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Received August 4, 2021
Accepted October 31, 2021
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Melamine sponge-based copper-organic framework (Cu-CPP) as a multi-functional filter for air purifiers
Van Cam Thi Le1 2
Tuu Nguyen Thanh3
Eunsil Kang1 4
Soyeong Yoon1 5
Hien Duy Mai1 2
Mahshab Sheraz1 2
Tae Uk Han6
Jinjoo An7
Seungdo Kim1 2†
1Department of Environmental Sciences and Biotechnology, Hallym University, Chuncheon 24252, Korea 2Nano-InnoTek Corporation, 123, Digital-ro 26-gil, Guro-gu, Seoul 08390, Korea 3Tra Vinh University, 126, Nguyen Thien Thanh Street, Tra Vinh City 87000, Tra Vinh Province, Vietnam 4Research Center for Climate Change and Energy (RCCCE), Hallym University, Chuncheon 24252, Korea 5, Korea 6Environmental Resources Research Department, National Institute of Environmental Research, Hwangyeong-ro 42, Seo-gu, Incheon 22689, Korea 7Process Design and Development Research Center, Korea Research Institute of Chemical Technology, Daejeon 34114, Korea
Korean Journal of Chemical Engineering, April 2022, 39(4), 954-962(9), 10.1007/s11814-021-1000-4
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Abstract
COVID-19 has drawn great attention on the necessity for establishing pathogen-free indoor air. This paper offers an insight into the potential application of a multi-purpose filter to remove fine particulates and disinfect pathogens using melamine sponge with a copper-organic framework. In-situ growth dip coating method was applied to coat Cu-based coordination polymer particle (Cu-CPP) on melamine sponge (MS). The integration of Cu-CPPs with high crystallinity and highly active surface area (1,318.1m2/g) enabled Cu-CPP/MS to have an excellent capture rate (99.66%) and an instant disinfection rate of 99.54% for Escherichia coli. Electrostatic attraction seemed to play a crucial role in capturing negative-charged pathogens effectively by positive charges on Cu-CPP arising from unbalanced copper ions in Cu-CPP. Disinfection of pathogens was mainly attributed to catalytically active Cu2+ sites. Organic ligand played an important role in bridging and maintaining Cu2+ ions within the framework. This study highlights the design of a new capture-and-disinfection (CDS) air filter system for pathogens using Cu-CPP/MS. It can be applied as a substitute for conventional high-efficiency particulate air (HEPA) filters.
Keywords
References
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de Abajo FJG, Hernández RJ, Kaminer I, Meyerhans A, Rosell-Llompart J, Sanchez-Elsner T, ACS Nano, 14, 7704 (2020)
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Oren I, Haddad N, Finkelstein R, Rowe JM, Am. J. Hematol., 66, 257 (2001)
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Maus R, Goppelsröder A, Umhauer H, Atmos. Environ., 35, 105 (2001)
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Perrier JCB, Coq LL, Andrès Y, Cloirec PL, Int. J. Chem. React. Eng., 6, 1 (2008)
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Ding Y, Xu W, Yu Y, Hou H, Zhu Z, ACS Appl. Mater. Interfaces, 10, 6652 (2018)
Deng CH, Gong JL, Zhang P, Zeng GM, Song B, Liu HY, J. Colloid Interface Sci., 488, 26 (2017)
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Kuo CH, Tang Y, Chou LY, Sneed BT, Brodsky CN, Zhao Z, Tsung CK, J. Am. Chem. Soc., 134, 14345 (2012)
Nasrullah A, Khan AS, Bhat AH, Din IU, Inayat A, Muhammad N, Bakhsh EM, Khan SB, Renew. Energy, 168, 723 (2021)
Chen H, Wang L, Yang J, Yang RT, J. Phys. Chem. C, 117, 7565 (2013)
Gao H, Sun P, Zhang Y, Zeng X, Wang D, Zhang Y, Wang W, Wu J, Surf. Coat. Technol., 339, 147 (2018)
Zhou H, Zhang T, Yue X, Peng Y, Qiu F, Yang D, Ind. Eng. Chem. Res., 58, 4844 (2019)
Loera-Serna S, Oliver-Tolentino MA, de Lourdes López- Núñez M, Santana-Cruz A, Guzmán-Vargas A, Cabrera-Sierra R, J. Alloy. Compd., 540, 113 (2012)
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Ma K, Wang Y, Chen Z, Islamoglu T, Lai C, Wang X, Fei B, Farha OK, Xin JH, ACS Appl. Mater. Interfaces, 11, 22714 (2019)
Zhang Y, Yuan S, Feng X, Li H, Zhou J, Wang B, J. Am. Chem. Soc., 138, 5785 (2016)
Li TT, Cen X, Ren HT, Wu L, Peng HK, Wang W, Gao B, Lou CW, Lin JH, ACS Appl. Mater. Interfaces, 12, 8730 (2020)
Li Z, Ma J, Ruan J, Zhuang X, Nanoscale Res. Lett., 14, 195 (2019)
Rauf A, Ye J, Zhang S, Qi Y, Wang G, Che Y, Ning G, Dalton Trans., 48, 17810 (2019)
Kumar R, Münstedt H, Biomaterials, 26, 2081 (2005)
Li B, Li Y, Zhao Y, Sun L, J. Phys. Chem. Solids, 74, 1842 (2013)
Shen M, Forghani F, Kong X, Liu D, Ye X, Chen S, Ding T, Compr. Rev. Food Sci. Food Saf., 19, 1397 (2020)
