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Received March 2, 2022
Accepted May 26, 2022
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Characteristics of the all-vanadium redox flow battery using ammonium metavanadate electrolyte

Grad. School, Dept. Green Energy Eng., Hoseo University, Asan City, Chungnam 31499, Korea
gjhwang@hoseo.edu
Korean Journal of Chemical Engineering, September 2022, 39(9), 2361-2367(7), 10.1007/s11814-022-1190-4
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Abstract

An electrolyte was prepared using ammonium metavanadate (AMV) to apply in the all-vanadium redox flow battery (VRFB). The component and composition of the prepared electrolyte by AMV were analyzed by X-ray diffraction (XRD) and inductively coupled plasma (ICP). It was confirmed from the analysis results that the component was almost the same as that of vanadyl sulfate and the composition was almost the same as that of prepared by 2.1mol of the vanadyl sulfate dissolved in 3M H2SO4. The cell performance of VRFB using the prepared electrolyte by AMV was measured at current density of 60mA cm-2. The efficiency of VRFB using the prepared electrolyte by AMV was 97.66%, 86.31%, 84.30% for an average current efficiency, average voltage efficiency and average energy efficiency, respectively. It was expected that the prepared electrolyte by AMV was usable as the electrolyte of VRFB from the viewpoint of the cell performance.

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