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Received April 4, 2022
Accepted May 23, 2022
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Effective separation of Zn, Fe, and Mn from roasting-water leaching solution of blast-furnace dust using a precipitation-solvent extraction process
1Civil and Resource Engineering School, University of Science and Technology Beijing, Beijing 100083, China 2Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China 3, China 4University of Chinese Academy of Sciences, Beijing 100049, China
jjrng0906@163.com
Korean Journal of Chemical Engineering, December 2022, 39(12), 3442-3451(10), 10.1007/s11814-022-1185-1
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Abstract
Selective extraction of Zn from blast furnace dust can be achieved by the ammonium sulfate roasting-water leaching process. An innovative method for effective separation of Zn, Fe, and Mn from roasting-water leaching solution of blast-furnace dust by precipitation-solvent extraction process is proposed in this research. The Fe of leaching solution was selectively converted into FePO4·2H2O precipitate by using Na2HPO4 as precipitant. The precipitation efficiency of Fe reached 99.17%, while that of Zn was only 0.20% under the solution pH of 2.2, molar ratio of Na2HPO4 to Fe of 1.2 : 1, reaction temperature of 30 ℃, and reaction time of 50 min. The zinc in the filtrate was extracted with Cyanex 302, and Zn (99.94%) was extracted through two-stage countercurrent extraction under initial pH of 3.4, Cyanex 302 concentration of 25%, and O/A of 2 : 1. Subsequently, Zn (99.96%) of the organic phase was stripped using 0.75 mol/L sulfuric acid by one-stage countercurrent stripping. Furthermore, according to thermodynamic calculation, it is proved that extracting Zn from sulfuric acid solution with Cyanex 302 is an exothermic reaction. The proposed process flowsheet may be used to efficiently recover Zn and Fe from blast-furnace dust.
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