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- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received January 29, 2023
Revised June 5, 2023
Accepted July 5, 2023
- Acknowledgements
- The work was funded by the Researchers Supporting Project Number (RSPD2023R763) King Saud University, Riyadh, Saudi Arabia.
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Melamine-benzaldehyde tris-schiff base as an efficient corrosion inhibitor for mild steel in 0.5 molar hydrochloric acid solution: Weight loss, electrochemical, theoretical and surface studies
Ifzan Arshad1 2†
Khizar Qureshi3
Shern-Long Lee1†
Safia Khan3
Muhammad Amin Abid5
Awais Bokhari6
Aboud Ahmed Awadh Bahajjaj7
Muhammad Naeem Ahmed8
1Institute for Advanced Study, Shenzhen University, Shenzhen, Guangdong 518060, P. R. of China 2College of Civil and Transportation Engineering, Shenzhen University, Shenzhen, China 3Department of Chemistry, University of Management and Technology, Sialkot, Pakistan 4Shandong Technology Centre of Nanodevices and Integration, School of Microelectronics, Shandong University, Jinan 25101, China 5Department of Chemistry, University of Sahiwal, Sahiwal Pakistan 6Sustainable Process Integration Laboratory, Faculty of Mechanical Engineering, Brno University of Technology, 2896/2,61600, Brno, Czech Republic 7Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia 8Department of Chemistry, The University of Azad Jammu and Kashmir, Muzaffarabad 13100, Pakistan
arshadmi@mail.ustc.edu.cn,, Sllee@szu.edu.cn
Korean Journal of Chemical Engineering, October 2023, 40(10), 2555-2564(10), 10.1007/s11814-023-1527-7
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Abstract
In the current study, the N,N',N''-(1,3,5-triazine-2,4,6-triyl)tris(1-phenylmethanimine) (MBSB) condensation product of melamine (triazine) and benzaldehyde was investigated as a mild steel corrosion inhibitor in a 0.5 M
HCl. The ability of the synthesized tris-Schiff base to suppress corrosion was evaluated utilizing weight loss measurements and electrochemical techniques. The maximum inhibition efficiency of 94.78%, 93.99% and 93.80% was achieved
using 100 ppm of MBSB in weight loss measurements, polarization, and EIS tests, respectively. It was observed that
increasing inhibitor concentration enhanced inhibition performance, whereas increasing temperature lowered inhibition performance. The analyses demonstrated that the synthesized tris-Schiff base inhibitor followed the Langmuir
adsorption isotherm, and the inhibitor was an effective mixed-type inhibitor having a low cathodic predominance.
According to the electrochemical impedance measurements, the Rct values increased with the increase of inhibitor concentration. In addition, theoretical calculations using density functional theory (DFT) were performed to reveal the
anticorrosion mechanism. The weight loss and electrochemical assessments were also supported by surface characterization analysis and show a substantial smoothness in the surface morphology
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25. N. Z. N. Hashim, K. Kassim, H. M. Zaki, A. I. Alharthi and Z. Embong, Appl. Surf. Sci., 476, 861 (2019).
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27. P. Shetty, Chem. Eng. Commun., 207(7), 985 (2020).
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35. I. Arshad, S. Ashraf, A. Abbas, S. Hameed, K. M. Lo and M. M. Naseer, Eur. Chem. Bull., 3, 587 (2014).
36. M. Mirzaei-Saatlo, H. Jamali, S. Moradi-Alavian, E. Asghari, R. Teimuri-Mofrad and M. D. Esrafili, Mater. Chem. Phys., 293, 126895 (2023).
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46. I. Arshad, J. Yameen, A. Saeed, J. M. White and F. Albericio, Crystals, 7(1), 19 (2017).
47. A. Saeed, I. Arshad and U. Flörke, J. Struct. Chem., 56(2), 396 (2015).
48. S. K. Ahmed, W. B. Ali and A. A. Khadom, Int. J. Ind. Chem., 10(2), 159 (2019).
49. A. Shareef Jasim, A. A. Khadom, K. H. Rashid and K. F. Al-Azawi, Results Chem., 4, 100569 (2022).
50. A. A. Fadhil, A. A. Khadom, H. Liu, C. Fu, J. Wang, N. A. Fadhil and H. B. Mahood, J. Mol. Liq., 276, 503 (2019).
51. L. Ouksel, R. Bourzami, S. Chafaa and N. Chafai, J. Mol. Struct., 1222, 128813 (2020).
52. H.R. Obayes, A.A. Al-Amiery, G.H. Alwan, T.A. Abdullah, A.A.H. Kadhum and A. B. Mohamad, J. Mol. Struct., 1138, 27 (2017).
53. R. Bourzami, L. Ouksel and N. Chafai, J. Mol. Struct., 1195, 839 (2019).
54. I. Arshad, K. Qureshi, A. S. Saleemi, A. Abdullah, A. A. A. Bahajjaj, S. Ali and A. Bokhari, RSC Adv., 13(28), 19301 (2023).
55. O. Moumeni, S. Chafaa, R. Kerkour, K. Benbouguerra and N. Chafai, J. Mol. Struct., 1206, 127693 (2020).
56. S. Mammeri, N. Chafai, H. Harkat, R. Kerkour and S. Chafaa, Iran. J. Sci. Technol. Trans. A: Sci., 45(5), 1607 (2021).
57. A. Zarrouk, B. Hammouti, A. Dafali, M. Bouachrine, H. Zarrok, S. Boukhris and S. S. Al-Deyab, J. Saudi Chem. Soc., 18(5), 450 (2014).
58. N. Assad, F. Abdul-Hameed, E. Yousif and A. Balakit, Al-Nahrain J. Sci., 18(2), 69 (2015)
