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Received March 31, 2022
Accepted July 29, 2022
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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An effective and smart corrosion inhibitor in acidic environment: Experimental & theoretical studies
Asmae Bouoidina
Rajesh Haldhar1
Rajae Salim†
Elhachmia Ech-chihbi
Hamza Ichou2
Fadoua El-Hajjaji
Seong-Cheol Kim1†
Brahim El Ibrahimi3
Savas Kaya4
Mustapha Taleb
Engineering Laboratory of Organometallic, Molecular Materials, and Environment, Faculty of Sciences, University Sidi Mohamed Ben Abdellah, Fez, Morocco 1School of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Korea 2Centre d’élaboration de Matériaux et d’études Structurales, CEMES-CNRS, UPR 8011, F-31055 Toulouse, France 3Applied Chemistry-Physic Team, Faculty of Sciences, University of Ibn Zohr, Agadir, Morocco 4Math. and Sci. Edu., Sivas Cumhuriyet University, Math, 58140, Sivas, Turkey
salimrajae@gmail.com
Korean Journal of Chemical Engineering, January 2023, 40(1), 235-247(13), 10.1007/s11814-022-1246-5
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Abstract
The application of corrosion inhibitors is the best way to protect metals from degradation. Therefore, the P-anisidine molecule was investigated as a corrosion inhibitor for mild steel in a 1M HCl medium. This study used different methods, such as electrochemical impedance spectroscopy, polarization potentiodynamic curves, scanning electron microscopy, and theoretical method. The addition of this molecule to the aggressive medium achieved inhibition of 81% at a concentration of 10-3M. The potentiodynamic polarization curves reveal a mixed type character (anodic and cathodic) and adsorb on the metal surface according to Langmuir adsorption isotherm. This adsorption was also proved by scanning electron microscopy proving the presence of a protective layer on the steel surface used. The theoretical results confirmed the experimental part and showed that P-anisidine adsorbed parallel onto the steel surface covering a large surface area.
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Arrousse N, Mabrouk E, Salim R, Alaoui KI, El-hajjaji F, Rais Z, Taleb M, Hammouti B, Mater. Today: Proc., 27, 3184 (2020)
Haldhar R, Prasad D, J. Bio-Tribo-Corros., 6, 48 (2020)
El-hajjaji F, Abrigach F, Hamed O, Hasan AR, Taleb M, Jodeh S, Rodriguez-Castellon E, Yuso MVM, Algarra M, Coatings, 8, 330 (2018)
Haldhar R, Prasad D, Bahadur I, Dagdag O, Berisha A, J. Mol. Liq., 323, 114958 (2021)
Haldhar R, Prasad D, Bahadur I, Dagdag O, Kaya S, Verma DK, Kim SC, J. Mol. Liq., 335, 116184 (2021)
Haldhar R, Prasad D, Kamboj D, Kaya S, Dagdag O, Guo L, Appl. Sci., 3, 25 (2021)
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Haldhar R, Prasad D, Mandal N, Benhiba F, Bahadur I, Dagdag O, Colloids Surf. A: Physicochem. Eng. Asp., 614, 126211 (2021)
Shukla SK, Quraishi A, J. Appl. Polym. Sci., 124, 5130 (2012)
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Ma Y, Fan B, Liu H, Fan G, Hao H, Yang B, Appl. Surf. Sci., 514, 146086 (2020)
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Arrousse N, Mabrouk E, Hammouti B, El-hajjaji F, Rais Z, Taleb M, Int. J. Corros. Scale Inhib., 9, 661 (2020)
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Haldhar R, Prasad D, Saxena A, J. Environ. Chem. Eng., 6, 5230 (2018)
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Hameed RSA, Alfakeer M, Abdallah M, Surf. Eng. Appl. Electrochem., 54, 599 (2018)
Arrousse N, Salim R, Obot IB, Abdellaui A, El-hajjaji F, Mabrouk E, Taleb M, J. Mol. Liq., 359, 119311 (2022)
Ghazoui A, Benchat N, El-hajjaji F, Taleb M, Rais R, Saddik R, Elaatiaoui A, Hammouti B, J. Alloy. Compd., 693, 510 (2017)
Mrani SA, Ech-chihbi E, Arrousse N, Rais Z, El-hajjaji F, El-Abiad C, Radi S, Mabrouki J, Taleb M, Jodeh S, Arab. J. Sci. Eng., 46, 5691 (2021)
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Nahlé A, Salim R, El-hajjaji F, Aouad MR, Messali M, Echchihbi E, Hammouti B, Taleb M, RSC Adv., 11, 4147 (2021)
Messali M, Larouj M, Lgaz H, Rezki N, Al-Blewi FF, Aouad MR, Chaouiki A, Salghi R, Chung ML, J. Mol. Struct., 1168, 39 (2018)
Arrousse N, Salim R, Benhiba F, Mabrouk EH, Abdelaoui A, El-hajjaji F, Warad I, Zakkrouk A, Taleb M, J. Mol. Liq., 338, 116610 (2021)
El-hajjaji F, Salim R, Messali M, Hammouti B, Chauhan DS, Almutairi SM, Quraishi MA, J. Bio-Tribo-Corros., 5, 4 (2019)
Rahimi A, Abdouss M, Farhadian A, Guo L, Neshati J, Eng. Chem. Res., 60, 11030 (2020)
Chile NE, Haldhar R, Godffrey UK, Chijioke OC, Umezuruike EA, Ifeoma OP, Oke MO, Ichou H, Arrousse N, Kim SC, Lubricants, 10, 1 (2022)
Saady A, El-hajjaji F, Taleb M, Alaoui KI, El-Biache A, Mahfoud A, Alhouari G, Hammouti B, Chauhan DS, Quraishi MA, Mater. Discov., 12, 30 (2019)
Kumari PP, Shetty P, Rao SA, Arab. J. Chem., 10, 653 (2017)
Dohare P, Chauhan DS, Sorour AA, Quraishi MA, Mater. Discov., 9, 30 (2017)
Obaid AY, Ganash AA, Qusti AH, Elroby SA, Hermas AA, Arab. J. Chem., 10, S1276 (2017)
Murulana LC, Singh AK, Shukla SK, Kabanda MM, Ebenso EE, Ind. Eng. Chem. Res., 51, 13282 (2012)
Ma Q, Qi S, He X, Tang Y, Lu G, Corrosion Sci., 129, 91 (2017)
Lazrak J, Salim R, Arrousse N, Ech-chihbi E, El-hajjaji F, Taleb M, Farah F, Ramzi A, Int. J. Corros. Scale Inhib., 9, 1580 (2020)
Olasunkanmil O, Obot IB, Kabanda MM, Ebenso EE, J. Phys. Chem., 119, 16004 (2015)
El-hajjaji F, Ech-chihbi E, Rezki N, Benhiba F, Taleb M, Chauhan DS, Quraishi MA, J. Mol. Liq., 314, 113737 (2020)
Kumar R, Chahal S, Kumar S, Lata S, Salghi R, Jodeh S, Lgaz H, J. Mol. Liq., 243, 439 (2017)
Hamani H, Douadi T, Daoud D, Al-Noaimi M, Rikkouh RA, Chafaa S, J. Electroanal. Chem., 801, 425 (2017)
El-Ibrahimi B, Jmiai A, El-Mouaden K, Baddouh A, El-Issami S, Bazzi L, Hilali M, J. Mol. Struct., 1196, 105 (2019)
Qiang Y, Zhang S, Guo L, Zheng X, Xiang B, Chen S, Corrosion Sci., 119, 68 (2017)
Singh A, Ansari KR, Lin Y, Quraishi MA, Lgaz H, Chung IM, J. Taiwan Inst. Chem. Eng., 95, 341 (2018)
El-hajjaji F, Salim R, Taleb M, Benhiba F, Rezki N, Chauhan DS, Quraishi MA, Surf. Interfaces, 22, 100881 (2021)
Li F, Bai M, Wei SA, Jin S, Shen W, Ind. Eng. Chem. Res., 58, 7166 (2019)
Feng L, Zhang S, Qiang Y, Xu S, Tan B, Chen S, Mater. Chem. Phys., 215, 229 (2018)
Salim R, Ech-chihbi E, Oudda H, El-hajjaji F, Taleb M, Jodeh S, J. Bio-Tribo-Corros., 13, 5 (2019)
Arrousse N, Mabrouk E, Salim R, Alaoui KI, El-hajjaji F, Rais Z, Taleb M, Hammouti B, Mater. Today: Proc., 27, 3184 (2020)
Haldhar R, Prasad D, J. Bio-Tribo-Corros., 6, 48 (2020)
El-hajjaji F, Abrigach F, Hamed O, Hasan AR, Taleb M, Jodeh S, Rodriguez-Castellon E, Yuso MVM, Algarra M, Coatings, 8, 330 (2018)
Haldhar R, Prasad D, Bahadur I, Dagdag O, Berisha A, J. Mol. Liq., 323, 114958 (2021)
Haldhar R, Prasad D, Bahadur I, Dagdag O, Kaya S, Verma DK, Kim SC, J. Mol. Liq., 335, 116184 (2021)
Haldhar R, Prasad D, Kamboj D, Kaya S, Dagdag O, Guo L, Appl. Sci., 3, 25 (2021)
Butoi B, Groza A, Dinca P, Balan A, Barna V, Polymer, 9, 732 (2017)
Haldhar R, Prasad D, Mandal N, Benhiba F, Bahadur I, Dagdag O, Colloids Surf. A: Physicochem. Eng. Asp., 614, 126211 (2021)
Shukla SK, Quraishi A, J. Appl. Polym. Sci., 124, 5130 (2012)
Karthikaiselvi R, Subhashini S, J. Assoc. Arab Univ. Basic Appl. Sci., 16, 74 (2014)
Ma Y, Fan B, Liu H, Fan G, Hao H, Yang B, Appl. Surf. Sci., 514, 146086 (2020)
Abdellaoui O, Skalli MK, Haoudi A, Rodi YK, Mazzah A, Arrousse N, Taleb M, Ghibate R, Senhaji O, Mor. J. Chem., 9, 44 (2021)
Arrousse N, Mabrouk E, Hammouti B, El-hajjaji F, Rais Z, Taleb M, Int. J. Corros. Scale Inhib., 9, 661 (2020)
Arrousse N, Salim R, Abdellaoui A, El-hahhaji F, Hammouti B, Mabarouk E, Dino WA, Taleb M, J. Taiwan Inst. Chem. Eng., 120, 344 (2021)
Haldhar R, Prasad D, Nguyen LTD, Kaya S, Bahadur I, Dagdag O, Kim SC, Mater. Chem. Phys., 267, 124613 (2021)
Ech-chihbi E, Nahlé A, Salim R, Benhiba F, Moussaif A, Elhajjaji F, Oudda H, Guenbour A, Taleb M, Warad I, Zarrouk A, J. Alloy. Compd., 844, 155842 (2020)
Haldhar R, Prasad D, Saharan H, J. Ind. Eng. Chem., 11, 1 (2020)
Bourzi H, Oukhrib R, El-Ibrahimi B, Oualid HA, Abdellaoui Y, Balkard B, El-Issami S, Hilali M, Bazzi L, Len C, Sustainability, 12, 3304 (2020)
Haldhar R, Prasad D, Saxena A, J. Environ. Chem. Eng., 6, 5230 (2018)
El-Ibrahimi B, Jmiai A, El-Mouaden K, Oukhrib R, Soumoue A, El-Issami S, Bazzi L, J. King Saud Univ. Sci., 32, 163 (2020)
El-Ibrahimi B, Colloids Interface Sci. Commun., 37, 100279 (2020)
Farhadian A, Kashani SA, Rahimi A, Oguzie EE, Parvar AJ, Nwanonenyi SC, Zadeh SY, Nabi MR, J. Mol. Liq., 338, 11660 (2021)
Haldhar R, Prasad D, Saxena A, Kaur A, Eur. Phys. J. Plus, 133, 356 (2018)
Saha SK, Dutta A, Ghosh P, Sukul D, Banerjee P, Phys. Chem. Chem. Phys., 18, 17898 (2016)
Kumari PP, Shetty P, Rao SA, Arab. J. Chem., 10, 653 (2017)
Saady A, Ech-chihbi E, El-hajjaji F, Benhiba F, Zarrouk A, Kandrirodi Y, Taleb M, El-Biache A, Rais Z, J. Appl. Electrochem., 51, 245 (2021)
Zhang Y, Tan B, Zhang X, Guo L, Zhang S, J. Mol. Liq., 33, 116702 (2021)
Sĭgircik G, Tunc T, Erbil M, Corrosion Sci., 102, 437 (2016)
Xu B, Yang W, Liu Y, Yin X, Gong W, Chen Y, Corrosion Sci., 78, 260 (2014)
Hameed RSA, Alfakeer M, Abdallah M, Surf. Eng. Appl. Electrochem., 54, 599 (2018)
Arrousse N, Salim R, Obot IB, Abdellaui A, El-hajjaji F, Mabrouk E, Taleb M, J. Mol. Liq., 359, 119311 (2022)
Ghazoui A, Benchat N, El-hajjaji F, Taleb M, Rais R, Saddik R, Elaatiaoui A, Hammouti B, J. Alloy. Compd., 693, 510 (2017)
Mrani SA, Ech-chihbi E, Arrousse N, Rais Z, El-hajjaji F, El-Abiad C, Radi S, Mabrouki J, Taleb M, Jodeh S, Arab. J. Sci. Eng., 46, 5691 (2021)
Liu YW, Chen Y, Chen XH, Yang ZN, Hang ZZ, J. Alloy. Compd., 758, 184 (2018)
Nahlé A, Salim R, El-hajjaji F, Aouad MR, Messali M, Echchihbi E, Hammouti B, Taleb M, RSC Adv., 11, 4147 (2021)
Messali M, Larouj M, Lgaz H, Rezki N, Al-Blewi FF, Aouad MR, Chaouiki A, Salghi R, Chung ML, J. Mol. Struct., 1168, 39 (2018)
Arrousse N, Salim R, Benhiba F, Mabrouk EH, Abdelaoui A, El-hajjaji F, Warad I, Zakkrouk A, Taleb M, J. Mol. Liq., 338, 116610 (2021)
El-hajjaji F, Salim R, Messali M, Hammouti B, Chauhan DS, Almutairi SM, Quraishi MA, J. Bio-Tribo-Corros., 5, 4 (2019)
Rahimi A, Abdouss M, Farhadian A, Guo L, Neshati J, Eng. Chem. Res., 60, 11030 (2020)
Chile NE, Haldhar R, Godffrey UK, Chijioke OC, Umezuruike EA, Ifeoma OP, Oke MO, Ichou H, Arrousse N, Kim SC, Lubricants, 10, 1 (2022)
Saady A, El-hajjaji F, Taleb M, Alaoui KI, El-Biache A, Mahfoud A, Alhouari G, Hammouti B, Chauhan DS, Quraishi MA, Mater. Discov., 12, 30 (2019)
Kumari PP, Shetty P, Rao SA, Arab. J. Chem., 10, 653 (2017)
Dohare P, Chauhan DS, Sorour AA, Quraishi MA, Mater. Discov., 9, 30 (2017)
Obaid AY, Ganash AA, Qusti AH, Elroby SA, Hermas AA, Arab. J. Chem., 10, S1276 (2017)
Murulana LC, Singh AK, Shukla SK, Kabanda MM, Ebenso EE, Ind. Eng. Chem. Res., 51, 13282 (2012)
Ma Q, Qi S, He X, Tang Y, Lu G, Corrosion Sci., 129, 91 (2017)
Lazrak J, Salim R, Arrousse N, Ech-chihbi E, El-hajjaji F, Taleb M, Farah F, Ramzi A, Int. J. Corros. Scale Inhib., 9, 1580 (2020)
Olasunkanmil O, Obot IB, Kabanda MM, Ebenso EE, J. Phys. Chem., 119, 16004 (2015)
El-hajjaji F, Ech-chihbi E, Rezki N, Benhiba F, Taleb M, Chauhan DS, Quraishi MA, J. Mol. Liq., 314, 113737 (2020)
Kumar R, Chahal S, Kumar S, Lata S, Salghi R, Jodeh S, Lgaz H, J. Mol. Liq., 243, 439 (2017)
Hamani H, Douadi T, Daoud D, Al-Noaimi M, Rikkouh RA, Chafaa S, J. Electroanal. Chem., 801, 425 (2017)
El-Ibrahimi B, Jmiai A, El-Mouaden K, Baddouh A, El-Issami S, Bazzi L, Hilali M, J. Mol. Struct., 1196, 105 (2019)
Qiang Y, Zhang S, Guo L, Zheng X, Xiang B, Chen S, Corrosion Sci., 119, 68 (2017)
Singh A, Ansari KR, Lin Y, Quraishi MA, Lgaz H, Chung IM, J. Taiwan Inst. Chem. Eng., 95, 341 (2018)
El-hajjaji F, Salim R, Taleb M, Benhiba F, Rezki N, Chauhan DS, Quraishi MA, Surf. Interfaces, 22, 100881 (2021)
Li F, Bai M, Wei SA, Jin S, Shen W, Ind. Eng. Chem. Res., 58, 7166 (2019)
Feng L, Zhang S, Qiang Y, Xu S, Tan B, Chen S, Mater. Chem. Phys., 215, 229 (2018)