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Received October 31, 2021
Accepted January 25, 2022
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Design of low-loaded NiRe bimetallic catalyst on N-doped mesoporous carbon for highly selective deoxygenation of oleic acid to n-heptadecane
1Key Laboratory of Biomass Chemical Engineering of the Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, 38 Zheda Road, Xihu District, Hangzhou 310027, P. R. China 2Institute of Zhejiang University-Quzhou, 78 Jinhua Boulevard North, Quzhou 324000, P. R. China 3Research and Development Base of Catalytic Hydrogenation, College of Pharmaceutical Science, Zhejiang University of Technology, 18 Chaowang Road, Xiacheng District, Hangzhou 310014, P. R. China
Korean Journal of Chemical Engineering, July 2022, 39(7), 1753-1761(9), 10.1007/s11814-022-1079-2
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Abstract
Using nitrogen-doped mesoporous carbon (NMC) as the support, several NiRe bimetallic catalysts with low metal loading of 1 wt% were designed and prepared for the selective deoxygenation of oleic acid to n-heptadecane in the absence of hydrogen. Results showed that the Ni80Re20/NMC catalyst with a Ni/Re molar ratio of 80 : 20 achieved the highest yield of n-heptadecane (92.3%) at 330℃ for 2 h in isopropanol solvent, and at a metal/oleic acid weight ratio of 1 : 333. The catalyst can be reused at least five times with slight activity loss. Combined with the results of insitu XRD, HRTEM, XPS and CO2-TPD, the formation of NiRe alloy, the very fine NiRe nanoparticle size at 2.30 nm, as well as the hydrophobic, mesoporous and weakly basic properties of the NMC support surface were demonstrated to contribute to the excellent catalytic performance of the catalyst.
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References
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