Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received April 21, 2021
Accepted August 8, 2021
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Optimization of synergistic green emulsion liquid membrane stability for enhancement of silver recovery from aqueous solution
Norela Jusoh1 2
Norasikin Othman1 2†
Raja Norimie Raja Sulaiman1 2
Norul Fatiha Mohamed Noah1
Muhammad Abbas Ahmad Zaini1 2
1School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia 2Centre of Lipids Engineering and Applied Research (CLEAR), Ibnu Sina Institute for Scientific and Industrial Research (ISI-SIR), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
Korean Journal of Chemical Engineering, February 2022, 39(2), 423-430(8), 10.1007/s11814-021-0921-2
Download PDF
Abstract
The emulsion liquid membrane (ELM) process for silver recovery containing synergistic Cyanex 302/Cyanex 272 carriers, palm oil as a diluent, acidic thiourea as a stripping agent, and sorbitan monooleate (Span 80) as a surfactant was attempted. A suitable range of mixed carrier concentration on the facilitated extraction performance of silver was first determined. Response surface methodology (RSM) was applied to optimize and evaluate the effect of mixed carrier concentration, stripping agent concentration, and treat ratio on the stability of the process. The results showed that the system was stable with no breakage or swelling. At the optimum condition of 8.26/12.39mM Cyanex 302/Cyanex 272, 1.27 M acidic thiourea, and 0.62 treat ratio, the silver extraction performance and recovery were 97% and 54% (4.33 times enrichment), respectively. Further modification of the process and addition of 5% w/v of modifier resulted in 6.57 times enrichment, which accounted for 82% of the silver recovery. Hence, this study shows the capability of silver recovery using a synergistic ELM process and potential to be applied in industrial effluent.
Keywords
References
Tang B, Yu GJ, Fang JZ, Shi TH, J. Hazard. Mater., 177(1-3), 377 (2010)
Jeon C, Korean J. Chem. Eng., 34(2), 384 (2017)
Liu C, Fiol N, Poch J, Villaescusa I, J. Water Process Eng., 11, 143 (2016)
Scarazzato T, Panossian Z, Tenorio JAS, Perez-Herranz V, Espinosa DCR, J. Clean Prod., 168, 1590 (2017)
Kobya M, Demirbas E, Ozyonar F, Sirtbas G, Gengec E, Process Saf. Environ. Prot., 105, 373 (2017)
Gielen B, Silver plating industry effluent, https://www.finishing.com/433/21.shtml (2006).
Mesli M, Belkhouche NE, Chem. Eng. Res. Des., 129, 160 (2018)
Gupta S, Khandale PB, Chakraborty M, J. Dispersion Sci. Technol., 41, 393 (2020)
Wu M, He HY, Xu F, Xu ZG, Zhang WJ, He ZY, Qu J, Chi R, Huang LY, Sep. Purif. Technol., 212, 255 (2019)
Guimaraes AS, Silva LA, Pereira AM, Correia JCG, Mansur MB, Sep. Purif. Technol., 239, 116570 (2020)
Sulaiman RNR, Rahman HA, Othman N, Rosly MB, Jusoh N, Noah NFM, Korean J. Chem. Eng., 37(1), 141 (2020)
Duan HP, Wang SX, Yang XJ, Yuan XH, Zhang Q, Huang ZJ, Guo H, Chem. Eng. Res. Des., 117, 460 (2017)
Hu J, Zou D, Chen J, Li D, Sep. Purif. Technol., 233, 115977 (2020)
Chang SH, Desalin. Water Treat., 52, 88 (2014)
Moyo F, Tandlich R, J. Biorem. Biodegrad., 5, 228 (2014)
Sulaiman RNR, Othman N, Saidina Amin NA, J. Ind. Eng. Chem., 20(5), 3243 (2014)
Kumar A, Thakur A, Panesar PS, Rev. Environ. Sci. Biotechnol., 18, 153 (2019)
Keyvani M, Davarpanah L, Vahabzadeh F, Korean J. Chem. Eng., 31(9), 1681 (2014)
Rosly MB, Jusoh N, Othman N, Rahman HA, Noah NFM, Sulaiman RNR, Chem. Eng. Res. Des., 145, 268 (2019)
Park HN, Cho CW, Choi HA, Won SW, Korean J. Chem. Eng., 34(9), 2519 (2017)
Inyang V, Lokhat D, Sep. Sci. Technol., 1 (2021).
Jusoh N, Othman N, Sulaiman RNR, Noah NFM, Kamarudin KSN, J. Membr. Sci. Res., 7, 59 (2021)
Jusoh N, Sulaiman RNR, Othman N, Noah NFM, Rosly MB, Rahman HA, Food Bioprod. Process., 119, 161 (2020)
Peng W, Jiao HP, Shi HC, Xu CJ, Desalination, 286, 372 (2012)
Kumbasar RA, J. Ind. Eng. Chem., 18(1), 145 (2012)
Ichlas ZT, Ibana DC, Int. J. Miner. Metall. Mater., 24, 37 (2017)
Rasouli M, Yaghobi N, Gilani SZM, Atashi H, Rasouli M, Chin. J. Chem. Eng., 23(1), 64 (2015)
Benyahia N, Belkhouche N, Jonsson JA, J. Environ. Chem. Eng., 2, 1756 (2014)
Olushola S, Folahan A, Alafara A, Bhekumusa J, Olalekan S, Int. J. Phy. Sci., 8, 89 (2013)
Goyal RK, Jayakumar NS, Hashim MA, J. Hazard. Mater., 195, 383 (2011)
Mortaheb HR, Amini MH, Sadeghian F, Mokhtarani B, Daneshyar H, J. Hazard. Mater., 160(2-3), 582 (2008)
Fabrega FDM, Mansur MB, Hydrometallurgy, 87, 83 (2007)
Abbassian K, Kargari A, J. Environ. Chem. Eng., 4, 3926 (2016)
Nguyen TH, Hoa NVN, Metals, 10, 1 (2020)
Ooi ZY, Harruddin N, Othman N, Biotechnol. Progr., 31, 1305 (2015)
El-Nadi YA, Int. J. Miner. Process., 82(1), 14 (2007)
Kumar A, Thakur A, Panesar PS, J. Ind. Eng. Chem., 70, 394 (2019)
Gaikwad S, Pandit A, Ultrason. Sonochem., 15, 554 (2008)
Ammar SH, Attia HG, Affat AKD, FCNES, 1 (2012).
Jeon C, Korean J. Chem. Eng., 34(2), 384 (2017)
Liu C, Fiol N, Poch J, Villaescusa I, J. Water Process Eng., 11, 143 (2016)
Scarazzato T, Panossian Z, Tenorio JAS, Perez-Herranz V, Espinosa DCR, J. Clean Prod., 168, 1590 (2017)
Kobya M, Demirbas E, Ozyonar F, Sirtbas G, Gengec E, Process Saf. Environ. Prot., 105, 373 (2017)
Gielen B, Silver plating industry effluent, https://www.finishing.com/433/21.shtml (2006).
Mesli M, Belkhouche NE, Chem. Eng. Res. Des., 129, 160 (2018)
Gupta S, Khandale PB, Chakraborty M, J. Dispersion Sci. Technol., 41, 393 (2020)
Wu M, He HY, Xu F, Xu ZG, Zhang WJ, He ZY, Qu J, Chi R, Huang LY, Sep. Purif. Technol., 212, 255 (2019)
Guimaraes AS, Silva LA, Pereira AM, Correia JCG, Mansur MB, Sep. Purif. Technol., 239, 116570 (2020)
Sulaiman RNR, Rahman HA, Othman N, Rosly MB, Jusoh N, Noah NFM, Korean J. Chem. Eng., 37(1), 141 (2020)
Duan HP, Wang SX, Yang XJ, Yuan XH, Zhang Q, Huang ZJ, Guo H, Chem. Eng. Res. Des., 117, 460 (2017)
Hu J, Zou D, Chen J, Li D, Sep. Purif. Technol., 233, 115977 (2020)
Chang SH, Desalin. Water Treat., 52, 88 (2014)
Moyo F, Tandlich R, J. Biorem. Biodegrad., 5, 228 (2014)
Sulaiman RNR, Othman N, Saidina Amin NA, J. Ind. Eng. Chem., 20(5), 3243 (2014)
Kumar A, Thakur A, Panesar PS, Rev. Environ. Sci. Biotechnol., 18, 153 (2019)
Keyvani M, Davarpanah L, Vahabzadeh F, Korean J. Chem. Eng., 31(9), 1681 (2014)
Rosly MB, Jusoh N, Othman N, Rahman HA, Noah NFM, Sulaiman RNR, Chem. Eng. Res. Des., 145, 268 (2019)
Park HN, Cho CW, Choi HA, Won SW, Korean J. Chem. Eng., 34(9), 2519 (2017)
Inyang V, Lokhat D, Sep. Sci. Technol., 1 (2021).
Jusoh N, Othman N, Sulaiman RNR, Noah NFM, Kamarudin KSN, J. Membr. Sci. Res., 7, 59 (2021)
Jusoh N, Sulaiman RNR, Othman N, Noah NFM, Rosly MB, Rahman HA, Food Bioprod. Process., 119, 161 (2020)
Peng W, Jiao HP, Shi HC, Xu CJ, Desalination, 286, 372 (2012)
Kumbasar RA, J. Ind. Eng. Chem., 18(1), 145 (2012)
Ichlas ZT, Ibana DC, Int. J. Miner. Metall. Mater., 24, 37 (2017)
Rasouli M, Yaghobi N, Gilani SZM, Atashi H, Rasouli M, Chin. J. Chem. Eng., 23(1), 64 (2015)
Benyahia N, Belkhouche N, Jonsson JA, J. Environ. Chem. Eng., 2, 1756 (2014)
Olushola S, Folahan A, Alafara A, Bhekumusa J, Olalekan S, Int. J. Phy. Sci., 8, 89 (2013)
Goyal RK, Jayakumar NS, Hashim MA, J. Hazard. Mater., 195, 383 (2011)
Mortaheb HR, Amini MH, Sadeghian F, Mokhtarani B, Daneshyar H, J. Hazard. Mater., 160(2-3), 582 (2008)
Fabrega FDM, Mansur MB, Hydrometallurgy, 87, 83 (2007)
Abbassian K, Kargari A, J. Environ. Chem. Eng., 4, 3926 (2016)
Nguyen TH, Hoa NVN, Metals, 10, 1 (2020)
Ooi ZY, Harruddin N, Othman N, Biotechnol. Progr., 31, 1305 (2015)
El-Nadi YA, Int. J. Miner. Process., 82(1), 14 (2007)
Kumar A, Thakur A, Panesar PS, J. Ind. Eng. Chem., 70, 394 (2019)
Gaikwad S, Pandit A, Ultrason. Sonochem., 15, 554 (2008)
Ammar SH, Attia HG, Affat AKD, FCNES, 1 (2012).
