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Received February 14, 2022
Accepted August 10, 2022
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Dynamic simulation and control of a triple column process for dimethyl carbonate-methanol separation
Department of Mechanical Engineering, North University of China, No. 3 Xueyuan Road, Taiyuan, Shanxi, 030051, China 1Shanxi Province Key Laboratory of Higee-Oriented Chemical Engineering, North University of China, No. 3 Xueyuan Road, Taiyuan, Shanxi, 030051, China 2Low Carbon Energy Conversion Technology Research Center, Chinese Academy of Science, Shanghai, 201203, P. R. China, Chad
jwz0306@126.com
Korean Journal of Chemical Engineering, December 2022, 39(12), 3190-3203(14), 10.1007/s11814-022-1259-0
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Abstract
Separation of dimethyl carbonate/methanol azeotropic mixture by using pressure-swing distillation process has been a hot-point in the study of the synthesis process of dimethyl carbonate by urea methanolysis method. This study updates the work of the writers (Ind.Eng.Chem.Res,2013,52,11463-11478), which explores the dynamic control structure of the three-column separation dimethyl carbonate (DMC)/methanol (MeOH) process from an actual pilot plant. At first, the conventional DMC/MeOH separation process in the pilot test of the DMC synthesis process through alcoholysis of urea was described in detail. Then an optimized control structure for the entire DMC/MeOH separation unit was obtained by implementing a general heuristic design procedure. An economic analysis was performed to evaluate the optimized process. Finally, three dynamic control schemes were proposed and evaluated with several large disturbances, an improved control scheme CS3, using the multiplier blocks “QR1/F1” and “RR1” in T1, “QR1/F1” and “R/F” in both T2 and T3, outperformed CS1 and CS2 by maintaining the product specification in each column.
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