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Received March 7, 2023
Revised July 12, 2023
Accepted August 10, 2023
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Investigation on hydrogen storage capacity of spherical activated carbons from ion exchange resins
1CO2 & Energy Research Center, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon 34114, Korea 2Department of Advanced Material and Chemical Engineering, University of Science & Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon 34113, Korea 3Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, Korea
jshong@krict.re.kr, jksuh@krict.re.kr
Korean Journal of Chemical Engineering, October 2023, 40(10), 2463-2471(9), 10.1007/s11814-023-1551-7
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Abstract
The role of spherical activated carbon from ion exchange resin as an adsorption material for hydrogen
storage was researched. Spherical activated carbon samples were prepared from two types of physical activation methods using steam and CO2. The porosity induced by each method and the resulting hydrogen adsorption performance
were compared and evaluated. When the samples had similar BET surface areas, steam activation induced microporous spherical activated carbon to increase hydrogen storage performance at low pressure (~1 bar) under low temperature conditions (under 77 K). CO2 activation enabled good formation of the 1-2 nm sized pore ratio in the micropores,
thus enhancing hydrogen storage performance at high pressure (~200 bar) under ambient temperature (under 298 K).
In conclusion, this indicates that there exists a range of spherical activated carbon pore size favorable for hydrogen
adsorption, dependent on the pressure range applied.
Keywords
References
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51. G. Yushin, R. Dash, J. Jagiello, J. E. Fisher and Y. Gogotsi, Adv. Funct.Mater., 16, 2288 (2006).
