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Received May 7, 2021
Accepted August 25, 2021
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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A RuO2IrO2 electrocatalyst with an optimal composition and novelmicrostructure for oxygen evolving in the single cell
Feng Ye
Yanpeng Cao
Weiwei Han1
Yakun Yang
Yuancheng Feng
Peng Liu
Chao Xu†
Xiaoze Du
Woochul Yang1
Guicheng Liu1†
Key Laboratory of Power Station Energy Transfer Conversion and System of MOE, North China Electric Power University, Beijing 102206, P. R. China 1Department of Physics, Dongguk University, Seoul 04620, Korea
mechx@ncepu.edu.cn, log67@163.com
Korean Journal of Chemical Engineering, March 2022, 39(3), 596-604(9), 10.1007/s11814-021-0942-x
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Abstract
A highly active RuO2IrO2 electrocatalyst was developed via dip-coating/calcination method for oxygen evolution reaction (OER). The catalyst on Ti substrate with a 7/3 molar ratio between Ru and Ir showed the highest electrocatalytic activity for OER among composite samples in different molar ratios. Moreover, the properties of RuO2IrO2 grown on carbon paper were evaluated by proton exchange membrane water electrolysis single cell. Compared with the micron-particle structure of RuO2IrO2 catalyst on the Ti substrate, the catalyst grown on the carbon paper showed a novel nano dendrite shape and can be used directly as the gas diffusion electrode. Owing to the large surface area of the catalyst, the nano dendrite-shaped RuO2IrO2 catalyst exhibits excellent OER performance in the single cell. Furthermore, a cell voltage of 2.50 V is achieved under 200mA cm-2 at 30°C by using the optimal composition RuO2IrO2(Ru : Ir=7/3) and the commercial 20% Pt/C as anode and cathode, respectively.
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Terezo AJ, Pereira EC, Electrochim. Acta, 44(25), 4507 (1999)
Da Silva LA, Alves VA, Trasatti S, Boodts JFC, J. Electroanal. Chem., 427(1-2), 97 (1997)
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