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Received February 16, 2022
Accepted June 25, 2022
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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The improvement effect of surfactants on hydrogenation at condition containing water for Cu/SiO2 catalysts
1College of Chemistry, Chemical Engineering and Materials Science, Zaozhuang University, Zaozhuang 277160, Shandong, China 2College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, China
chenzhengtt@163.com
Korean Journal of Chemical Engineering, November 2022, 39(11), 2983-2990(8), 10.1007/s11814-022-1215-z
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Abstract
In the industrial production, water exists inevitably into feed stocks in the form of impurity, and it can produce a negative effect in the hydrogenation reaction due to the preferential adsorption of water on active sites. Here, the surfactants (polyvinylpyrrolidone, poloxamer, polyethylene glycol and hexadecyl trimethyl ammonium bromide) are used to improve physicochemical property of Cu/SiO2 catalysts, so that Cu/SiO2 catalysts had a good hydrogenation performance at condition containing water. The appropriate addition amount of surfactants in the catalyst preparation process effectively hindered the agglomeration of copper species by steric configuration and repulsion effect between Cu2+ and positive ionizable, which brought about high copper dispersion and small particle size. Meanwhile, the decomposition of surfactants produced many pores during calcination, resulting in the increased of specific surface area and average pore diameter. These advantages provided more chances for reactants to touch active sites due to spatial restriction and the increase of the number of active sites, so that the negative effects of water can be counteracted. The conversion of Cu/SiO2 catalysts, that the surfactants was added in the catalyst preparation process, increased 60% to 200% at reaction condition containing water.
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References
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