Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received April 16, 2021
Accepted October 19, 2021
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
The effect of chitosan (CS) coagulation bath on structure and performance of polylactic acid (PLA) microfiltration membrane
Department of Chemical Engineering, Changchun University of Technology, 2055 Yanan Street, Changchun 130012, P. R. China 1School of Chemical Engineering and Material Science, Zaozhuang University, Zaozhuang 277160, P. R. China
lbingbing2002@163.com
Korean Journal of Chemical Engineering, May 2022, 39(5), 1307-1315(9), 10.1007/s11814-021-0992-0
Download PDF
Abstract
Membrane hydrophilicity is a crucial factor in evaluating ultrafiltration processes. In this paper, chitosan (CS) was selected for the hydrophilic modification of the polylactic acid (PLA) membrane, and PLACS membranes were prepared for the densification of the yeast solution. By non-solvent phase inversion method (NIPS), the PLACS microfiltration membranes were prepared by using chitosan (CS) acetic acid solution as the coagulation bath and glutaraldehyde as the crosslinking agent. PLACS membranes were characterized by water contact angle, porosity, pore size distribution, mechanical properties, ATR-FTIR, SEM, TGA and the ultrafiltration experiment. The viscosity of coagulation bath solution can severely influence the exchange rate of the solvent and the non-solvent as well during phase inversion; therefore, it can regulate the precipitation kinetics and membrane morphology. The results showed that chitosan (CS) was presented as granular on the pore surfaces of the PLACS membranes. When chitosan (CS) content increased, gel rate became smaller and membrane forming process was prolonged; the porosity and pore size of the PLACS were increased compared to the polylactic acid (PLA) membrane, pure water flux increased from 90.31 L· m-2· h-1 to 120.14 L· m-2· -1, and yeast rejection rate increased from 75% to more than 90%.
References
Kiely PD, Cusick R, Call DF, Selembo PA, Regan JM, Logan BEJBT, Bioresour. Technol., 102, 388 (2011)
Saba N, Paridah MT, Jawaid M, Abdan K, Azowa NJSIP, Agric. Biomass Based Pot. Mater. (2015).
Villadiego KM, Tapia M, Useche J, J. Polym. Environ. (2021)
Freitas ED, Moura CF, Kerwald J, Beppu MM, Polymer, 12, 2878 (2020)
Hao L, Zheng T, Jiang J, Zhang G, Wang P, Chem. Eng. J., 292, 163 (2016)
Rajaeian B, Heitz A, Tade MO, Liu S, J. Membr. Sci., 485, 48 (2015)
Zinadini S, Gholami F, J. Appl. Res. Water Wastewater, 3, 188 (2016)
Fan GD, Su ZY, Lin RJ, Lin XY, Xu RX, Chen W, Int. J. Polym. Sci., 2016, 1 (2016)
Wu QD, Tiraferri A, Li T, Xie WC, Chang HQ, Bai YH, Liu BC, Acs Omega, 5, 23450 (2020)
Darwish NB, Abdulgader HA, Alromaih H, Alalawi A, J. Water Process Eng., 27, 32 (2019)
Wang W, Shi YP, Zhang P, Zhang ZC, Xu X, J. Appl. Polym. Sci., 138, 51165 (2021)
Padilha LF, Borges CP, Braz. J. Chem. Eng., 36, 497 (2019)
Bilican I, Pekdemir S, Onses MS, Akyuz L, Altuner EM, Koc-Bilican B, Zang LS, Mujtaba M, Mulercikas P, Kaya M, Acs Sustain. Chem. Eng., 8, 18083 (2020)
Wu JF, Zhang LY, Int. J. Biol. Macromol., 121, 1101 (2019)
Giraldo JD, Rivas BL, Polym. Bull., 78, 1465 (2021)
Shi AP, Guan Y, Zhang YJ, J. Bioact. Compat. Polym., 35, 289 (2020)
Li J, Xu ZI, Hu Y, Polym. Adv. Technol., 19, 251 (2010)
Sun D, Liu MQ, Guo JH, Zhang JY, Li BB, Li DY, Desalination, 373, 63 (2015)
Xu ZL, Liu M, Wei YM, Zhao LB, Xu MX, Chem. Eng. Sci., 137, 131 (2015)
Essalhi M, Khayet M, J. Membr. Sci., 454, 133 (2014)
Lee CW, Bae SD, Han SW, Kang LS, Desalination, 202, 239 (2007)
Bajpai PK, Singh I, Madaan J, J. Thermoplast. Compos. Mater., 27, 52 (2014)
Xu F, Liu Z, Zhu J, Zhang Q, Li S, Appl. Surf. Sci., 26, 368 (2013)
Devi S, Ray P, Singh K, Singh PS, Desalination, 346, 9 (2014)
Zhao LB, Xu ZL, Liu M, Wei YM, J. Membr. Sci., 454, 184 (2014)
Xu HP, Lang WZ, Yan X, Zhang X, Guo YJ, J. Membr. Sci., 467, 142 (2014)
Su JO, Kim N, Yong TL, J. Membr. Sci., 345, 13 (2009)
Singhvi MS, Zinjarde SS, Gokhale DV, J. Appl. Microbiol., 127, 6 (2019)
Li WH, Zhang C, Chi H, Li L, Lan TQ, Han P, Chen HY, Qin YY, Molecules, 22, 1170 (2017)
Li G, Zhao MH, Xu F, Yang B, Li XY, Meng XX, Teng LS, Sun FY, Li YX, Molecules, 25, 5023 (2020)
Avila A, Bierbrauer K, Pucci G, Lopez-Gonzalez M, Strumia M, J. Food Eng., 109, 752 (2012)
Jiang S, Jian L, Man D, Li Y, Wang H, Jiang S, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 59, 86 (2016)
Haghbin M, Esmaeilzadeh J, Kahrobaee S, Macromol. Res., 28, 1232 (2020)
Das M, Chakraborty D, J. Appl. Polym. Sci., 102, 5050 (2010)
Pal AK, Katiyar V, Int. J. Biol. Macromol., 95, 1267 (2017)
Mokhena TC, Sefadi JS, Sadiku ER, John MJ, Mochane MJ, Mtibe A, Polymer, 10, 1363 (2018)
Trang NTT, Chinh NT, Giang NV, Thanh DTM, Lam TD, Hoang T, J. Electron. Mater., 45, 3581 (2016)
Zhu LX, Qiu JH, Liu WD, Sakai E, Compos. Commun., 13, 18 (2019)
Rahman MM, Islam MS, Li GS, Polym. Test, 68, 302 (2018)
Saba N, Paridah MT, Jawaid M, Abdan K, Azowa NJSIP, Agric. Biomass Based Pot. Mater. (2015).
Villadiego KM, Tapia M, Useche J, J. Polym. Environ. (2021)
Freitas ED, Moura CF, Kerwald J, Beppu MM, Polymer, 12, 2878 (2020)
Hao L, Zheng T, Jiang J, Zhang G, Wang P, Chem. Eng. J., 292, 163 (2016)
Rajaeian B, Heitz A, Tade MO, Liu S, J. Membr. Sci., 485, 48 (2015)
Zinadini S, Gholami F, J. Appl. Res. Water Wastewater, 3, 188 (2016)
Fan GD, Su ZY, Lin RJ, Lin XY, Xu RX, Chen W, Int. J. Polym. Sci., 2016, 1 (2016)
Wu QD, Tiraferri A, Li T, Xie WC, Chang HQ, Bai YH, Liu BC, Acs Omega, 5, 23450 (2020)
Darwish NB, Abdulgader HA, Alromaih H, Alalawi A, J. Water Process Eng., 27, 32 (2019)
Wang W, Shi YP, Zhang P, Zhang ZC, Xu X, J. Appl. Polym. Sci., 138, 51165 (2021)
Padilha LF, Borges CP, Braz. J. Chem. Eng., 36, 497 (2019)
Bilican I, Pekdemir S, Onses MS, Akyuz L, Altuner EM, Koc-Bilican B, Zang LS, Mujtaba M, Mulercikas P, Kaya M, Acs Sustain. Chem. Eng., 8, 18083 (2020)
Wu JF, Zhang LY, Int. J. Biol. Macromol., 121, 1101 (2019)
Giraldo JD, Rivas BL, Polym. Bull., 78, 1465 (2021)
Shi AP, Guan Y, Zhang YJ, J. Bioact. Compat. Polym., 35, 289 (2020)
Li J, Xu ZI, Hu Y, Polym. Adv. Technol., 19, 251 (2010)
Sun D, Liu MQ, Guo JH, Zhang JY, Li BB, Li DY, Desalination, 373, 63 (2015)
Xu ZL, Liu M, Wei YM, Zhao LB, Xu MX, Chem. Eng. Sci., 137, 131 (2015)
Essalhi M, Khayet M, J. Membr. Sci., 454, 133 (2014)
Lee CW, Bae SD, Han SW, Kang LS, Desalination, 202, 239 (2007)
Bajpai PK, Singh I, Madaan J, J. Thermoplast. Compos. Mater., 27, 52 (2014)
Xu F, Liu Z, Zhu J, Zhang Q, Li S, Appl. Surf. Sci., 26, 368 (2013)
Devi S, Ray P, Singh K, Singh PS, Desalination, 346, 9 (2014)
Zhao LB, Xu ZL, Liu M, Wei YM, J. Membr. Sci., 454, 184 (2014)
Xu HP, Lang WZ, Yan X, Zhang X, Guo YJ, J. Membr. Sci., 467, 142 (2014)
Su JO, Kim N, Yong TL, J. Membr. Sci., 345, 13 (2009)
Singhvi MS, Zinjarde SS, Gokhale DV, J. Appl. Microbiol., 127, 6 (2019)
Li WH, Zhang C, Chi H, Li L, Lan TQ, Han P, Chen HY, Qin YY, Molecules, 22, 1170 (2017)
Li G, Zhao MH, Xu F, Yang B, Li XY, Meng XX, Teng LS, Sun FY, Li YX, Molecules, 25, 5023 (2020)
Avila A, Bierbrauer K, Pucci G, Lopez-Gonzalez M, Strumia M, J. Food Eng., 109, 752 (2012)
Jiang S, Jian L, Man D, Li Y, Wang H, Jiang S, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 59, 86 (2016)
Haghbin M, Esmaeilzadeh J, Kahrobaee S, Macromol. Res., 28, 1232 (2020)
Das M, Chakraborty D, J. Appl. Polym. Sci., 102, 5050 (2010)
Pal AK, Katiyar V, Int. J. Biol. Macromol., 95, 1267 (2017)
Mokhena TC, Sefadi JS, Sadiku ER, John MJ, Mochane MJ, Mtibe A, Polymer, 10, 1363 (2018)
Trang NTT, Chinh NT, Giang NV, Thanh DTM, Lam TD, Hoang T, J. Electron. Mater., 45, 3581 (2016)
Zhu LX, Qiu JH, Liu WD, Sakai E, Compos. Commun., 13, 18 (2019)
Rahman MM, Islam MS, Li GS, Polym. Test, 68, 302 (2018)
