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Received October 20, 2021
Accepted January 21, 2022
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Eco-friendly inorganic-organic bionanocomposite (Copper oxide - Carboxyl methyl cellulose - Guar gum): Preparation and effective removal of dye from aqueous solution
1Department of Chemical and Polymer Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran 2Nanotechnology Research Centre, Tehran South Branch, Islamic Azad University, Tehran 15847-43311, Iran 3Department of Chemistry, Faculty of Science, Shahr-e-Qods Branch, Islamic Azad University, Tehran, Iran 4, Iran 5Department of Chemistry, Amirkabir University of Technology, Tehran 15875-4413, Iran
mohammad.kalaee@gmail.com
Korean Journal of Chemical Engineering, August 2022, 39(8), 2138-2147(10), 10.1007/s11814-022-1074-7
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Abstract
Biopolymers, such as Carboxyl methylcellulose (CMC) and Guar gum (GG), have attracted much attention. Herein, binary organic composite (Carboxyl methyl cellulose - Guar gum) and ternary inorganic-organic ecofriendly bionanocomposite (Copper oxide - Carboxyl methyl cellulose - Guar gum) with different wt% of CuO (1%, 3%, and 5% denoted as CMC/GG/CuO-1, CMC/GG/CuO-3, and CMC/GG/CuO-5) were prepared. The CMC, GG, CuO, CMC/GG, CMC/GG/CuO-1, CMC/GG/CuO-3, and CMC/GG/CuO-5 were characterized by XRD, FTIR, SEM, and EDX and used to remove malachite green (MG) dye from water. The effect of operational parameters on the adsorption process was investigated in detail. The maximum dye capacity was 18.5mg/g. The isotherm data showed the Freundlich isotherm, which indicated the non-uniformity of adsorption on the adsorbent surface. Pollutant removal followed the pseudo-second-order kinetics. Also, the thermodynamic study presented that adsorption was spontaneous and endothermic.
Keywords
References
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Gurses A, Karaca S, Dogar C, Bayrak R, Acıkyıldız M, Yalcın M, J. Colloid Interface Sci., 269, 310 (2004)
Davarpanah S, Mahmoodi NM, Arami M, Bahrami H, Mazaheri F, Appl. Surf. Sci., 255, 4171 (2009)
Mahmoodi NM, Abdi J, Microchem J., 144, 436 (2019)
Kashefi S, Borghei SM, Mahmoodi NM, J. Mol. Liq., 276, 153 (2019)
Nasrollahi N, Aber S, Vatanpour V, Mahmoodi NM, Mater. Chem. Phys., 222, 338 (2019)
Mai NTT, Nga NK, Hue DTM, Dung TN, Chinh HD, Huy TQ, Adsorpt. Sci. Technol., 2021, 9193052 (2021)
Nga NK, Chau NTT, Viet PH, J. Sci. Adv. Mater. Dev., 5, 65 (2020)
Mahmoodi NM, Fib. Polym., 15, 273 (2014)
Abdi J, Mahmoodi NM, Vossoughi M, Alemzadeh I, Microporous Mesoporous Mater., 273, 177 (2019)
Yang Z, Peng H, Wang W, Liu T, J. Appl. Polym. Sci., 116, 2658 (2010)
Mahmoodi NM, Limaee NY, Arami M, Borhany S, Mohammad-Taheri M, J. Photochem. Photobiol. A-Chem., 189, 1 (2007)
Mahmoodi NM, Saffar-Dastgerdi MH, Appl. Catal. B: Environ., 268, 118443 (2019)
Mahmoodi NM, Taghizadeh M, Taghizadeh A, Abdi J, Hayati B, Shekarchi AA, Appl. Surf. Sci., 480, 288 (2019)
Mahmoodi NM, J. Environ. Eng.-ASCE, 139, 1368 (2013)
Mahmoodi NM, Saffar-Dastgerdi MH, Microchem J., 145, 74 (2019)
Mahmoodi NM, Hayati B, Arami M, J. Chem. Eng. Data, 55, 4638 (2010)
Kong Q, Wang X, Lou T, Carbohydr. Polym., 244, 116481 (2020)
Kanikireddy V, Varaprasad K, Rani MS, Venkataswamy P, Reddy BJM, Vithal M, Carbohydr. Polym., 236, 116053 (2020)
Mahmoodi NM, Mokhtari-Shourijeh Z, Fib. Polym., 16, 1861 (2015)
Hattori K, Abe E, Yoshida T, Cuculo JA, Polym. J., 36, 123 (2004)
Rachtanapun P, Kasetsart J.- Nat. Sci., 43, 259 (2009)
Tijsen CJ, Kolk HJ, Stamhuis EJ, Beenackers AACM, Carbohydr. Polym., 45, 219 (2001)
Singh RK, Singh AK, Waste Biomass Valor., 4, 129 (2013)
Bono A, Ying PH, Yan FY, Muei CL, Sarbatly R, Krishnaiah D, Adv. Nat. Appl. Sci., 3, 5 (2009)
Karabinos JV, Hindert M, Advances in carbohydrate chemistry, Sincedirect (1954).
Karimzadeh Z, Javanbakht S, Namazi H, Bioimpacts, 9, 5 (2019)
Saxena R, Sharma S, Int. J. Sci. Eng. Res., 7, 675 (2016)
Sharma G, Sharma S, Kumar A, Al-Muhtaseb AH, Naushad M, Ghfar AA, Mola GT, Stadler FJ, Carbohydr. Polym., 199, 534 (2018)
Jain V, Tammishetti V, Joshi K, Kumar D, Pradip, Rai B, Miner. Eng., 109, 144 (2017)
Verma D, Sharma SK, Int. J. Biol. Macromol., 181, 653 (2021)
Thombare N, Jha U, Mishra S, Siddiqui MZ, Int. J. Biol. Macromol., 88, 361 (2016)
Mudgil D, Barak S, Khatkar BS, J. Food Sci. Technol., 51, 409 (2014)
Sharma G, Kumar A, Sharma S, Naushad M, Ghfar AA, Al-Muhtaseb AH, Ahamad T, Sharma N, Stadler FJ, Cellulose, 27, 3677 (2020)
Lv Y, Xing B, Zheng M, Yi G, Huang G, Zhang C, Yuan R, Chen Z, Cao Y, Nanomaterials, 8, 1 (2018)
Capanema NSV, Mansur AAP, Mansur HS, de Jesus AC, Carvalho SM, Chagas P, de Oliveira LC, Environ. Technol., 39, 2856 (2018)
Pal P, Corpuz AG, Hasan SW, Sillanpää M, Banat F, Sep. Purif. Technol., 255, 117684 (2021)
Eltaweil AS, Elgarhy GS, El-Subruiti GM, Omer AM, Int. J. Biol. Macromol., 154, 307 (2020)
Mahmoodi NM, Arabloo M, Abdi J, Water Res., 67, 216 (2014)
Mahmoodi NM, Desalin. Water Treat., 53, 84 (2015)
Mahmoodi NM, Arami M, J. Appl. Polym. Sci., 109, 4043 (2008)
Mahmoodi NM, Hayati B, Arami M, Mazaheri F, J. Chem. Eng. Data, 55, 4660 (2010)
Mahmoodi NM, J. Mol. Catal. A-Chem., 366, 254 (2013)
Mahmoodi NM, J. Environ. Eng.-ASCE, 139, 1382 (2013)
Khan TA, Nazir M, Ali I, Kumar A, Arab. J. Chem., 10, S2388N (2017)
dos Reis LGT, Robaina NF, Pacheco WF, Cassella RJ, Chem. Eng. J., 171, 532 (2011)
Abuzerr S, Darwish M, Mahvi AH, Water Sci. Technol., 2017, 534 (2017)
Tella AC, Olawale MD, Neuburger M, Obaleye JA, J. Solid State Chem., 255, 157 (2017)
Ghaedi M, Ansari A, Habibi MH, Asghari AR, J. Ind. Eng. Chem., 20, 17 (2014)
Zare K, Sadegh H, Shahryari-Ghoshekandi R, Maazinejad B, Ali V, Tyagi I, Agarwal S, Gupta VK, J. Mol. Liq., 212, 266 (2015)
Marsiezade N, Javanbakht V, Int. J. Biol. Macromol., 162, 1140 (2020)
Mahmoodi NM, Water. Air. Soil Pollut., 224, 1419 (2013)
Mahmoodi NM, Najafi F, Microporous Mesoporous Mater., 156, 153 (2012)
Mahmoodi NM, Oveisi M, Taghizadeh A, Taghizadeh M, J. Hazard. Mater., 368, 746 (2019)
Mahmoodi NM, Oveisi M, Taghizadeh A, Taghizadeh M, Carbohydr. Polym., 227, 115364 (2020)
Oveisi M, Mahmoodi NM, Asli MA, J. Clean Prod., 222, 669 (2019)
Mahmoodi NM, J. Taiwan Instit. Chem. Eng., 45, 2008 (2014)
Hoseinzadeh H, Hayati B, Shahmoradi F, Seifpanahi-shabani K, Mahmoodi NM, Mater. Res. Bull., 142, 111408 (2021)
Li J, Wu Z, Duan Q, Alsaedi A, Hayat T, Chen C, J. Clean Prod., 204, 896 (2018)
Naeimi S, Faghihian H, Environ. Toxicol. Pharmacol., 53, 121 (2017)
Bhadra BN, Yoo DK, Jhung SH, Appl. Surf. Sci., 504, 144348 (2020)
Inonu Z, Keskin S, Erkey C, ACS Appl. Nano Mater., 1, 5959 (2018)
Thurm S, Odenbach S, J. Magn. Magn. Mater., 252, 247 (2002)
Sun J, Xu R, Zhang Y, Ma M, Gu N, J. Magn. Magn. Mater., 312, 354 (2007)
Meshko V, Markovska L, Mincheva M, Rodrigues AE, Water Res., 35, 3357 (2001)
Gurses A, Karaca S, Dogar C, Bayrak R, Acıkyıldız M, Yalcın M, J. Colloid Interface Sci., 269, 310 (2004)
