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- In relation to this article, we declare that there is no conflict of interest.
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Received October 11, 2022
Revised January 6, 2023
Accepted January 31, 2023
- Acknowledgements
- This work was supported by the Conselho Nacional de Desenvolvimento Científico e Tecnológico - CNPQ, Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPES and Fundação de Amparo à Pesquisa do Estado de Minas Gerais - FAPEMIG.
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Thioanisole oxidation promoted by new niobium-based catalyst: The effect of surface hydroxyl groups on catalytic performance
Guilherme Carletti de Aguiar1
Daniel Carreira Batalha1
Humberto Vieira Fajardo1
José Balena Gabriel Filho2
Carlos Giovanni Oliveira Bruziquesi2
Luiz Carlos Alves de Oliveira2
Mateus Aquino Gonçalves3
Teodorico de Castro Ramalho3
Adilson Candido Silva1†
1Department of Chemistry, Federal University of Ouro Preto, 35400-000, Ouro Preto, MG, Brazil 2Department of Chemistry, Federal University of Minas Gerais, 31270-901, Belo Horizonte, MG, Brazil 3Department of Chemistry, Federal University of Lavras, 37200-000, Lavras, MG, Brazil
adilsonqui@ufop.br
Korean Journal of Chemical Engineering, October 2023, 40(10), 2434-2441(8), 10.1007/s11814-023-1447-6
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Abstract
In this work, the application of a new, synthesized niobium-based catalyst, called S4 (niobium oxyhydroxide), in the liquid-phase oxidation of methyl-phenyl sulfide (thioanisole) using hydrogen peroxide as oxidant was proposed. The synthetic method employed provided a material with low crystallinity and high specific surface area and
acidity. A commercial material, called HY-340 (hydrated niobium oxide), was also employed as heterogeneous catalyst
for comparative purposes. The results showed that the synthesized S4 material is an outstanding catalyst, being able to
completely convert the substrate (thioanisole) that achieves almost 90% of selectivity for methyl phenyl sulfone formation, under mild reaction conditions. According to the theoretical and experimental combined results, the superior performance of S4 catalyst is related to the better interaction of H2O2 and thioanisole molecules with S4 surface, compared
to HY-340, pointing to the greater ability of this catalyst to form reactive oxygen species in contact with hydrogen peroxide, due to its higher content of free hydroxyl groups present on its s
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8. D. C. Batalha and M. J. da Silva, Energies, 14(17), 5506 (2021).
9. K. Skrodczky, M. M. Antunes, X. Han, S. Santangelo, G. Scholz, A.
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42. D. C. Batalha, N. H. Marins, R. M. Silva, N. L. V. Carreno, H. V.Fajardo and M. J. da Silva, Mol. Catal., 489, 110941 (2020).
43. Z. T. Alismaeel, T. M. Al-Jadir, T. M. Albayati, A. S. Abbas and A. M.Doyle, Adv. Powder Technol., 33 (2022).
44. T. F. Rosado, M. P. Teixeira, L. C. Moraes, L. A. da Silva, A. V. Pontes-Silva, J. G. Taylor, I. C. de Freitas, D. C. de Oliveira, J. Gardener,
G. Solórzano, T. V. Alves, M. F. Venancio, M. I. P. da Silva, E. Brocchi, H. V. Fajardo and A. G. M. da Silva, Appl. Catal., A, 613, 118010 (2021).
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47. P. Cruz, M. Fajardo, I. del Hierro and Y. Perez, Catal. Sci. Technol.,9, 620 (2018).
48. N.E. Thornburg and J.M. Notestein, ChemCatChem, 9, 3714 (2017).
49. O. V. Zalomaeva, N. V. Maksimchuk, G. M. Maksimov and O. A.Kholdeeva, Eur. J. Inorg. Chem., 2019, 410 (2019)
