, 436 (2018)
Feng X, Chen H, Jiang F, J. Colloid Interface Sci., 494, 32 (2017)
Nguyen VH, Bach LG, Bui QTP, Nguyen TD, Vo DVN, Vu HT, Do ST, J. Environ. Chem. Eng., 6, 7434 (2018)
Oladipo AA, Process Saf. Environ. Protect., 116, 413 (2018)
Feng J, Zhang Z, Gao M, Gu M, Wang J, Zeng W, Lv Y, Ren Y, Fan Z, Zhao H, Liu R, Zhang Q, Wang Q, Mater. Res. Bull., 223, 172 (2019)
Zhao H, Liu R, Zhang Q, Wang Q, Mater. Res. Bull., 75, 172 (2016)
Matli PR, Zhou X, Shiyu D, Huang Q, Int. Nano Lett., 5, 53 (2015)
Abbasian AR, Afarani MS, Appl. Phys. A-Mater. Sci. Process., 125, 721 (2019)
Feng J, Zhang Z, Gao M, Gu M, Wang J, Zeng W, Lv Y, Ren Y, Fan Z, Mater. Chem. Phys., 223, 758 (2019)
Bagherzadeh SB, Kazemeini M, Mahmoodi NM, J. Mol. Liq., 19, 35661 (2020)
Wang D, Jia F, Wang H, Chen F, Fang Y, Dong W, Zeng G, Li X, Yang Q, Yuan X, J. Colloid Interface Sci., 519, 273 (2018)
Zhang C, Ai L, Jiang J, Ind. Eng. Chem. Res., 54, 153 (2015)
Borthakur S, Saikia L, J. Environ. Chem. Eng., 7, 103035 (2019)
Liang PL, Yuan LY, Deng H, Wang XC, Wang L, Li ZJ, Luo SZ, Shi WQ, Appl. Catal. B: Environ., 267, 118688 (2020)
Sun Y, Lei J, Wang Y, Tang Q, Kang C, RSC Adv., 10, 17293 (2020)
Oladipo AA, Ifebajo AO, Gazi M, Appl. Catal. B: Environ., 243, 243 (2019)
Liu J, Liu G, Yuan C, Chen L, Tian X, Fang M, New J. Chem., 42, 3736 (2018)
Yang J, Niu X, An S, Chen W, Wang J, Liu W, RSC Adv., 7, 2943 (2017)
Wu Q, Yang H, Kang L, Gao Z, Ren F, Appl. Catal. B: Environ., 263, 118282 (2020)
Rawal SB, Kang HJ, Won DI, Lee WI, Appl. Catal. B: Environ., 256, 117856 (2019)
Xiao H, Zhang W, Yao Q, Huang L, Chen L, Boury B, Chen Z, Appl. Catal. B: Environ., 244, 719 (2019)
Ahmad M, Chen S, Ye F, Quan X, Afzal S, Yu H, Zhao X, Appl. Catal. B: Environ., 245, 428 (2018)
Vuong GT, Pham MH, Do TO, CrystEngComm., 15, 9694 (2013)
Veldurthi NK, Eswar NK, Singh SA, Madras G, Catal. Sci. Technol., 8, 1083 (2018)
Z. Yang, X. Xu, X. Liang, Lei C, Wei Y, He P, Lv B, Ma H, Lei Z, Appl. Catal
Wang M, Yang L, Yuan J, He L, Song Y, Zhang H, Zhang Z, Fang S, RSC Adv., 8, 12459 (2018)
Gao C, Chen S, Quan X, Yu H, Zhang Y, J. Catal., 356, 125 (2017)
Nguyen TB, Doong RA, RSC Adv., 7, 50006 (2017)
Mahmoodi NM, Arami M, Chem. Eng. J., 146, 189 (2009)
Mahmoodi NM, Taghizadeh A, Taghizadeh M, Abdi J, J. Hazard. Mater., 378, 120741 (2019)
Oveisi M, Mahmoodi NM, Asli MA, J. Clean Prod., 222, 669 (2019)
Mahmoodi NM, Water Air Soil Pollut., 224, 1612 (2013)
Oveisi M, Asli MA, Mahmoodi NM, Inorg. Chim. Acta., 487, 169 (2019)
Mahmoodi NM, Environ. Monit. Assess., 186, 5595 (2014)
Mahmoodi NM, Bashiri M, Moeen SJ, Mater. Res. Bull., 47, 4403 (2012)
Mahmoodi NM, Abdi J, Taghizadeh M, Taghizadeh A, Hayati B, Shekarchi AA, Vossuoghi M, J. Environ. Manage., 233, 660 (2019)
Ruan S, Huang W, Zhao M, Song H, Gao Z, Mater. Sci. Semicond. Process, 107, 104835 (2020)
Low J, Yu J, Jaroniec M, Wageh S, Al-Ghamdi AA, Adv. Mater., 29, 1 (2017)
Marschall R, Adv. Funct. Mater., 24, 2421 (2014)
Mahmoodi NM, Desalin. Water Treat., 53, 84 (2015)
Mahmoodi NM, J. Environ. Eng.-ASCE, 139, 1368 (2013)
Mahmoodi NM, Limaee NY, Arami M, Borhany S, Mohammad-Taheri M, J. Photochem. Photobiol. A-Chem., 189, 1 (2007)
Mahmoodi NM, Arami M, Limaee NY, Gharanjig K, Ardejani FD, Colloids Surf. A: Physicochem. Eng. Asp., 290, 125 (2006)
Asefi D, Mahmoodi NM, Arami M, Colloids Surf. A: Physicochem. Eng. Asp., 355, 183 (2010)
Mahmoodi NM, Arami M, J. Appl. Polym. Sci., 109, 4043 (2008)
Mahmoodi NM, J. Ind. Eng. Chem., 20, 2050 (2014)
Davarpanah S, Mahmoodi NM, Arami M, Bahrami H, Mazaheri F, Appl. Surf. Sci., 255, 4171 (2009)
Mahmoodi NM, J. Taiwan Instit. Chem. Eng., 45, 2008 (2014)
Mahmoodi NM, Najafi F, Microporous Mesoporous Mater., 156, 153 (2012)
Mahmoodi NM, Arabloo M, Abdi J, Water Res., 67, 216 (2014)
Mahmoodi NM, J. Mol. Catal. A-Chem., 366, 254 (2013)
Mahmoodi NM, Arami M, Zhang J, J. Alloy. Compd., 509, 4754 (2011)
Mahmoodi NM, Arami M, Limaee NY, Gharanjig K, Nourmohammadian F, Mater. Res. Bull., 42, 797 (2007)
Zhang Q, Jiang L, Wang J, Zhu Y, Pu Y, Dai W, Appl. Catal. B: Environ., 277, 119122 (2020)
Mamba G, Mishra AK, Appl. Catal. B: Environ., 198, 347 (2016)
Zhao W, Liang C, Wang B, Xing S, ACS Appl. Mater. Interface, 9, 41927 (2017)
Chen M, Dai Y, Guo J, Yang H, Liu D, Zhai Y, Appl. Surf. Sci., 493, 1361 (2019)
Sambathkumar C, Arasi SE, Natarajan B, Arivarasan A, Devendran P, Int. J. Eng. Adv. Technol., 9, 1085 (2019)
Kuang M, Zhang J, Wang W, Chen J, Liu R, Xie S, Wang J, Ji Z, Solid State Sci., 96, 105901 (2019)
Su J, Shang Q, Guo T, Yang S, Wang X, Ma Q, Guan H, Xu F, Tsang SC, Mater. Chem. Phys., 219, 22 (2018)
Xie T, Xu L, Liu C, Wang Y, Appl. Surf. Sci., 273, 684 (2013)
Erusappan E, Thiripuranthagan S, Durai M, Kumaravel S, Vembuli T, New J. Chem., 44, 7758 (2020)
Yao Y, Cai Y, Lu F, Qin J, Wei F, Xu C, Wang S, Ind. Eng. Chem. Res., 493, 17294 (2014)
Dhal JP, Mishra BG, Hota G, RSC Adv., 5, 58072 (2015)
Wang Z, Lai C, Qin L, Fu Y, He J, Huang D, Chem. Eng. J., 392, 124851 (2020)
Zhang S, Xu Y, Zhao D, Chen W, Li H, Hou C, Molecules, 25, 124 (2020)
Gao Y, Li S, Li Y, Yao L, Zhang H, Appl. Catal. B: Environ., 202, 165 (2017)
Lin KYA, Chang HA, Hsu CJ, RSC Adv., 5, 32520 (2015)
Du JJ, Yuan YP, Sun JX, Peng FM, Jiang X, Qiu LG, Xie AJ, Shen YH, Zhu JF, J. Hazard. Mater., 190, 945 (2011)
Liu Q, Zeng C, Ai L, Hao Z, Jiang J, Appl. Catal. B: Environ., 224, 38 (2018)
Su J, Yuan S, Wang HY, Huang L, Ge JY, Joseph E, Qin J, Cagin T, Zuo JL, Zhou HC, Nat. Commun., 8, 1 (2017)
Carrington EJ, McAnally CA, Fletcher AJ, Thompson SP, Warren M, Brammer L, Nat. Chem., 9, 882 (2017)
Millange F, Guillou N, Medina ME, Férey G, Carlin-Sinclair A, Golden KM, Walton RI, Chem. Mater., 22, 4237 (2010)
Du J, Yuan Y, Sun J, Peng F, Jiang X, Qiu L, J. Hazard. Mater., 190, 945 (2011)
Panda R, Rahut S, Basu JK, RSC Adv., 6, 80981 (2016)
Abida O, Kolar M, Jirkovsky J, Mailhot G, Photochem. Photobiol. Sci., 11, 794 (2012)
Wang Z, Chen X, Ji H, Ma W, Chen C, Zhao J, Environ. Sci. Technol., 44, 263 (2010)
Park H, Kim HI, Moon GH, Choi W, Energy Environ. Sci., 9, 411 (2016)
Hu P, Chen C, Song J, Tang Z, Mater. Sci. Semicond. Process, 77, 40 (2018)
Zhang C, Ai L, Jiang J, J. Mater. Chem. A, 3, 3074 (2015)
Xiao J, Yang W, Gao S, Sun C, Li Q, J. Mater. Sci. Technol., 34, 2331 (2018)
Ghimire S, Flury M, Scheenstra EJ, Miles CA, Sci. Total Environ., 703, 135577 (2019)
Hu L, Deng G, Lu W, Pang S, Hu X, Appl. Surf. Sci., 410, 401 (2017)
Bayat R, Derakhshi P, Rahimi R, Safekordi AA, Rabbani M, Solid State Sci., 89, 167 (2019)
Araya T, Jia M, Yang J, Zhao P, Cai K, Ma W, Huang Y, Appl. Catal. B: Environ., 203, 768 (2017)
Liang R, Jing F, Shen L, Qin N, Wu L, J. Hazard. Mater., 287, 364 (2015)
Kulkarni SD, Kumbar S, Menon SG, Choudhari KS, Santhosh C, Mater. Res. Bull., 77, 70 (2016)
Munn AS, Ramirez-Cuesta AJ, Millange F, Walton RI, Chem. Phys., 427, 30 (2013)
Chen H, Liu Y, Cai T, Dong W, Tang L, Xia X, Wang L, Li T, ACS Appl. Mater. Interface, 11, 28791 (2019)
Behera A, Kandi D, Majhi SM, Martha S, Parida K, Beilstein J. Nanotechnol., 9, 436 (2018)
Feng X, Chen H, Jiang F, J. Colloid Interface Sci., 494, 32 (2017)
Nguyen VH, Bach LG, Bui QTP, Nguyen TD, Vo DVN, Vu HT, Do ST, J. Environ. Chem. Eng., 6, 7434 (2018)
Oladipo AA, Process Saf. Environ. Protect., 116, 413 (2018)
Feng J, Zhang Z, Gao M, Gu M, Wang J, Zeng W, Lv Y, Ren Y, Fan Z, Zhao H, Liu R, Zhang Q, Wang Q, Mater. Res. Bull., 223, 172 (2019)
Zhao H, Liu R, Zhang Q, Wang Q, Mater. Res. Bull., 75, 172 (2016)
Matli PR, Zhou X, Shiyu D, Huang Q, Int. Nano Lett., 5, 53 (2015)
Abbasian AR, Afarani MS, Appl. Phys. A-Mater. Sci. Process., 125, 721 (2019)
Feng J, Zhang Z, Gao M, Gu M, Wang J, Zeng W, Lv Y, Ren Y, Fan Z, Mater. Chem. Phys., 223, 758 (2019)
Bagherzadeh SB, Kazemeini M, Mahmoodi NM, J. Mol. Liq., 19, 35661 (2020)
Wang D, Jia F, Wang H, Chen F, Fang Y, Dong W, Zeng G, Li X, Yang Q, Yuan X, J. Colloid Interface Sci., 519, 273 (2018)
Zhang C, Ai L, Jiang J, Ind. Eng. Chem. Res., 54, 153 (2015)
Borthakur S, Saikia L, J. Environ. Chem. Eng., 7, 103035 (2019)
Liang PL, Yuan LY, Deng H, Wang XC, Wang L, Li ZJ, Luo SZ, Shi WQ, Appl. Catal. B: Environ., 267, 118688 (2020)
Sun Y, Lei J, Wang Y, Tang Q, Kang C, RSC Adv., 10, 17293 (2020)
Oladipo AA, Ifebajo AO, Gazi M, Appl. Catal. B: Environ., 243, 243 (2019)
Liu J, Liu G, Yuan C, Chen L, Tian X, Fang M, New J. Chem., 42, 3736 (2018)
Yang J, Niu X, An S, Chen W, Wang J, Liu W, RSC Adv., 7, 2943 (2017)
Wu Q, Yang H, Kang L, Gao Z, Ren F, Appl. Catal. B: Environ., 263, 118282 (2020)
Rawal SB, Kang HJ, Won DI, Lee WI, Appl. Catal. B: Environ., 256, 117856 (2019)
Xiao H, Zhang W, Yao Q, Huang L, Chen L, Boury B, Chen Z, Appl. Catal. B: Environ., 244, 719 (2019)
Ahmad M, Chen S, Ye F, Quan X, Afzal S, Yu H, Zhao X, Appl. Catal. B: Environ., 245, 428 (2018)
Vuong GT, Pham MH, Do TO, CrystEngComm., 15, 9694 (2013)
Veldurthi NK, Eswar NK, Singh SA, Madras G, Catal. Sci. Technol., 8, 1083 (2018)
Z. Yang, X. Xu, X. Liang, Lei C, Wei Y, He P, Lv B, Ma H, Lei Z, Appl. Catal
Wang M, Yang L, Yuan J, He L, Song Y, Zhang H, Zhang Z, Fang S, RSC Adv., 8, 12459 (2018)
Gao C, Chen S, Quan X, Yu H, Zhang Y, J. Catal., 356, 125 (2017)
Nguyen TB, Doong RA, RSC Adv., 7, 50006 (2017)
Mahmoodi NM, Arami M, Chem. Eng. J., 146, 189 (2009)
Mahmoodi NM, Taghizadeh A, Taghizadeh M, Abdi J, J. Hazard. Mater., 378, 120741 (2019)
Oveisi M, Mahmoodi NM, Asli MA, J. Clean Prod., 222, 669 (2019)
Mahmoodi NM, Water Air Soil Pollut., 224, 1612 (2013)
Oveisi M, Asli MA, Mahmoodi NM, Inorg. Chim. Acta., 487, 169 (2019)
Mahmoodi NM, Environ. Monit. Assess., 186, 5595 (2014)
Mahmoodi NM, Bashiri M, Moeen SJ, Mater. Res. Bull., 47, 4403 (2012)
Mahmoodi NM, Abdi J, Taghizadeh M, Taghizadeh A, Hayati B, Shekarchi AA, Vossuoghi M, J. Environ. Manage., 233, 660 (2019)
Ruan S, Huang W, Zhao M, Song H, Gao Z, Mater. Sci. Semicond. Process, 107, 104835 (2020)
Low J, Yu J, Jaroniec M, Wageh S, Al-Ghamdi AA, Adv. Mater., 29, 1 (2017)
Marschall R, Adv. Funct. Mater., 24, 2421 (2014)
Mahmoodi NM, Desalin. Water Treat., 53, 84 (2015)
Mahmoodi NM, J. Environ. Eng.-ASCE, 139, 1368 (2013)
Mahmoodi NM, Limaee NY, Arami M, Borhany S, Mohammad-Taheri M, J. Photochem. Photobiol. A-Chem., 189, 1 (2007)
Mahmoodi NM, Arami M, Limaee NY, Gharanjig K, Ardejani FD, Colloids Surf. A: Physicochem. Eng. Asp., 290, 125 (2006)
