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Received November 19, 2021
Accepted March 25, 2022
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Enhancing performance of polyacrylonitrile membranes for pervaporation dehydration of ethanol by tailoring morphology and process parameters
Seyed Mohammad Hosseini Nejad1
Amir Hossein Mostafavi1
Seyed Saeid Hosseini1 2†
Haoze Zeng3
Lu Shao3
1Membrane Science and Technology Research group, Department of Chemical Engineering, Tarbiat Modares University, Jalal-Ale-Ahmad, Tehran, Iran 2Institute for Nanotechnology and Water Sustainability, College of Science, Engineering and Technology, University of South Africa, Johannesburg, South Africa 3State Key Laboratory of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, P. R. China
saeid.hosseini@modares.ac.ir
Korean Journal of Chemical Engineering, October 2022, 39(10), 2764-2774(11), 10.1007/s11814-022-1125-0
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Abstract
Development of high performance membranes for ethanol (EtOH) dehydration constitutes one of the main applications of pervaporation technology. In the present study, the properties of membranes derived from PAN were examined for this purpose. Heat treatment and variation of operational parameters were explored as viable strategies for enhancing the process performance. The characteristics of the membranes including morphology, thickness and sorption behavior were investigated in detail to identify their roles. Application of heat treatment with regards to polymer Tg resulted in membranes with distinct morphological and sorption characteristics. Increase in operational temperature was found effective for optimizing the opposing trends of permeate flux and separation factor. The maximum PSI value for the pristine PAN membrane was 5,564.0 g·m-2h-1, which occurred for operation at 50 ℃. Also, application of heat treatment led to drop in flux and increase in separation factor by which PSI reached 41.3 kg·m-2h-1, which was 7.5 times than that of pristine PAN membrane. This study demonstrates successful implementation of facile strategies for tuning the characteristics and performance of membranes derived from PAN for efficient dehydration of EtOH via pervaporation process.
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Amid S, Aghbashlo M, Tabatabaei M, Karimi K, Nizami AS, Rehan M, Hosseinzadeh-Bandbafha H, Soufiyan MM, Energy Conv. Manag., 227, 113637 (2021)
Heidari M, Hosseini SS, Nasrin MO, Ghadimi A, Sep. Purif. Technol., 509, 503 (2019)
Khalid A, Aslam M, Qyyum MA, Faisal A, Khan AL, Ahmed F, Lee M, Kim J, Jang N, Chang IS, Bazmi AA, Yasin M, Renew. Sust. Energ. Rev., 105, 427 (2019)
Dehkordi JA, Hosseini SS, Kundu PK, Tan NR, Chem. Product Precess Modeling., 11(1), 11 (2016)
Leeper SA, Tsao GT, J. Membr. Sci., 30(3), 289 (1987)
Min HK, Sung SA, Lee SY, Lee SW, Kidney Res. Clin. Pract., 38(2), 196 (2019)
Gupta O, Roy S, Mitra S, Ind. Eng. Chem. Res., 58(39), 18313 (2019)
Gryta M, Morawski AW, Tomaszewska M, Catal. Today, 56(1), 159 (2000)
Lecaros RLG, Ho SY, Tsai HA, Hung WS, Hu CC, Huang SH, Lee KR, Lai JY, Sep. Purif. Technol., 275, 119125 (2021)
Mokarinezhad M, Hosseini SS, Ghadimi A, Asadi E, Nashrieh Shimi va Mohandesi Shimi Iran (NSMSI), Accepted In Press (2022).
Grzybek P, Jakubski L, Borys P, Kołodziej S, Ślusarczyk C, Turczyn R, Dudek G, Sep. Purif. Technol., 281, 119897 (2022)
Asadi E, Ghadimi A, Hosseini SS, Sadatnia B, Rostamizadeh M, Nadeali A, Microporous Mesoporous Mater., 329, 111539 (2022)
Samanta HS, Ray SK, Sep. Purif. Technol., 146, 176 (2015)
Akieh-Pirkanniemi M, Lisak G, Arroyo J, Bobacka J, Ivaska A, J. Membr. Sci., 511, 76 (2016)
Tamaddondar M, Pahlavanzadeh H, Hosseini SS, Ruan G, Tan NR, J. Membr. Sci., 472, 91 (2014)
Vane LM, J. Chem. Technol. Biotechnol., 95(3), 495 (2020)
Zeng H, He S, Hosseini SS, Zhu B, Shao L, Adv. Membr., 2, 100015 (2022)
Hosseini SS, Mehralian E, Ekbatan MH, Li P, Korean J. Chem. Eng., 38(3), 587 (2021)
Raza W, Jianhua Y, Wang J, Saulat H, Wang L, Lu J, Zhang Y, J. Appl. Polym. Sci., 138(37), 50942 (2021)
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Zentou H, Abidin ZZ, Yunus R, Biak DRA, Issa MA, Pudza MY, Chem. Eng. Res. Des., 175, 320 (2021)
Hosseini SS, Pahlavanzadeh H, Tamadondar M, Ir. Chem. Eng. J., 13, 76 (2014)
Jafarinasab M, Barzin J, Mortaheb HR, Mobedi H, Iran. Polym. J., 24(12), 989 (2015)
Di Carlo BV, Habert AC, J. Mater. Sci., 48(4), 1457 (2013)
Chen SH, Liou RM, Lai CL, Hung MY, Tsai MH, Huang SL, Desalination, 234(1), 221 (2008)
Li J, Si X, Li X, Wang N, An Q, Ji S, Sep. Purif. Technol., 192, 205 (2018)
Ang MBMY, Huang SH, Chang MW, Lai CL, Tsai HA, Hung WS, Hu CC, Lee KR, Sep. Purif. Technol., 235, 116155 (2020)
Claes S, Vandezande P, Mullens S, Leysen R, De Sitter K, Andersson A, Maurer FHJ, Van den Rul H, Peeters R, Van Bael MK, J. Membr. Sci., 351(1-2), 160 (2010)
Amarante RCA, Donaldson AA, Sep. Purif. Technol., 258, 117953 (2021)
Mali MG, Gokavi GS, AIP Conf Proc., 1989(1), 020027 (2018)
Amnuaypanich S, Naowanon T, Wongthep W, Phinyocheep P, J. Appl. Polym. Sci., 124(S1), E319 (2012)
Shahriari HR, Hosseini SS, Chem. Eng. Process., 147, 107766 (2020)
Wang ZG, Wan LS, Xu ZK, J. Membr. Sci., 304(1), 8 (2007)
Yushkin AA, Efimov MN, Malakhov AO, Karpacheva GP, Bondarenko G, Marbelia L, Vankelecom IFJ, Volkov AV, React. Funct. Polym., 158, 104793 (2021)
Scharnagl N, Buschatz H, Desalination, 139(1), 191 (2001)
Hosseini SS, Nazif A, Shahmirzadi MAA, Ortiz I, Sep. Purif. Technol., 187, 46 (2017)
Zhang X, Yang S, Yu B, Tan Q, Zhang X, Cong H, Sci. Rep., 8(1), 1260 (2018)
Shahmirzadi MAA, Hosseini SS, Ir. Chem. Eng. J., 13(77), 91 (2015)
Hosseini SS, Khodadadi H, Bakhshi B, Korean J. Chem. Eng., 38(1), 32 (2021)
Huang YH, Huang SH, Chao WC, Li CL, Hsieh YY, Hung WS, Liaw DJ, Hu CC, Lee KR, Lai JY, Polym. Int., 63(8), 1478 (2014)
Mostafavi AH, Mishra AK, Ulbricht M, Denayer J, Hosseini SS, J. Membr. Sci. Res., 7(4), 230 (2021)
Kim YJ, Ahn CH, Choi MO, Eur. Polym. J., 46(10), 1957 (2010)
Liu B, Wang S, Zhao P, Liang H, Zhang W, Crittenden J, Appl. Surf. Sci., 435, 415 (2018)
Duthie X, Kentish S, Pas SJ, Hill AJ, Powell C, Nagai K, Stevens G, Qiao G, J. Polym. Sci. B: Polym. Phys., 46(18), 1879 (2008)
Hamta A, Ashtiani FZ, Karimi M, Safikhani A, Polym. Adv. Technol., 32(2), 872 (2021)
Liang B, Pan K, Li L, Giannelis EP, Cao B, Desalination, 347, 199 (2014)
Shahmirzadi MAA, Hosseini SS, Ruan G, Tan NR, RSC Adv., 5(61), 49080 (2015)
Xu YM, Japip S, Chung TS, J. Membr. Sci., 595, 117571 (2020)
Tsai H, Ciou Y, Hu C, Lee K, Yu D, Lai J, J. Membr. Sci., 255(1-2), 33 (2005)
Alibakhshi S, Youssefi M, Hosseini SS, Zadhoush A, Polym. Eng. Sci., 61(3), 742 (2021)
Kamarudin D, Hashim NA, Ong BH, Kakihana Y, Higa M, Matsuyama H, J. Environ. Chem. Eng., 9(4), 105769 (2021)
Rahimpour A, Madaeni SS, Amirinejad M, Mansourpanah Y, Zereshki S, J. Membr. Sci., 330(1-2), 189 (2009)
Shen Y, Lua AC, J. Appl. Polym. Sci., 116, 2906 (2010)
Balani K, Verma V, Agarwal A, Narayan R, in: Biosurfaces: A materials science and engineering perspective, John Wiley & Sons, Hoboken, New Jersey (2015).
Hosseini SS, Najari S, in Nanostructured polymer membranes, volume 2: Applications, Visakh PM, Olga N Eds., Wiley Scrivener, Beverly, Massachusetts (2016).
Hosseini SS, Khodakarami AH, Nxumalo EN, Polym. Eng. Sci., 60(8), 1795 (2020)
Xu S, Wang Y, J. Membr. Sci., 496, 142 (2015)
Wang Y, Jiang L, Matsuura T, Chung TS, Goh SH, J. Membr. Sci., 318(1-2), 217 (2008)
Hao W, Tong Z, Liu X, Zhang B, Sep. Purif. Technol., 251, 117322 (2020)
Dobrak A, Figoli A, Chovau S, Galiano F, Simone S, Vankelecom IFJ, Drioli E, Van der Bruggen B, J. Colloid Interface Sci., 316(1), 254 (2010)
Zentou H, Abidin ZZ, Yunus R, Biak DRA, Issa MA, J. Appl. Polym. Sci., 138(19), 50408 (2020)
Zhan X, Wang M, Gao T, Lu J, He Y, Li J, Sep. Purif. Technol., 236, 116238 (2020)
Ye L, Wang L, Jie X, Yu C, Kang G, Cao Y, J. Membr. Sci., 595, 117540 (2020)
Tsai HA, Ye YL, Lee KR, Huang SH, Suen MC, Lai JY, J. Membr. Sci., 368(1-2), 254 (2011)
Suhas DP, Aminabhavi TM, Raghu AV, Polym. Eng. Sci., 54(8), 1774 (2014)
Zhang H, Wang Y, AIChE J., 62(5), 1728 (2016)
Penkova AV, Dmitrenko ME, Savon NA, Missyul AB, Mazur AS, Kuzminova AI, Zolotarev AA, Mikhailovskii V, Lahderanta E, Markelov DA, Sep. Purif. Technol., 204, 1 (2018)
Lin YF, Ho JC, Lin KYA, Tung KL, Chung TW, Lee CC, Sep. Purif. Technol., 221, 325 (2019)
Cai W, Cheng X, Chen X, Li J, Pei J, ACS Omega, 5(12), 6277 (2020)
