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Received July 16, 2021
Accepted October 10, 2021
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Effect of Fe nanoparticle-loaded sawdust carbon on catalytic pyrolysis of heavy oil
1College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, 610500, P. R. China 2State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, 610500, P. R. China
txda429@163.com
Korean Journal of Chemical Engineering, April 2022, 39(4), 1078-1085(8), 10.1007/s11814-021-0978-y
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Abstract
This work was focused on the synthesis and characterization of iron nanoparticle loaded sawdust carbon (Fe/SC) by low cost green synthesis approach and its application for catalytic pyrolysis of heavy oil. Fourier transform infrared (FT-IR), X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma optical emission spectrometer (ICP-OES) methods were used to analyze the catalyst of Fe/SC. The properties of heavy oil before and after reaction were characterized by SARA analysis, FT-IR, gas chromatography-mass spectrometry (GCMS) and thermogravimetric analysis (TGA). The experimental results showed that after pyrolytic reaction at 350℃ for 30 min with 0.1 wt% catalyst, the viscosity of heavy oil may decrease by 80.81% with a net efficiency of catalyst of 20.68%. The catalyst of Fe/SC is promising, low cost, high efficiency, highly stable and eco-friendly for catalytic upgrading and viscosity reduction of heavy oil.
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