Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received June 23, 2021
Accepted August 30, 2021
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Integrating advanced Keggin-structure polyoxometalate into polymeric membrane to enhance photocatalytic self-cleaning and antifouling functionalities
Daniel Chin Hao Koo1
Nee Nee Tan1
Qi Hwa Ng2
2†
Siti Kartini Enche Ab Rahim2
2†
Siew Chun Low3
Ryan Yow Zhong Yeo1
1Faculty of Chemical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Perlis, Malaysia 2Frontier Materials Research, Centre of Excellence (FrontMate), Universiti Malaysia Perlis (UniMAP), Perlis, Malaysia 3School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, Seri Ampangan, 14300 Nibong Tebal, S.P.S., Penang, Malaysia
Korean Journal of Chemical Engineering, April 2022, 39(4), 1045-1052(8), 10.1007/s11814-021-0945-7
Download PDF
Abstract
The high photocatalytic activity of environmentally benign Keggin-type polyoxometalate (POM) was introduced into polyethersulfone (PES) membrane to promote membrane anti-fouling and self-cleaning functionality. Neat PES and POM/PES hybrid membranes were synthesized via phase inversion method. X-ray diffraction (XRD) and attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectroscopy proved the success of synthesizing Keggin-type POM. The traits of the membranes were evaluated using scanning electron microscopy (SEM), ATRFTIR, contact angle measurement, porosity and porometer. The hydrophilicity of all the POM/PES hybrid membranes was enhanced and resulted in the reduction of contact angle of the membrane (52.21±0.1101°, 45.11±0.6657° and 50.30±0.1054°) for 0.025, 0.05 and 0.1wt% POM/PES hybrid membranes, respectively, compared to that of the neat PES membrane (57.30±0.0817°). Additionally, all the POM/PES hybrid membranes showed excellent anti-fouling and self-cleaning characteristics as compared to that of the neat PES membrane. 0.05 wt% POM/PES hybrid membrane outstood all the other membranes, which marks the HA rejection at 77.12% and was able to achieve flux recovery ratio (FRR) of 111.34% with temporal superhydrophilicity effect in just merely 150 seconds at 254 nm UV irradiation.
Keywords
References
Ayati A, Shahrak MN, Tanhaei B, Sillanpää M, Chemosphere, 160, 30 (2016)
Padhi RK, Subramanian S, Mohanty AK, Satpathy KK, J. Water Process Eng., 29, 100769 (2019)
Javdaneh S, Mehrnia MR, Homayoonfal M, Korean J. Chem. Eng., 32, 1 (2016)
Yang Y, Qiao S, Jin R, Zhou J, Quan X, Korean J. Chem. Eng., 35, 964 (2018)
Li X, Fang X, Pang R, Li J, Sun X, Shen J, Han W, Wang L, J. Membr. Sci., 467, 226 (2014)
Zinadini S, Zinatizadeh AA, Rahimi M, Vatanpour V, Zangeneh H, J. Membr. Sci., 453, 292 (2014)
Pang R, Li X, Li J, Lu Z, Sun X, Wang L, Desalination, 332, 60 (2014)
Omwoma S, Gore CT, Ji Y, Hu C, Song YF, Coord. Chem. Rev., 286, 17 (2015)
Liu CG, Zheng T, Liu S, Zhang HY, J. Mol. Struct., 1110, 44 (2016)
Aouissi A, Al-Deyab SS, Al-Owais A, Al-Amro A, Int. J. Mol. Sci., 11, 2770 (2010)
Briand LE, Thomas HJ, Baronetti GT, Appl. Catal. A: Gen., 201, 191 (2000)
Liu S, Liu Y, Jiang S, Liu S, He D, Li N, Miao J, Ye J, J. Environ. Chem. Eng., 4, 908 (2016)
Zhang Z, Ma H, Pang H, Zhang C, Chai D, Hou Y, J. Solid State Chem., 258, 170 (2018)
Sampurnam S, Muthamizh S, Dhanasekaran T, Latha D, Padmanaban A, Selvam P, Stephen A, Narayanan V, J. Photochem. Photobiol. A-Chem., 370, 26 (2019)
Zangeneh H, Zinatizadeh AA, Zinadini S, Feyzi M, Bahnemann DW, Sep. Purif. Technol., 209, 764 (2019)
Zhao X, Xuan H, Chen Y, He C, J. Membr. Sci., 494, 48 (2015)
El-Naggar MR, Aglan RF, Sayed MS, J. Environ. Chem. Eng., 1, 516 (2013)
Qu P, Tang H, Gao Y, Zhang L, Wang S, Bioresources, 5, 2323 (2010)
Garcia-Ivars J, Iborra-Clar MI, Alcaina-Miranda MI, Mendoza-Roca JA, Pastor-Alcañiz L, Chem. Eng. J., 283, 231 (2016)
Kusworo TD, Utomo DP, J. Environ. Chem. Eng., 5, 6077 (2017)
Djoko T, Ariyanti N, Puji D, J. Water Process Eng., 35, 101190 (2020)
Fuad AK, Enche SK, Rahim AB, Int. J. Curr. Res. Sci. Eng. Technol., 1, 300 (2018)
Méricq JP, Mendret J, Brosillon S, Faur C, Chem. Eng. Sci., 123, 283 (2015)
Yang Y, Zhang H, Wang P, Zheng Q, Li J, J. Membr. Sci., 288, 231 (2007)
Younas H, Bai H, Shao J, Han Q, Ling Y, He Y, J. Membr. Sci., 541, 529 (2017)
Munshi AM, Singh VN, Kumar M, Singh JP, J. Appl. Phys., 103, 084315 (2008)
Hobbs C, Taylor J, Hong S, J. Water Supply Res. T., 55, 559 (2006)
Subramaniam MN, Goh PS, Sevgili E, Karaman M, Lau WJ, Ismail AF, Eur. Polym. J., 122, 109360 (2020)
Hoek EMV, Bhattacharjee S, Elimelech M, Langmuir, 19, 4836 (2003)
Fathizadeh M, Xu WL, Zhou F, Yoon Y, Yu M, Adv. Mater. Interfaces, 1600918, 1 (2017)
Fang G, Liu J, Yan X, Wang D, Israr J, Xue T, Adv. Mater. Interfaces, 1800844, 1 (2018)
Clavería-Cádiz F, Arratia-Pérez R, MacLeod-Carey D, Polyhedron, 117, 478 (2016)
Mendret J, Hatat-Fraile M, Rivallin M, Brosillon S, Sep. Purif. Technol., 111, 9 (2013)
Zangeneh H, Zinatizadeh AA, Zinadini S, Feyzi M, Bahnemann DW, React. Funct. Polym., 127, 139 (2018)
Song H, Shao J, He Y, Liu B, Zhong X, J. Membr. Sci., 405-406, 48 (2012)
Padhi RK, Subramanian S, Mohanty AK, Satpathy KK, J. Water Process Eng., 29, 100769 (2019)
Javdaneh S, Mehrnia MR, Homayoonfal M, Korean J. Chem. Eng., 32, 1 (2016)
Yang Y, Qiao S, Jin R, Zhou J, Quan X, Korean J. Chem. Eng., 35, 964 (2018)
Li X, Fang X, Pang R, Li J, Sun X, Shen J, Han W, Wang L, J. Membr. Sci., 467, 226 (2014)
Zinadini S, Zinatizadeh AA, Rahimi M, Vatanpour V, Zangeneh H, J. Membr. Sci., 453, 292 (2014)
Pang R, Li X, Li J, Lu Z, Sun X, Wang L, Desalination, 332, 60 (2014)
Omwoma S, Gore CT, Ji Y, Hu C, Song YF, Coord. Chem. Rev., 286, 17 (2015)
Liu CG, Zheng T, Liu S, Zhang HY, J. Mol. Struct., 1110, 44 (2016)
Aouissi A, Al-Deyab SS, Al-Owais A, Al-Amro A, Int. J. Mol. Sci., 11, 2770 (2010)
Briand LE, Thomas HJ, Baronetti GT, Appl. Catal. A: Gen., 201, 191 (2000)
Liu S, Liu Y, Jiang S, Liu S, He D, Li N, Miao J, Ye J, J. Environ. Chem. Eng., 4, 908 (2016)
Zhang Z, Ma H, Pang H, Zhang C, Chai D, Hou Y, J. Solid State Chem., 258, 170 (2018)
Sampurnam S, Muthamizh S, Dhanasekaran T, Latha D, Padmanaban A, Selvam P, Stephen A, Narayanan V, J. Photochem. Photobiol. A-Chem., 370, 26 (2019)
Zangeneh H, Zinatizadeh AA, Zinadini S, Feyzi M, Bahnemann DW, Sep. Purif. Technol., 209, 764 (2019)
Zhao X, Xuan H, Chen Y, He C, J. Membr. Sci., 494, 48 (2015)
El-Naggar MR, Aglan RF, Sayed MS, J. Environ. Chem. Eng., 1, 516 (2013)
Qu P, Tang H, Gao Y, Zhang L, Wang S, Bioresources, 5, 2323 (2010)
Garcia-Ivars J, Iborra-Clar MI, Alcaina-Miranda MI, Mendoza-Roca JA, Pastor-Alcañiz L, Chem. Eng. J., 283, 231 (2016)
Kusworo TD, Utomo DP, J. Environ. Chem. Eng., 5, 6077 (2017)
Djoko T, Ariyanti N, Puji D, J. Water Process Eng., 35, 101190 (2020)
Fuad AK, Enche SK, Rahim AB, Int. J. Curr. Res. Sci. Eng. Technol., 1, 300 (2018)
Méricq JP, Mendret J, Brosillon S, Faur C, Chem. Eng. Sci., 123, 283 (2015)
Yang Y, Zhang H, Wang P, Zheng Q, Li J, J. Membr. Sci., 288, 231 (2007)
Younas H, Bai H, Shao J, Han Q, Ling Y, He Y, J. Membr. Sci., 541, 529 (2017)
Munshi AM, Singh VN, Kumar M, Singh JP, J. Appl. Phys., 103, 084315 (2008)
Hobbs C, Taylor J, Hong S, J. Water Supply Res. T., 55, 559 (2006)
Subramaniam MN, Goh PS, Sevgili E, Karaman M, Lau WJ, Ismail AF, Eur. Polym. J., 122, 109360 (2020)
Hoek EMV, Bhattacharjee S, Elimelech M, Langmuir, 19, 4836 (2003)
Fathizadeh M, Xu WL, Zhou F, Yoon Y, Yu M, Adv. Mater. Interfaces, 1600918, 1 (2017)
Fang G, Liu J, Yan X, Wang D, Israr J, Xue T, Adv. Mater. Interfaces, 1800844, 1 (2018)
Clavería-Cádiz F, Arratia-Pérez R, MacLeod-Carey D, Polyhedron, 117, 478 (2016)
Mendret J, Hatat-Fraile M, Rivallin M, Brosillon S, Sep. Purif. Technol., 111, 9 (2013)
Zangeneh H, Zinatizadeh AA, Zinadini S, Feyzi M, Bahnemann DW, React. Funct. Polym., 127, 139 (2018)
Song H, Shao J, He Y, Liu B, Zhong X, J. Membr. Sci., 405-406, 48 (2012)
