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Received March 25, 2022
Accepted May 7, 2022
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Synthesis of polyethylenimine-modified magnetic hydrogel nanocomposite absorbents for heavy metals removal
1State Key Lab of Geohazard Prevention & Geoenvironment Protection, Chengdu University of Technology, Chengdu 610059, Sichuan, China 2Mineral Resources Chemistry Key Laboratory of Sichuan Higher Education Institutions, Chengdu University of Technology, Chengdu 610059, Sichuan, China
wantaos@126.com
Korean Journal of Chemical Engineering, November 2022, 39(11), 3138-3145(8), 10.1007/s11814-022-1168-2
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Abstract
Polyethylenimine(PEI)-modified magnetic hydrogel nanocomposite absorbents (PEI-mHNAs) were fabricated based on poly(acrylamide-co-acrylic acid) and PEI-modified magnetic nanoparticles by radical copolymerization. FTIR and XRD results preliminarily confirmed the target structure of PEI-mHNAs without destroying the structure of magnetic nanoparticles during modification and radical copolymerization. PEI-mHNAs with many rough porous and interstitial structure had high adsorption capacity of Cu(II) (217mg/g), Cd(II) (232mg/g) and Pb(II) (459mg/g). PEI-mHNAs had the best absorption capacity for heavy metal ions in the synthesis condition of acrylic acid/acrylamide mass ratio of 60 : 40, 0.8% initiator, AA neutralization degree of 70%, 0.75% crosslinker, and 15% PEImodified magnetic nanoparticles. Moreover, PEI-mHNAs had good magnetic responsiveness, high thermal stability and reusability, which make it a potential application in removing heavy metal ions from the contaminated wastewater.
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Kumar PS, Senthamarai C, Durgadevi A, Environ. Prog. Sustain. Energy, 33, 28 (2014)
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Yin CY, Aroua MK, Daud WMAW, Water Air Soil Pollut., 192, 337 (2008)
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Li J, Zuo KM, Wu WB, Xu ZY, Yi YG, Jing Y, Dai HQ, Fang GG, Carbohydr. Polym., 196, 376 (2018)
Zheng W, Kuchukulla RR, Xu XN, Zhang DD, Zhou LH, Zeng QL, J. Polym. Environ., 30, 653 (2022)
