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Received November 1, 2021
Accepted March 9, 2022
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Ethanol dry reforming over ordered mesoporous Co-Zn composite oxide for syngas production
Faculty of Light Industry and Chemical Engineering, Dalian Polytechnic University, 116023 Dalian, China 1Faculty of Environment and Life, Beijing University of Technology, 100124, Beijing, China 2Henan Key Laboratory of Coal Green Conversion, Henan Polytechnic University, 454000 Jiaozuo, China
secat@bjut.edu.cn
Korean Journal of Chemical Engineering, July 2022, 39(7), 1744-1752(9), 10.1007/s11814-022-1105-4
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Abstract
This work is mainly concerned with the synthesis of Co-Zn nanocomposites by employing MCM-41 silica as hard template (CoZnO-HT) and its catalytic behavior toward to CO2 reforming with ethanol. The physicochemical features of the as-prepared catalysts were probed through various characterization techniques, including XRD, TEM, BET, H2-TPR, and XPS. Indeed, CoZnO-HT catalyst possessed a highly ordered mesostructure with similarity to MCM-41 template and a higher specific surface area (304m2/g) compared to the reference CoZnO-C sample (4.75m2/ g) prepared by the conventional impregnation method. Consequently, CoZnO-HT exhibited good performance at low temperature, and full ethanol conversion could be achieved at 550℃ as well as the negligible formation of byproduct acetone. In addition, this catalyst depicted good stability and no obvious deactivation was observed after 40 h time on stream tests under the stoichiometric feed ratio. Indeed, superior specific surface area and efficient mass transport within the mesopores might be critical factors assigned to better activity and stability for CoZnO-HT.
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Thompson WA, Fernandez ES, Maroto-Valer MM, ACS Sustain. Chem. Eng., 8, 4677 (2020)
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Menchavez RN, Ha SH, Korean J. Chem. Eng., 36, 909 (2019)
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Bahari MB, Phuc NHH, Abdullah B, Alenazey F, Vo DVN, J. Environ. Chem. Eng., 4, 4830 (2016)
Kale GR, Kulkarni BD, Chem. Eng. J., 165, 864 (2010)
Drif A, Bion N, Brahmi R, Ojala S, Pirault-Roy L, Turpeinen E, Seelam PK, Keiski R, Epron F, Appl. Catal. A: Gen., 504, 576 (2015)
Bac S, Keskin S, Avci AK, Sustain. Energy Fuels, 4, 1029 (2020)
da Silva AM, de Souza KR, Jacobs G, Graham UM, Davis BH, Mattos LV, Noronha FB, Appl. Catal. B: Environ., 102, 94 (2011)
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Aw MS, Zorko M, Crnivec IGO, Pintar A, Ind. Eng. Chem. Res., 54, 3775 (2015)
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Vickers SM, Gholami R, Smith KJ, MacLachlan MJ, ACS Appl. Nano Mater., 3, 2346 (2020)
Sun TT, Shan NN, Xu LB, Wang JX, Chen JF, Zakhidov AA, Baughman RH, Chem. Mater., 30, 1617 (2018)
Vickers SM, Gholami R, Smith KJ, MacLachlan MJ, ACS Appl. Mater. Interfaces, 7, 11460 (2015)
González-Prior J, López-Fonseca R, Gutiérrez-Ortiz JI, de Rivas B, Appl. Catal. B: Environ., 222, 9 (2018)
Wang YG, Ren JW, Wang YQ, Zhang FY, Liu XH, Guo Y, Lu GZ, J. Phys. Chem. C, 112, 15293 (2008)
Djinovic P, Batista J, Levec J, Pintar A, Appl. Catal. A: Gen., 364, 156 (2009)
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Park JH, Yeo S, Chang TS, J. CO2. Util., 26, 465 (2018)
Rodriguez-Gomez A, Pereniguez R, Caballreo A, J. Phys. Chem. B, 122, 500 (2018)
Lin SSY, Daimon H, Ha SY, Appl. Catal. A: Gen., 440, 1047 (2018)
Khodakov AY, Lynch J, Bazin B, Rebours B, Zanier N, Moisson B, Chaumette P, J. Catal., 168, 16 (1997)
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Cai WJ, Chen Q, Wang FG, Li ZC, Yu H, Zhang SY, Cui L, Li CM, Catal. Lett., 149, 2508 (2019)
Gac W, Greluka M, Slowika G, Turczyniak-Surdacka S, Appl. Surf. Sci., 440, 1047 (2018)
Park JH, Yeo S, Heo I, Chang TS, Appl. Catal. A: Gen., 562, 120 (2018)
Wang S, Hou Y, Wang X, ACS Appl. Mater. Interface, 7, 4327 (2015)
Yuan ZL, Liu B, Zhou P, Zhang ZH, Chi Q, Catal. Sci. Technol., 8, 4430 (2018)
Zhao HJ, Dong F, Han WL, Tang ZC, Ind. Eng. Chem. Res., 58, 18055 (2019)
Xie YJ, Guo Y, Guo YL, Wang L, Zhan WC, Wang YS, Gong XQ, Lu GZ, RSC Adv., 6, 50228 (2016)
Zhang F, Liu ZY, Zhang SH, Akter N, Palomino RM, Vovchok D, Orozco I, Salazar D, Rodriguez J, Llorca J, Lee J, Kim DH, ACS Catal., 8, 3550 (2018)
Nishiguchi T, Matsumoto T, Kanai H, Utani K, Matsumura Y, Shen WJ, Imamura S, Appl. Catal. A: Gen., 279, 273 (2005)
Singha RK, Yadav A, Shukla A, Kumar M, Bal R, Catal. Commun., 92, 19 (2017)
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Zhang JS, Li FX, Appl. Catal. B: Environ., 176-177, 513 (2015)
Paksoy AI, Caglayan BS, Aksoylu AE, Appl. Catal. B: Environ., 168-169, 164 (2015)
Mattos LV, Jacobs G, Davis BH, Noronha FB, Chem. Rev., 112, 4094 (2012)
