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Received June 8, 2022
Accepted July 19, 2022
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Reactive extraction evaluation for vanadium (V) removal in the MRDC column using axial dispersion and central composition approach
Department of Energy Engineering, Sharif University of Technology, P. O. Box 11365-8639, Tehran, Iran 1Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, P. O. Box: 11365-8486, Tehran, Iran
Korean Journal of Chemical Engineering, December 2022, 39(12), 3399-3411(13), 10.1007/s11814-022-1239-4
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Abstract
Reactive extraction development was investigated to extract vanadium ions from sulfate solution in the modified rotating disc column (MRDC). It was found from batch experiments that D2EHPA and TBP concentrations, initial aqueous phase pH, and the concentration of NH4OH as a stripping agent were optimized equal to 0.3M, 0.36 M, 2, and 1M, respectively. In the continuous experiments, the effects of rotor speed, aqueous and organic phase flow rates, and mass transfer direction were investigated on the dispersed phase holdup, mass transfer coefficients, and vanadium extraction. The experiment design was based on the response surface design to analyze the dependence of responses with the input parameters. The uncertainty analysis by the Monte Carlo simulation indicates that the rotor speed, reaction conditions, and phase flow rates affected the dispersed phase holdup. By applying the axial dispersion model, the performance of mass transfer coefficients in terms of agitation speed, aqueous phase flow rate, organic phase flow rate, and mass transfer direction was evaluated under the chemical reaction system. A new model by considering the dimensionless numbers has been provided to predict overall mass transfer data based on the dispersed phase.
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References
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Torab-Mostaedi M, Asadollahzadeh M, Safdari J, Chin. J. Chem. Eng., 25, 288 (2017)
Torkaman R, Torab-Mostaedi M, Safdari J, Moosavian SMA, Asadollahzadeh M, Iranian J. Chem. Chem. Eng., 36, 145 (2017)
Amanabadi M, Bahmanyar H, Zarkeshan Z, Mousavian MA, Chin. J. Chem. Eng., 17, 366 (2009)
Hemmati A, Shirvani M, Torab-Mostaedi M, Ghaemi A, Chem. Eng. Process., 100, 19 (2016)
Torab-Mostaedi M, Safdari J, Ghannadi-Maragheh M, Moosavian MA, J. Chem. Eng. Jpn., 42, 78 (2009)
Torab-Mostaedi M, Safdari J, Brazilian J. Chem. Eng., 26, 685 (2009)
Tuzen M, Kazi TG, Citak D, Soylak M, J. Anal. Atomic Spect., 28, 1441 (2013)
Truong HT, Nguyen TH, Lee MS, Hydrometallurgy, 171, 298 (2017)
Zeng L, Cheng CY, Hydrometallurgy, 101, 141 (2010)
Shi Q, Zhang Y, Huang J, Liu T, Liu H, Wang L, Sep. Purif. Technol., 181, 1 (2017)
Nayak AK, Devi N, Sarangi K, Trans. Indian Inst. Met., 74, 3155 (2021)
Li XB, Wei C, Wu J, Li CX, Li MT, Deng ZG, Xu HS, Trans. Nonferrous Met. Soc. China, 22, 461 (2012)
Liu H, Zhang YM, Huang J, Liu T, Luo DS, Sep. Purif. Technol., 215, 335 (2019)
Zhu Z, Tulpatowicz K, Pranolo Y, Cheng CY, Hydrometallurgy, 154, 72 (2015)
Yaftian MR, Almeida MIGS, Cattrall RW, Kolev SD, J. Membr. Sci., 545, 57 (2018)
Hu G, Chen D, Wang L, Liu JC, Zhao H, Liu Y, Qi T, Zhang C, Yu P, Sep. Purif. Technol., 125, 59 (2014)
Li X, Wei C, Deng Z, Li M, Li C, Fan G, Hydrometallurgy, 105, 359 (2011)
Tavakoli MR, Dreisinger DB, Hydrometallurgy, 141, 17 (2014)
Remya PN, Reddy ML, J. Chem. Eng. Biotechnol., 79, 434 (2004)
Asadollahzadeh M, Ghaemi A, Torab-Mostaedi M, Shahhosseini S, Chin. J. Chem. Eng., 24, 989 (2016)
Ettouney R, El-Rifai M, Chem. Eng. Res. Des., 89, 2228 (2011)
Asadollahzadeh M, Torkaman R, Torab-Mostaedi M, Saremi M, Inter. J. Heat Mass Trans., 188, 122638 (2022)
Asadollahzadeh M, Hemmati A, Torab-Mostaedi M, Shirvani M, Ghaemi A, Mohsenzadeh Z, Chin. J. Chem. Eng., 25, 53 (2017)
Murugesan T, Regupathi I, J. Chem. Eng. Jpn., 37, 1293 (2004)
Jia‐Wen Z, Shou‐Hua Z, Xiao‐Kui Z, Xiao‐Xiang C, Yuan‐Fu S, Vogelpohl A, Chem. Eng. Technol., 14, 167 (1991)
Chen X, Li K, Su Y, Ind. Eng. Chem. Res., 32, 453 (1993)
Hendre NV, Venkatasubramani V, Farakte RA, Patwardhan AW, Ind. Eng. Chem. Res., 57, 1630 (2018)
Kadam B, Joshi J, Patil R, Chem. Eng. Res. Des., 87, 756 (2009)
Hendre NV, Hinge SP, Patwardhan AW, Ind. Eng. Chem. Res., 60, 5945 (2021)
Porto A, Sarubbo L, Lima-Filho J, Aires-Barros M, Cabral J, Tambourgi E, Bioprocess Eng., 22, 215 (2000)
Coimbra JS, Mojola F, Meirelles AJ, J. Chem. Eng. Jpn., 31, 277 (1998)
Carneiro-da-Cunha M, Aires-Barros M, Tambourgi E, Cabral J, Biotechnol. Tech., 8, 413 (1994)
Hemmati A, Ghaemi A, Asadollahzadeh M, Sep. Sci. Technol., 57, 225 (2022)
Shakib B, Torkaman R, Torab-Mostaedi M, Saremi M, Asadollahzadeh M, Chem. Eng. Process., 171, 108762 (2022)
Asadollahzadeh M, Torkaman R, Torab-Mostaedi M, Chem. Eng. Process., 169, 108608 (2021)
Torkaman R, Rovais MRA, Heydari M, Torab-Mostaedi M, Asadollahzadeh M, Prog. Nucl. Energy, 147, 104217 (2022)
Shakib B, Torkaman R, Torab-Mostaedi M, Asadollahzadeh M, Inter. J. Heat Mass Trans., 185, 122337 (2022)
Asadollahzadeh M, Torkaman R, Torab-Mostaedi M, Saremi M, Sci. Rep., 12, 1609 (2022)
Hemmati A, Ghaemi A, Asadollahzadeh M, Sep. Sci. Technol., 56, 2734 (2020)
Shakib B, Ghaemi A, Hemmati A, Asadollahzadeh M, Prog. Nucl. Energy, 141, 103969 (2021)
Gröber H, Var Z, Dtsch. Ing., 69, 705 (1925)
Kronig R, Brink J, Appl. Sci. Res., 2, 142 (1951)
Handlos A, Baron T, AIChE J., 3, 127 (1957)
Johnson AI, Hamielec A, AIChE J., 6, 145 (1960)
Kumar A, Hartland S, Ind. Eng. Chem. Res., 35, 2682 (1996)
Wilke C, Chang P, AIChE J., 1, 264 (1955)
Torab-Mostaedi M, Ghaemi A, Asadollahzadeh M, Chem. Eng. Res. Des., 89, 2742 (2011)
Danckwerts PV, Chem. Eng. Sci., 2, 1 (1953)
Pratt H, Stevens G, Science and practise of liquid-liquid extraction, Clarendon Press, Oxford (1992).
Shakib B, Torkaman R, Torab-Mostaedi M, Asadollahzadeh M, Inter. Commun. Heat Mass Trans., 118, 104903 (2020)
Shakib B, Torkaman R, Torab-Mostaedi M, Asadollahzadeh M, Chem. Pap., 74, 4295 (2020)
Macdonald I, Strachan P, Energy Build., 33, 219 (2001)
Boyadzhiev L, Elenkov D, Kyuchukov G, Can. J. Chem. Eng., 47, 42 (1969)
Steiner L, Chem. Eng. Sci., 41, 1979 (1986)
Hemmati A, Torab-Mostaedi M, Asadollahzadeh M, Chem. Eng. Res. Des., 93, 747 (2015)
Asadollahzadeh M, Shahhosseini S, Torab-Mostaedi M, Ghaemi A, Chem. Eng. Res. Des., 100, 104 (2015)
Bahmanyar H, Nazari L, Sadr A, Chem. Eng. Process., 47, 57 (2008)
Torab‐Mostaedi M, Ghaemi A, Asadollahzadeh M, Can. J. Chem. Eng., 90, 1570 (2012)
Steiner L, Kumar A, Hartland S, Can. J. Chem. Eng., 66, 241 (1988)
Rahbar A, Azizi Z, Bahmanyar H, Moosavian MA, Can. J. Chem. Eng., 89, 508 (2011)
Shakib B, Torab-Mostaedi M, Outokesh M, Asadollahzadeh M, Heat Mass Transf., 56, 1995 (2020)
Torab-Mostaedi M, Asadollahzadeh M, Safdari J, Chin. J. Chem. Eng., 25, 288 (2017)
Torkaman R, Torab-Mostaedi M, Safdari J, Moosavian SMA, Asadollahzadeh M, Iranian J. Chem. Chem. Eng., 36, 145 (2017)
Amanabadi M, Bahmanyar H, Zarkeshan Z, Mousavian MA, Chin. J. Chem. Eng., 17, 366 (2009)
Hemmati A, Shirvani M, Torab-Mostaedi M, Ghaemi A, Chem. Eng. Process., 100, 19 (2016)
Torab-Mostaedi M, Safdari J, Ghannadi-Maragheh M, Moosavian MA, J. Chem. Eng. Jpn., 42, 78 (2009)
Torab-Mostaedi M, Safdari J, Brazilian J. Chem. Eng., 26, 685 (2009)