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Received May 30, 2021
Accepted September 26, 2021
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Preparation of chromium fumarate metal-organic frameworks for removal of pharmaceutical compounds from water
Engineering Faculty, Department of Chemical Engineering, Istanbul University-Cerrahpaşa, 34320, Avcılar, Istanbul, Turkey 1Engineering Faculty, Department of Chemical Engineering, Istanbul University-Cerrahpasa, 34320, Avcılar, Istanbul, Turkey, Korea 2Faculty of Engineering & Architecture, Department of Chemical Engineering, Beykent University, Istanbul, 34396, Sarıyer, Turkey
Korean Journal of Chemical Engineering, March 2022, 39(3), 638-645(8), 10.1007/s11814-021-0966-2
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Abstract
Pharmaceutical pollution in water is the major cause of antibiotic resistance, so remediation of water from pharmaceuticals is a very important issue. Different methods are used for this purpose, with adsorption as one of the most preferred. Different adsorbents have been used for water treatment processes. Metal-organic frameworks that have highly porous structures have gained attention in the last decades. In this study, novel chromium fumarate (Cr-Fum) was prepared, and the efficiency of Cr-Fum was tested by ciprofloxacin (CPX) adsorption. Cr-Fum was prepared under reflux and characterized by scanning electron microscopy (SEM), X-ray diffraction spectroscopy (XRD),_x000D_
Fourier transform infrared spectroscopy (FTIR), thermal analysis (TGA), and differential scanning calorimetry (DSC). The general approach of the process was monolayer adsorption at low temperature and heterogeneous adsorption at high temperature. 2.5mg of adsorbent was adsorbed 4.97mg/g and 11.47% of CPX. 10mg of Cr-Fum was adsorbed 0.82mg/g and 7.27% of CPX. Partition coefficients were calculated and 0.07mg/g/?M was found at 298 K. The reaction followed pseudo-first- and pseudo-second-order kinetic models. Thermodynamic analysis showed that the reaction is spontaneous and exothermic. Additional ions caused decreasing CPX adsorption, but this study showed that Cr-Fum has NaCl adsorption capacity. In future studies, NaCl adsorption should be investigated. Desorption studies were applied to Cr-Fum after the adsorption processes. 0.1M NaOH and phosphate buffer (pH=7.4) solution were used as desorption eluents. The desorption period was chosen as 6 h. NaOH solution desorbed 67.38% of CPX at first cycle and buffer solution desorbed 26.87% of CPX at second cycle.
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