Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received February 28, 2022
Accepted June 29, 2022
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Heavy metal removal from aqueous solution by granular hydrated Portland cement
1Key Laboratory of Northwest Water Resource, Environment and Ecology, Xi'an University of Architecture and Technology, Xi'an 710055, P. R. China 2Shaanxi Key Laboratory of Environmental Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, P. R. China 3Xi'an Botanical Garden, Xi'an 710061, Shaanxi Province, P. R. China
Korean Journal of Chemical Engineering, December 2022, 39(12), 3350-3360(11), 10.1007/s11814-022-1219-8
Download PDF
Abstract
Granular hydrated Portland cement (HPC) was prepared as adsorbent to remove heavy metals in aqueous solution. Batch experiment results confirmed that heavy metals were removed through a combination of adsorption and precipitation. Adsorption played a more important role in the initial stage of the removal process or at lower concentrations of the heavy metals. After adsorption equilibrium was obtained in two days, the removal process continued for about three days due to the precipitation. Besides precipitation, the maximum Langmuir adsorption capacity reached 132.27, 87.14, 123.43 and 112.05mg/g for Pb, Cu, Zn, and Cd, respectively. When various heavy metals coexisted, the removal capacity followed the order of Cu>Pb>Cd>Zn. The adsorption on the surfaces of HPC was mainly governed by surface precipitation and Ca2+ exchange, as suggested by XRD, SEM-EDS and released Ca2+ results. Most of the adsorbed heavy metals on the HPC and the precipitation formed in the liquid phase were stable under neutral and alkaline conditions. Overall, HPC particles exhibited a large potential for heavy metal removal. When cement-related materials containing HPC are employed for heavy metal removal, the dissolution of the precipitate at low pH might facilitate the migration of the heavy metals.
References
Carolin CF, Kumar PS, Saravanan A, Joshiba GJ, Naushad M, J. Environ. Chem. Eng., 5, 2782 (2017)
Mnasri-Ghnimi S, Frini-Srasra N, Appl. Clay Sci., 179, 105151 (2019)
Wadhawan S, Jain A, Nayyar J, Mehta SK, J. Water Process Eng., 33, 101038 (2020)
Fu F, Wang Q, J. Environ. Manage., 92, 407 (2011)
Bolisetty S, Peydayesh M, Mezzenga R, Chem. Soc. Rev., 48, 463 (2019)
Huang L, He M, Chen B, Hu B, J. Mater. Chem. A, 4, 5159 (2016)
Efome JE, Rana D, Matsuura T, Lan CQ, Sci. Total Environ., 674, 355 (2019)
Mukherjee R, Bhunia P, De S, Chem. Eng. J., 292, 284 (2016)
Chang Q, Zhang M, Wang J, J. Hazard. Mater., 169, 621 (2009)
Gomravi Y, Karimi A, Azimi H, Korean J. Chem. Eng., 38, 1843 (2021)
Uddin MK, Chem. Eng. J., 308, 438 (2017)
Yanagisawa H, Matsumoto Y, Machida M, Appl. Surf. Sci., 256, 1619 (2010)
Ray PZ, Shipley HJ, RSC Adv., 5, 29885 (2015)
Fiyadh SS, AlSaadi MA, Jaafar WZ, AlOmar MK, Fayaed SS, Mohd NS, Hin LS, El-Shafie A, J. Clean Prod., 230, 783 (2019)
Da’na E, Microporous Mesoporous Mater., 247, 145 (2017)
Shao N, Tang S, Liu Z, Li L, Yan F, Liu F, Li S, Zhang Z, ACS Sustain. Chem. Eng., 6, 14926 (2018)
Mancini A, Wieland E, Geng G, Dähn R, Skibsted J, Wehrli B, Lothenbach B, Appl. Geochem., 113, 104460 (2020)
Guo B, Sasaki K, Hirajima T, Cem. Concr. Res., 100, 166 (2017)
Martemianov D, Xie BB, Yurmazova T, Khaskelberg M, Wang F, Wei CH, Preis S, J. Environ. Chem. Eng., 5, 3930 (2017)
Ok YS, Yang JE, Zhang YS, Kim SJ, Chung DY, J. Hazard. Mater., 147, 91 (2007)
Kumara GMP, Kawamoto K, Saito T, Hamamoto S, Asamoto S, J. Environ. Eng.-ASCE, 145, 04019078 (2019)
Shabalala AN, Ekolu SO, Diop S, Solomon F, J. Hazard. Mater., 323, 641 (2017)
Holmes RR, Hart ML, Kevern JT, J. Contam. Hydrol., 196, 52 (2017)
Ali ZTA, Naji LA, Almuktar SAAAN, Faisal AAH, Abed SN, Scholz M, Naushad M, Ahamad T, J. Water Process Eng., 33, 101033 (2020)
Zayat ME, Elagroudy S, Haggar SE, Water Sci. Technol., 70, 1011 (2014)
Amin AEEAZ, Selmy SAH, Commun. Soil Sci. Plant Anal., 48, 1301 (2017)
Staunton J, Williams CD, Morrison L, Henry T, Fleming GTA, Gormally MJ, Land Use Policy, 49, 43 (2015)
Rahman MA, Imteaz MA, Arulrajah A, Piratheepan J, Disfani MM, J. Clean Prod., 90, 183 (2015)
Rahman MA, Imteaz MA, Arulrajah A, Disfani MM, Horpibulsuk S, J. Environ. Eng.-ASCE, 141, 04015019 (2015)
Gill LW, Ring P, Higgins NMP, Johnston PM, Ecol. Eng., 70, 133 (2014)
Gill LW, Ring P, Casey B, Higgins NMP, Johnston PM, Sci. Total Environ., 601, 32 (2017)
Mondal M, Ray AK, Adsorption, 26, 387 (2020)
Guan W, Ji F, Chen Q, Yan P, Zhang Q, Ceram. Int., 39, 1385 (2013)
Monier M, Ayad DM, Wei Y, Sarhan AA, J. Hazard. Mater., 177, 962 (2010)
Gupta SS, Bhattacharyya KG, J. Environ. Manage., 87, 46 (2008)
Zhang H, Tong Z, Wei T, Tang Y, Desalination, 276, 103 (2011)
Nguyen TC, Loganathan P, Nguyen TV, Vigneswaran S, Kandasamy J, Naidu R, Chem. Eng. J., 270, 393 (2015)
Niu M, Li G, Cao L, Wang X, Wang W, J. Clean Prod., 256, 120700 (2020)
Mitrogiannis D, Psychoyou M, Baziotis I, Inglezakis VJ, Koukouzas N, Tsoukalas N, Palles D, Kamitsos E, Oikonomou G, Markou G, Chem. Eng. J., 320, 510 (2017)
Singh NB, Nagpal G, Agrawal S, Rachna, Environ. Technol. Innov., 11, 187 (2018)
Zhao J, Liu J, Li N, Wang W, Nan J, Zhao Z, Cui F, Chem. Eng. J., 304, 737 (2016)
Cho H, Oh D, Kim K, J. Hazard. Mater., 127, 187 (2005)
Chen Q, Yao Y, Li X, Lu J, Zhou J, Huang Z, J. Water Process Eng., 26, 289 (2018)
Srivastava P, Singh B, Angove M, J. Colloid Interface Sci., 290, 28 (2005)
Liu C, Bai R, Ly QS, Water Res., 42, 1511 (2008)
Chen X, Guo Y, Ding S, Zhang H, Xia F, Wang J, Zhou M, J. Clean Prod., 207, 789 (2019)
Wang Y, Li ZW, Huang B, Jiang WG, Guo L, Huang JQ, Zeng GM, J. Cent. South Univ., 22, 1269 (2015)
Zhang J, Zhao H, Cao H, Li H, Li Z, J. Environ. Sci., 25, 1719 (2013)
Trezza MA, Mater. Res., 10, 331 (2007)
dos Reis GS, Thue PS, Cazacliu BG, Lima EC, Sampaio CH, Quattrone M, Ovsyannikova E, Kruse A, Dotto GL, J. Clean Prod., 256, 120416 (2020)
Mandaliev P, Dähn R, Tits J, Wehrli B, Wieland E, J. Colloid Interface Sci., 342, 1 (2010)
Mnasri-Ghnimi S, Frini-Srasra N, Appl. Clay Sci., 179, 105151 (2019)
Wadhawan S, Jain A, Nayyar J, Mehta SK, J. Water Process Eng., 33, 101038 (2020)
Fu F, Wang Q, J. Environ. Manage., 92, 407 (2011)
Bolisetty S, Peydayesh M, Mezzenga R, Chem. Soc. Rev., 48, 463 (2019)
Huang L, He M, Chen B, Hu B, J. Mater. Chem. A, 4, 5159 (2016)
Efome JE, Rana D, Matsuura T, Lan CQ, Sci. Total Environ., 674, 355 (2019)
Mukherjee R, Bhunia P, De S, Chem. Eng. J., 292, 284 (2016)
Chang Q, Zhang M, Wang J, J. Hazard. Mater., 169, 621 (2009)
Gomravi Y, Karimi A, Azimi H, Korean J. Chem. Eng., 38, 1843 (2021)
Uddin MK, Chem. Eng. J., 308, 438 (2017)
Yanagisawa H, Matsumoto Y, Machida M, Appl. Surf. Sci., 256, 1619 (2010)
Ray PZ, Shipley HJ, RSC Adv., 5, 29885 (2015)
Fiyadh SS, AlSaadi MA, Jaafar WZ, AlOmar MK, Fayaed SS, Mohd NS, Hin LS, El-Shafie A, J. Clean Prod., 230, 783 (2019)
Da’na E, Microporous Mesoporous Mater., 247, 145 (2017)
Shao N, Tang S, Liu Z, Li L, Yan F, Liu F, Li S, Zhang Z, ACS Sustain. Chem. Eng., 6, 14926 (2018)
Mancini A, Wieland E, Geng G, Dähn R, Skibsted J, Wehrli B, Lothenbach B, Appl. Geochem., 113, 104460 (2020)
Guo B, Sasaki K, Hirajima T, Cem. Concr. Res., 100, 166 (2017)
Martemianov D, Xie BB, Yurmazova T, Khaskelberg M, Wang F, Wei CH, Preis S, J. Environ. Chem. Eng., 5, 3930 (2017)
Ok YS, Yang JE, Zhang YS, Kim SJ, Chung DY, J. Hazard. Mater., 147, 91 (2007)
Kumara GMP, Kawamoto K, Saito T, Hamamoto S, Asamoto S, J. Environ. Eng.-ASCE, 145, 04019078 (2019)
Shabalala AN, Ekolu SO, Diop S, Solomon F, J. Hazard. Mater., 323, 641 (2017)
Holmes RR, Hart ML, Kevern JT, J. Contam. Hydrol., 196, 52 (2017)
Ali ZTA, Naji LA, Almuktar SAAAN, Faisal AAH, Abed SN, Scholz M, Naushad M, Ahamad T, J. Water Process Eng., 33, 101033 (2020)
Zayat ME, Elagroudy S, Haggar SE, Water Sci. Technol., 70, 1011 (2014)
Amin AEEAZ, Selmy SAH, Commun. Soil Sci. Plant Anal., 48, 1301 (2017)
Staunton J, Williams CD, Morrison L, Henry T, Fleming GTA, Gormally MJ, Land Use Policy, 49, 43 (2015)
Rahman MA, Imteaz MA, Arulrajah A, Piratheepan J, Disfani MM, J. Clean Prod., 90, 183 (2015)
Rahman MA, Imteaz MA, Arulrajah A, Disfani MM, Horpibulsuk S, J. Environ. Eng.-ASCE, 141, 04015019 (2015)
Gill LW, Ring P, Higgins NMP, Johnston PM, Ecol. Eng., 70, 133 (2014)
Gill LW, Ring P, Casey B, Higgins NMP, Johnston PM, Sci. Total Environ., 601, 32 (2017)
Mondal M, Ray AK, Adsorption, 26, 387 (2020)
Guan W, Ji F, Chen Q, Yan P, Zhang Q, Ceram. Int., 39, 1385 (2013)
Monier M, Ayad DM, Wei Y, Sarhan AA, J. Hazard. Mater., 177, 962 (2010)
Gupta SS, Bhattacharyya KG, J. Environ. Manage., 87, 46 (2008)
Zhang H, Tong Z, Wei T, Tang Y, Desalination, 276, 103 (2011)
Nguyen TC, Loganathan P, Nguyen TV, Vigneswaran S, Kandasamy J, Naidu R, Chem. Eng. J., 270, 393 (2015)
Niu M, Li G, Cao L, Wang X, Wang W, J. Clean Prod., 256, 120700 (2020)
Mitrogiannis D, Psychoyou M, Baziotis I, Inglezakis VJ, Koukouzas N, Tsoukalas N, Palles D, Kamitsos E, Oikonomou G, Markou G, Chem. Eng. J., 320, 510 (2017)
Singh NB, Nagpal G, Agrawal S, Rachna, Environ. Technol. Innov., 11, 187 (2018)
Zhao J, Liu J, Li N, Wang W, Nan J, Zhao Z, Cui F, Chem. Eng. J., 304, 737 (2016)
Cho H, Oh D, Kim K, J. Hazard. Mater., 127, 187 (2005)
Chen Q, Yao Y, Li X, Lu J, Zhou J, Huang Z, J. Water Process Eng., 26, 289 (2018)
Srivastava P, Singh B, Angove M, J. Colloid Interface Sci., 290, 28 (2005)
Liu C, Bai R, Ly QS, Water Res., 42, 1511 (2008)
Chen X, Guo Y, Ding S, Zhang H, Xia F, Wang J, Zhou M, J. Clean Prod., 207, 789 (2019)
Wang Y, Li ZW, Huang B, Jiang WG, Guo L, Huang JQ, Zeng GM, J. Cent. South Univ., 22, 1269 (2015)
Zhang J, Zhao H, Cao H, Li H, Li Z, J. Environ. Sci., 25, 1719 (2013)
Trezza MA, Mater. Res., 10, 331 (2007)
dos Reis GS, Thue PS, Cazacliu BG, Lima EC, Sampaio CH, Quattrone M, Ovsyannikova E, Kruse A, Dotto GL, J. Clean Prod., 256, 120416 (2020)
Mandaliev P, Dähn R, Tits J, Wehrli B, Wieland E, J. Colloid Interface Sci., 342, 1 (2010)
