Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received August 25, 2021
Accepted October 27, 2021
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Modification of hollow BiOCl/TiO2 nanotubes with phosphoric acid to enhance their photocatalytic performance
Guozhe Sui1 2†
Yulin Zhang1 3
Jinlong Li1 2†
Yan Zhuang1 3
Dongxuan Guo1 2
Ze Luo1 3
Rongping Xu1 3
Shuang Liang1 3
Hong Yao1 3
Chao Wang1 3
1College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, P. R. China 2Heilongjiang Provincial Key Laboratory of Catalytic Synthesis for Fine Chemicals, Qiqihar University, Qiqihar 161006, P. R. China 3, China
gzhsui@qqhru.edu.cn
Korean Journal of Chemical Engineering, April 2022, 39(4), 986-996(11), 10.1007/s11814-021-0997-8
Download PDF
Abstract
Organic pollutants in dyed wastewater are hazardous to human health and the environment. The photocatalytic degradation of pollutants is considered a green treatment with significant social and environmental benefits. In this study, hollow BiOCl/TiO2 nanotubes with open pores at both ends, prepared by hydrothermal synthesis, were modified using phosphoric acid to promote photoelectron transfer. The hollow nanotubes offer an increased number of electroactive sites, which enhances the photoelectric transfer efficiency and reduces the electron-hole recombination rate. The modification by H3PO4 significantly optimized the photocatalytic activity of the nanotubes. The results show that the H3PO4 modified hollow BiOCl/TiO2 (molar ratio of BiOCl to TiO2 is 0.8) nanotubes exhibited the most efficient photocatalytic performance toward rhodamine B (RhB) with a photodegradation efficiency of up to 98.8% under visible-light illumination. These nanotubes have broad application prospects for the effective removal of organic pollutants from wastewater and can potentially inform future research on photocatalysts.
References
Wang H, Hu XT, Ma YJ, Zhu DJ, Li T, Wang JY, Chin. J. Catal., 41, 95 (2020)
Wang C, Sui GZ, Guo DX, Li JL, Zhang L, Li SB, Xin JJ, Chai DF, Guo WX, J. Colloid Interface Sci., 599, 577 (2021)
Farooq U, Sajid M, Shan A, Wang XH, Lyu SG, Chem. Eng. J., 423, 130221 (2021)
Li JL, Jia SQ, Sui GZ, Du LJ, Chem. Pap., 72, 369 (2018)
Ghanbari F, Moradi M, Boca Raton: CRC Press (2016).
Ur Rehman MS, Kim I, Rashid N, Umer MA, Sajid M, Han JI, Clean-Soil Air Water, 44, 55 (2016)
Luna-Sanguino G, Tolosana-Moranchel A, Carbajo J, Pascual L, Rey A, Faraldos M, Bahamonde A, Mol. Catal., 493, 111059 (2020)
Liu HH, Huang J, Chen JF, Zhong JB, Li JZ, Ma DM, Chem. Phys. Lett., 748, 137401 (2020)
Ye LQ, Jin XL, Leng YM, Su YR, Xie HQ, Liu C, J. Power Sources, 293, 409 (2015)
Yu HB, Ge D, Liu YP, Lu Y, Wang XH, Huo MX, Qin WC, Sep. Purif. Technol., 251, 117414 (2020)
Hu XL, Li CQ, Song JY, Zheng SL, Sun ZM, J. Colloid Interface Sci., 574, 61 (2020)
Wang Q, Li PJ, Zhang Z, Jiang CY, Zuojiao KC, Liu JX, Wang YP, J. Photochem. Photobiol. A-Chem., 378, 114 (2019)
Li L, Zhang MY, Liu Y, Zhang XT, J. Colloid Interface Sci., 435, 26 (2014)
Qu XF, Yi YD, Qiao FY, Liu MH, Wang XR, Meng HH, Shi L, Du FL, Ceram. Int., 44, 1348 (2018)
Li HY, Liu JF, Qian JJ, Li QY, Yang JJ, Chin. J. Catal., 35, 1578 (2014)
Li JL, Zhen DS, Sui GZ, Zhang CM, Deng QG, Jia LH, J. Nanosci. Nanotech., 12, 6265 (2012)
Tong X, Shen WH, Chen XQ, Corriou JP, Ceram. Int., 43, 14200 (2017)
Bao SRQQG, Liang HO, Li CP, Bai J, J. Photochem. Photobiol. A-Chem., 397, 112590 (2020)
Sui GZ, Li JL, Liu T, Zhao TT, Hao ZL, Zhen DS, Lv J, Jia LH, Jing T, Mater. Express, 6, 1 (2016)
Li Z, Ma BJ, Zhang XF, Sang YH, Liu H, Environ. Res., 182, 109077 (2019)
Liu HH, Yang C, Huang J, Chen JF, Zhong JB, Li JZ, Inorg. Chem. Commun., 113, 107806 (2020)
Zhang J, Zhu K, Zhu YK, Qin CC, Liu LY, Wang YJ, Gan W, Fu XC, Hao HQ, Chem. Phys. Lett., 750, 137483 (2020)
Tian J, Chen ZY, Jing JP, Feng C, Sun MM, Li WB, Mater. Lett., 272, 127860 (2020)
Zhang GX, Sun ZM, Hu XL, Song AK, Zheng SL, J. Taiwan Inst. Chem. E., 81, 435 (2017)
Alam U, Fleisch M, Kretschmer I, Bahnemann D, Muneer M, Appl. Catal. B: Environ., 218, 758 (2017)
Cheng ZQ, Zhao SZ, Kang LJ, Li MT, Gao ZL, Mater. Lett., 214, 80 (2017)
Yao SJ, Wang J, Zhou XX, Zhou SS, Pu XP, Adv. Powder Technol., 31, 1924 (2020)
Wang Z, Mahmood A, Xie XF, Wang X, Qiu HX, Sun J, Chem. Eng. J., 393, 124723 (2020)
Li JL, Liu T, Sui GZ, Zhen DS, J. Nanosci. Nanotechnol., 15, 1408 (2015)
Liu Q, Ma JF, Wang K, Feng T, Peng MG, Yao ZS, Fan CH, Komarneni S, Ceram. Int., 43, 5751 (2017)
Shen YH, Yu X, Lin WT, Zhu Y, Zhang YM, Appl. Surf. Sci., 399, 67 (2017)
Zhou WM, Wang J, Wang XG, Li JF, Li Y, Wang CW, Opt. Mater., 99, 109567 (2020)
Tian Y, Guo CF, Guo YJ, Wang Q, Liu Q, Appl. Surf. Sci., 258, 1949 (2012)
Jiang Q, Xie WL, Han SY, Wang YF, Zhang Y, Colloids Surf. A: Physicochem. Eng. Asp., 583, 123962 (2019)
Li DW, Wang Y, Zhou JJ, Wang JC, Liu XY, Tian YY, Zhang ZB, Qiao YY, Wei L, Li JH, Wen L, Mater. Lett., 230, 61 (2018)
Zhang ZB, Liu XY, Li DW, Gao TT, Lei YQ, Wu BG, Zhao JW, Wang YK, Wei L, Carbon, 144, 841 (2019)
Fu RR, Zeng XQ, Ma L, Gao SM, Wang QY, Wang ZY, Huang BB, Dai Y, Lu J, J. Power Sources, 312, 12 (2016)
Wang KX, Shao CL, Li XH, Zhang X, Lu N, Miao FJ, Liu YC, Catal. Commun., 67, 6 (2015)
Jia SQ, Li L, Sui GZ, Du LJ, Zhang YL, Zhuang Y, Li BX, RSC Adv., 9, 31177 (2019)
Li JL, Du LJ, Jia SQ, Sui GZ, Zhang YL, Zhuang Y, Li BX, Xing ZY, RSC Adv., 8, 29654 (2018)
Sikora MD, Rosario AV, Pereira EC, Paiva-Santos CO, Electrochim. Acta, 56, 3122 (2011)
Zhang LL, Zhang JH, Zhang WG, Liu JQ, Zhong H, Zhao YJ, Mater. Res. Bull., 66, 109 (2015)
Li JL, Zhuang Y, Sui GZ, Guo DX, Zhang YL, Luo Z, Xu RP, Liang S, Yao H, Ionics, 27, 3185 (2021)
Liu X, He CQ, Yu XJ, Bai YT, Ye L, Wang BS, Zhang LF, Powder Technol., 326, 181 (2018)
Jia ZH, Li T, Zheng ZF, Zhang JD, Liu JX, Wang YW, Zhang XC, Wang YF, Fan CM, Chem. Eng. J., 380, 122422 (2020)
Li JL, Li BX, Sui GZ, Du LJ, Zhuang Y, Zhang YL, Zou YF, J. Mol. Struct., 1231, 130023 (2021)
Wang C, Sui GZ, Guo DX, Li JL, Zhang L, Li SB, Xin JJ, Chai DF, Huang Y, Ionics, 27, 1723 (2021)
Cao BC, Dong PY, Cao S, Wang YH, J. Am. Ceram. Soc., 44, 544 (2013)
Dong F, Xiong T, Yan S, Wang HQ, Sun YJ, Zhang YX, Huang HW, Wu ZB, J. Catal., 344, 401 (2016)
Tang XD, Ma CS, Liu N, Liu CL, Liu SL, Chem. Phys. Lett., 709, 82 (2018)
Giannakis S, Lin KYA, Ghanbari F, Chem. Eng. J., 406, 127083 (2021)
Li JL, Jia SQ, Sui GZ, Du LJ, Li BX, RSC Adv., 7, 34857 (2017)
Mohseni-Bandpei A, Ghasemi SM, Eslami A, Rafiee M, Sadani M, Ghanbari F, J. Photochem. Photobiol. A-Chem., 418, 113425 (2021)
Sui GZ, Li JL, Du LJ, Zhuang Y, Zhang YL, Zou YF, Li BX, Li, J. Alloys
Wang C, Sui GZ, Guo DX, Li JL, Zhang L, Li SB, Xin JJ, Chai DF, Guo WX, J. Colloid Interface Sci., 599, 577 (2021)
Farooq U, Sajid M, Shan A, Wang XH, Lyu SG, Chem. Eng. J., 423, 130221 (2021)
Li JL, Jia SQ, Sui GZ, Du LJ, Chem. Pap., 72, 369 (2018)
Ghanbari F, Moradi M, Boca Raton: CRC Press (2016).
Ur Rehman MS, Kim I, Rashid N, Umer MA, Sajid M, Han JI, Clean-Soil Air Water, 44, 55 (2016)
Luna-Sanguino G, Tolosana-Moranchel A, Carbajo J, Pascual L, Rey A, Faraldos M, Bahamonde A, Mol. Catal., 493, 111059 (2020)
Liu HH, Huang J, Chen JF, Zhong JB, Li JZ, Ma DM, Chem. Phys. Lett., 748, 137401 (2020)
Ye LQ, Jin XL, Leng YM, Su YR, Xie HQ, Liu C, J. Power Sources, 293, 409 (2015)
Yu HB, Ge D, Liu YP, Lu Y, Wang XH, Huo MX, Qin WC, Sep. Purif. Technol., 251, 117414 (2020)
Hu XL, Li CQ, Song JY, Zheng SL, Sun ZM, J. Colloid Interface Sci., 574, 61 (2020)
Wang Q, Li PJ, Zhang Z, Jiang CY, Zuojiao KC, Liu JX, Wang YP, J. Photochem. Photobiol. A-Chem., 378, 114 (2019)
Li L, Zhang MY, Liu Y, Zhang XT, J. Colloid Interface Sci., 435, 26 (2014)
Qu XF, Yi YD, Qiao FY, Liu MH, Wang XR, Meng HH, Shi L, Du FL, Ceram. Int., 44, 1348 (2018)
Li HY, Liu JF, Qian JJ, Li QY, Yang JJ, Chin. J. Catal., 35, 1578 (2014)
Li JL, Zhen DS, Sui GZ, Zhang CM, Deng QG, Jia LH, J. Nanosci. Nanotech., 12, 6265 (2012)
Tong X, Shen WH, Chen XQ, Corriou JP, Ceram. Int., 43, 14200 (2017)
Bao SRQQG, Liang HO, Li CP, Bai J, J. Photochem. Photobiol. A-Chem., 397, 112590 (2020)
Sui GZ, Li JL, Liu T, Zhao TT, Hao ZL, Zhen DS, Lv J, Jia LH, Jing T, Mater. Express, 6, 1 (2016)
Li Z, Ma BJ, Zhang XF, Sang YH, Liu H, Environ. Res., 182, 109077 (2019)
Liu HH, Yang C, Huang J, Chen JF, Zhong JB, Li JZ, Inorg. Chem. Commun., 113, 107806 (2020)
Zhang J, Zhu K, Zhu YK, Qin CC, Liu LY, Wang YJ, Gan W, Fu XC, Hao HQ, Chem. Phys. Lett., 750, 137483 (2020)
Tian J, Chen ZY, Jing JP, Feng C, Sun MM, Li WB, Mater. Lett., 272, 127860 (2020)
Zhang GX, Sun ZM, Hu XL, Song AK, Zheng SL, J. Taiwan Inst. Chem. E., 81, 435 (2017)
Alam U, Fleisch M, Kretschmer I, Bahnemann D, Muneer M, Appl. Catal. B: Environ., 218, 758 (2017)
Cheng ZQ, Zhao SZ, Kang LJ, Li MT, Gao ZL, Mater. Lett., 214, 80 (2017)
Yao SJ, Wang J, Zhou XX, Zhou SS, Pu XP, Adv. Powder Technol., 31, 1924 (2020)
Wang Z, Mahmood A, Xie XF, Wang X, Qiu HX, Sun J, Chem. Eng. J., 393, 124723 (2020)
Li JL, Liu T, Sui GZ, Zhen DS, J. Nanosci. Nanotechnol., 15, 1408 (2015)
Liu Q, Ma JF, Wang K, Feng T, Peng MG, Yao ZS, Fan CH, Komarneni S, Ceram. Int., 43, 5751 (2017)
Shen YH, Yu X, Lin WT, Zhu Y, Zhang YM, Appl. Surf. Sci., 399, 67 (2017)
Zhou WM, Wang J, Wang XG, Li JF, Li Y, Wang CW, Opt. Mater., 99, 109567 (2020)
Tian Y, Guo CF, Guo YJ, Wang Q, Liu Q, Appl. Surf. Sci., 258, 1949 (2012)
Jiang Q, Xie WL, Han SY, Wang YF, Zhang Y, Colloids Surf. A: Physicochem. Eng. Asp., 583, 123962 (2019)
Li DW, Wang Y, Zhou JJ, Wang JC, Liu XY, Tian YY, Zhang ZB, Qiao YY, Wei L, Li JH, Wen L, Mater. Lett., 230, 61 (2018)
Zhang ZB, Liu XY, Li DW, Gao TT, Lei YQ, Wu BG, Zhao JW, Wang YK, Wei L, Carbon, 144, 841 (2019)
Fu RR, Zeng XQ, Ma L, Gao SM, Wang QY, Wang ZY, Huang BB, Dai Y, Lu J, J. Power Sources, 312, 12 (2016)
Wang KX, Shao CL, Li XH, Zhang X, Lu N, Miao FJ, Liu YC, Catal. Commun., 67, 6 (2015)
Jia SQ, Li L, Sui GZ, Du LJ, Zhang YL, Zhuang Y, Li BX, RSC Adv., 9, 31177 (2019)
Li JL, Du LJ, Jia SQ, Sui GZ, Zhang YL, Zhuang Y, Li BX, Xing ZY, RSC Adv., 8, 29654 (2018)
Sikora MD, Rosario AV, Pereira EC, Paiva-Santos CO, Electrochim. Acta, 56, 3122 (2011)
Zhang LL, Zhang JH, Zhang WG, Liu JQ, Zhong H, Zhao YJ, Mater. Res. Bull., 66, 109 (2015)
Li JL, Zhuang Y, Sui GZ, Guo DX, Zhang YL, Luo Z, Xu RP, Liang S, Yao H, Ionics, 27, 3185 (2021)
Liu X, He CQ, Yu XJ, Bai YT, Ye L, Wang BS, Zhang LF, Powder Technol., 326, 181 (2018)
Jia ZH, Li T, Zheng ZF, Zhang JD, Liu JX, Wang YW, Zhang XC, Wang YF, Fan CM, Chem. Eng. J., 380, 122422 (2020)
Li JL, Li BX, Sui GZ, Du LJ, Zhuang Y, Zhang YL, Zou YF, J. Mol. Struct., 1231, 130023 (2021)
Wang C, Sui GZ, Guo DX, Li JL, Zhang L, Li SB, Xin JJ, Chai DF, Huang Y, Ionics, 27, 1723 (2021)
Cao BC, Dong PY, Cao S, Wang YH, J. Am. Ceram. Soc., 44, 544 (2013)
Dong F, Xiong T, Yan S, Wang HQ, Sun YJ, Zhang YX, Huang HW, Wu ZB, J. Catal., 344, 401 (2016)
Tang XD, Ma CS, Liu N, Liu CL, Liu SL, Chem. Phys. Lett., 709, 82 (2018)
Giannakis S, Lin KYA, Ghanbari F, Chem. Eng. J., 406, 127083 (2021)
Li JL, Jia SQ, Sui GZ, Du LJ, Li BX, RSC Adv., 7, 34857 (2017)
Mohseni-Bandpei A, Ghasemi SM, Eslami A, Rafiee M, Sadani M, Ghanbari F, J. Photochem. Photobiol. A-Chem., 418, 113425 (2021)
Sui GZ, Li JL, Du LJ, Zhuang Y, Zhang YL, Zou YF, Li BX, Li, J. Alloys
