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Received March 29, 2021
Accepted August 12, 2021
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Cellulose-type binder enabling CuCl2 supported on nanoporous bayeriteto have high CO adsorption ability via reduction of Cu2+ to Cu+
Jungsu Kim1 2
Kanghee Cho1 3
Taesung Jung1 3
Hee Tae Beum1 3
Jong-ho Park1 3
Young Woo Rhee2†
Sang Sup Han1 3†
1Climate Change Research Division, Korea Institute of Energy Research, 152 Gajeong-ro, Yuseong-gu, Daejeon 34129, Korea 2Graduate School of Energy Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Korea 3, Korea
Korean Journal of Chemical Engineering, March 2022, 39(3), 684-694(11), 10.1007/s11814-021-0928-8
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Abstract
Previously, we developed a powder-form nanoporous CO-selective adsorbent synthesized via thermal_x000D_
monolayer dispersion of CuCl on bayerite, showing high CO adsorption capacity (48.5 cm3g-1) and a high CO/CO2 selectivity (12.4). For its industrial applications, it is necessary to pelletize it, avoiding pressure-drop problems. Here, we demonstrate a facile three-step method of pelletizing a CuCl/bayerite: 1) physical mixing of CuCl, methyl-cellulose, inorganic-binder, and bayerite, 2) pelletizing, and 3) thermal treatment at 573 K under vacuum. The pelletized adsorbent shows high CO adsorption capacity (42 cm3g-1), CO/CO2 selectivity (12), and commercial-level mechanical_x000D_
strength (1.3 kgf). Notably, the added methyl-cellulose binder has reducing role that maintains the initial CO adsorption capacity for 100 days’ exposure to humid air-condition, although CuCl-based adsorbent easily lost CO adsorption ability owing to oxidation of Cu+ to Cu2+. CuCl2, showing no specific interaction with CO, was converted to Cu+ by the methyl-cellulose. Thus, adsorbent prepared using CuCl2 instead of CuCl with the methyl-cellulose also showed high CO adsorption capacity (31.6 cm3 g-1) and maintained the initial capacity after seven days’ exposure. The reducing role_x000D_
of the methyl-cellulose binder allows inexpensive and feasible synthesis of the CO-adsorbent using CuCl2 that can be easily dispersed on bayerite, without additional reduction treatment.
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Jim?nez JA, J. Alloys Compd., 656, 685 (2016)
Klupfel L, Keiluweit M, Kleber M, Sander M, Environ. Sci. Technol., 48, 5601 (2014)
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