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Received October 18, 2021
Accepted September 14, 2022
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Phase equilibria and thermodynamic properties in the o-dichlorobenzene - m-dichlorobenzene system
Chemistry Department, Lomonosov Moscow State University, 119991 Moscow, Russian Federation 1PJSC Gazprom (“TransGasTomsk”), 634029 Tomsk, Russian Federation
samukovv@mail.ru
Korean Journal of Chemical Engineering, December 2022, 39(12), 3412-3421(10), 10.1007/s11814-022-1291-0
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Abstract
Rankine cycle is widely used in industry to convert heat to work using a working fluid. A mixture of oand m-isomers of dichlorobenzene can act efficiently as a working fluid in the cycle. An equation of state (EoS) approach was chosen to model vapor-liquid equilibria and phase properties in the system. The best results were achieved with Tsai-Chen EoS. Experimental measurements of volumetric properties of mixtures and solid-liquid equilibria were performed. These data were correctly predicted within the ideal assumption. An enthalpy-pressure diagram for the odichlorobenzene - m-dichlorobenzene system was calculated using the resulting EoS.
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Sekar J, Naidu P, Acree JW, J. Chem. Eng. Data, 38, 167 (1993)
Yadava SS, Singh S, Bhan R, Yadav N, Korean J. Chem. Eng., 28, 256 (2011)
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Baragi JG, Aralaguppi MI, Aminabhavi TM, Kariduraganavar MY, Kulkarni SS, J. Chem. Eng. Data, 50, 917 (2005)
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Raju R, Ravikumar S, Sivakumar K, Raveendra M, Pandiyan V, Chem. Data Collect., 17-18, 41 (2018)
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Syamala V, Sekhar D, Sivakumar K, Venkateswarlu P, Phys. Chem. Liq. An Int. J., 48, 171 (2010)
Ramanjaneyulu K, Krishnaiah A, Ramakrishna M, Fluid Phase Equilib., 40, 311 (1988)
Bhatia SC, Sangwan J, Rani R, Bhatia R, Int. J. Thermophys., 32, 2027 (2011)
Góralski P, Piekarski H, J. Chem. Eng. Data, 52, 655 (2007)
Reddy PM, Siva K, Venkatesu P, Fluid Phase Equilib., 310, 74 (2011)
Mato MM, Balseiro J, Salgado J, Jime E, Legido L, Pin MM, De Ciencias F, Corun EA, J. Chem. Eng. Data, 47, 4 (2002)
Chand GP, Sankar MG, Rani PNVVLP, Rambabu C, J. Mol. Liq., 201, 1 (2015)
Rao PV, Krishna TS, Gowri M, Ravindhranath K, J. Mol. Liq., 222, 873 (2016)
Syamala V, Kumar KS, Venkateswarlu P, J. Chem. Thermodyn., 38, 1553 (2006)
Syamala V, Venkatramana L, Rao CN, Sivakumar K, Venkateswarlu P, Gardas RL, Fluid Phase Equilib., 397, 68 (2015)
Vasundhara P, Rao CN, Venkatramana L, Sivakumar K, Venkateswarlu P, Gardas RL, J. Mol. Liq., 202, 158 (2015)
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Kumar VC, Sreenivasulu B, Naidu PR, J. Chem. Eng. Data, 38, 414 (1993)
Rajasekar J, Naidu PR, J. Chem. Eng. Data, 41, 373 (1996)
Rajasekhar J, Sivakumar K, Fluid Phase Equilib., 245, 149 (2006)
Vogel A, J. Chem. Soc., 644 (1948)
McDonald R, Shrader S, Stull D, J. Chem. Eng. Data, 4, 311 (1959)
Grayson BT, Fosbraey LA, Pestic. Sci., 13, 269 (1982)
Liu K, Dickhut RM, Chemosphere, 29, 581 (1994)
Fisk CF, Noyes WA, J. Am. Chem. Soc., 58, 1707 (1936)
Stull DR, Ind. Eng. Chem., 39, 517 (1947)
Dreisbach RR, Shrader SA, Ind. Eng. Chem., 41, 2879 (1949)
Poledníček M, Guetachew T, Jose J, Růžička V, Roháč V, Zábranský M, Int. Electron. J. Physico-Chemical Data, 2, 41 (1996)
Roháč V, Růžička V, Růžička K, Aim K, J. Chem. Eng. Data, 43, 770 (1998)
Mackay D, Shiu WY, Ma KC, Lee SC, Handbook of physical- chemical properties and environmental fate for organic chemicals: Volume I: Introduction and hydrocarbons, CRC Press, Boca Raton (2006).
Verevkin SP, Emel’yanenko VN, Varfolomeev MA, Solomonov BN, Zherikova KV, Melkhanova SV, J. Phys. Chem. B, 118, 14479 (2014)
Tanaka R, Benson GC, J. Chem. Eng. Data, 24, 37 (1979)
Lipovská M, Schmidt HG, Roháč V, Růžička V, Wolf G, Zábranský M, J. Therm. Anal. Calorim., 68, 753 (2002)
Roháč V, Růžička V, Růžička K, Poledníček M, Aim K, Jose J, Zábranský M, Fluid Phase Equilib., 157, 121 (1999)
Acree WE, Thermochim. Acta, 189, 37 (1991)
Wei D, Thermochim. Acta, 479, 32 (2008)
Timmermans J, Bull. Soc. Chim. Belg., 44, 17 (1935)
Narbutt J, Z. Elektrochem., 24, 339 (1918)
Domańska U, Letcher TM, J. Chem. Thermodyn., 32, 1635 (2000)
Donnelly JR, Drewes LA, Johnson RL, Munslow WD, Knapp KK, Sovocool GW, Thermochim. Acta, 167, 155 (1990)
Witschonke CR, Anal. Chem., 26, 562 (1954)
Basařová P, Svoboda V, Fluid Phase Equilib., 68, 13 (1991)
Stephenson RM, Malanowski S, Handbook of the thermodynamics of organic compounds, Elsevier, New York (1987).
Physical Property Data Bank. Appendix C.
Kalluru R, Abburi K, Fluid Phase Equilib., 40, 311 (1988)
Soave G, Chem. Eng. Sci., 27, 1197 (1972)
Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)
Gmehling J, Kleiber M, Kolbe B, Rarey J, Chemical thermodynamics for process simulation, 2nd ed., Wiley, New Jersey (2019).
Péneloux A, Rauzy E, Fréze R, Fluid Phase Equilib., 8, 7 (1982)
Young F, Pessoa FLP, Ahόn VRR, Fluid Phase Equilib., 435, 73 (2017)
Tsai JC, Chen YP, Fluid Phase Equilib., 145, 193 (1998)
Whitson CH, Brulé M, Phase behavior, Henry L. Doherty Memorial Fund of AIME, Society of Petroleum Engineers, Richardson (2000).
https://www.e-education.psu.edu/png520/.
Ding MS, Xu K, Jow TR, J. Therm. Anal. Calorim., 62, 177 (2000)
