ISSN: 0256-1115 (print version) ISSN: 1975-7220 (electronic version)
Copyright © 2024 KICHE. All rights reserved

Articles & Issues

Language
English
Conflict of Interest
In relation to this article, we declare that there is no conflict of interest.
Publication history
Received July 30, 2019
Accepted July 12, 2021
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.

All issues

Viscosity reduction of extra-heavy crude oil using nanocatalysts

Faculty of Chemical Engineering, Tarbiat Modares University, Tehran, Iran
omidkhah@modares.ac.ir
Korean Journal of Chemical Engineering, May 2022, 39(5), 1207-1214(8), 10.1007/s11814-021-0898-x
downloadDownload PDF

Abstract

Exploiting extra-heavy crude oil and converting it to operational products is considered a challenging process in the industry due to the difficulty in processing this kind of crude oil. So, in the present study, viscosity reduction of extra-heavy crude oil is inquired using nanocatalysts. This is the first study that investigates and juxtaposes the results of viscosity reduction of extra-heavy crude oil based on direct heating and microwave radiation as the indirect heating source at the presence of ZSM-5 catalyst as well as silica, clay, and synthesized nickel oxide nanocatalysts in order to facilitate the process of extra-heavy crude oil upgrading. The results illustrate that nanocatalysts have a fundamental impact on the viscosity reduction of extra-heavy crude oil. According to the findings, nanosilica represents the best efficiency among others as it makes a 98.3% reduction in the extra-heavy crude oil viscosity. Besides, the application of microwave radiation in the upgrading of extra-heavy crude oil leads to an incredible reaction duration reduction as approximately 60% of sample oil viscosity is reduced in just 90 seconds. Analysis of upgraded oil reveals that adding excess nanocatalyst to the extra-heavy crude oil actuates an efficiency reduction due to the agglomeration of nanoparticles. Finally, the findings offer appealing information for the enhancement of upgrading processes in the industry.

References

Ghannam MT, Hasan SW, Abu-Jdayil B, Esmail NJ, J. Pet. Sci. Eng., 81, 122 (2012)
Alboudwarej H, Felix J, Taylor S, Badry R, Bremner C, Brough B, Skeates C, Baker A, Palmer D, Pattison K, Oilfield Rev., 18, 34 (2006)
Oil Market Report in International Energy Agency (2010).
Doust AM, Rahimi M, Feyzi M, Iran. J. Chem. Eng., 13, 3 (2016)
Chuan W, Guang-Lun L, Yao CJ, Sun KJ, Gai PY, Cao YB, J. Fuel Chem. Technol., 38, 684 (2010)
Rahimi N, Karimzadeh R, Appl. Catal. A: Gen., 398, 1 (2011)
Clark PD, Kirk MJ, Energy Fuels, 8, 380 (1994)
Ovalles C, Filgueiras E, Morales A, Scott CE, Gonzalez-Gimenez F, Embaid BP, Fuel, 82, 887 (2003)
Jia H, Zhao JZ, Pu WF, Zhao J, Kuang XYJE, Fuels, 26, 1575 (2012)
Jia H, Zhao JZ, Pu WF, Liao R, Wang LLJES, Energy Sources Part A-Recovery Util. Environ. Eff., 34, 877 (2012)
Jia H, Liu PG, Pu WF, Ma XP, Zhang J, Gan LJPS, Pet. Sci., 13, 476 (2016)
Farsi A, Mansouri SS, Res. Chem. Intermed., 38, 1871 (2012)
Farsi A, Mansouri SS, Arab. J. Chem., 9, 28 (2016)
Wei L, Zhu JH, Qi JH, J. Fuel Chem. Technol., 35, 176 (2007)
Chen Y, Wang Y, Lu J, Wu C, Fuel, 88, 1426 (2009)
Tarboush BJA, Husein MM, J. Colloid Interface Sci., 378, 64 (2012)
Liu X, Yang Z, Li X, Zhang Z, Zhao M, Su C, Micro Nano Lett, 10, 167 (2015)
Li K, Hou B, Wang L, Cui Y, Nano Lett., 14, 3002 (2014)
Thomas SJ, Oil Gas Sci. Technol., 63, 9 (2008)
Jackson C, Upgrading a heavy oil using variable frequency microwave energy, in: SPE International Thermal Operations and Heavy Oil Symposium and International Horizontal Well Technology Conference, SPE (2002).
Greff J, Babadagli T, Catalytic effects of nano-size metal ions in breaking asphaltene molecules during thermal recovery of heavy-oil, in: SPE Annual Technical Conference and Exhibition, SPE (2011).
Jeon SG, Kwak NS, Rho NS, Ko CH, Na JG, Yi KB, Park SB, Chem. Eng. Res. Des., 90, 1292 (2012)
da Silva ASV, Weinschutz R, Yamamoto CI, Luz LF, Fuel, 106, 632 (2013)
Greff J, Babadagli T, Use of nano-metal particles as catalyst under electromagnetic heating for viscosity reduction of heavy oil, in: International Petroleum Technology Conference, IPTC (2011).
Bera A, Babadagli T, J. Pet. Sci. Eng., 153, 244 (2017)
Labuza T, Meister JJ, E. Energy, 27, 205 (1992)
Dehkordi JA, Jafari A, Sabet SA, Karami F, Chin. J. Chem. Eng., 26, 343 (2018)
Dorosti F, Omidkhah M, Pedram M, Moghadam F, Chem. Eng. Sci., 171, 1469 (2011)
Maghzi A, Mohammadi S, Ghazanfari MH, Kharrat R, Masihi MJ, F. Science, 40, 168 (2012)

The Korean Institute of Chemical Engineers. F5, 119, Anam-ro, Seongbuk-gu, 233 Spring Street Seoul 02856, South Korea.
TEL. No. +82-2-458-3078FAX No. +82-507-804-0669E-mail : kiche@kiche.or.kr

Copyright (C) KICHE.all rights reserved.

- Korean Journal of Chemical Engineering 상단으로