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- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received January 26, 2023
Revised May 13, 2023
Accepted May 24, 2023
- Acknowledgements
- This research was supported by the Korea Evaluation Institute of Industrial Technology [Grant number 20015430].
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Removal of carbon residue precursor in waste plastic pyrolysis oil via oxidation
Sukjeong Jeon1
Jaehong Lee1
Seong Cheon Kim1 2
Jin-Hyuk Kang3
Dongho Lee4
Hye Ryung Byon3 5
Jeasung Park2†
and Siyoung Q. Choi1 5†
1Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Korea 2Green and Sustainable Materials R&D Department, Korea Institute of Industrial Technology (KITECH), Cheonan-si, 31056, Korea 3Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Korea ****Process R&D Center, Hanwha Solutions R&D Institute, Daejeon 34128, Korea 4Process R&D Center, Hanwha Solutions R&D Institute, Daejeon 34128, Korea 5KAIST Institute for the Nanocentury, KAIST, Daejeon 34141, Korea (Received 26 January 2023 • Revised 13 May 2023 • Accepted 24 May 2023)
jpark@kitech.re.kr, sqchoi@kaist.ac.kr
Korean Journal of Chemical Engineering, November 2023, 40(11), 2624-2631(8), 10.1007/s11814-023-1500-5
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Abstract
A novel method to remove the carbon residue precursor from waste plastic pyrolysis oil has been developed to improve subsequent pyrolysis oil refining efficiency by reducing fouling. The carbon residue content of thepyrolysis oil that cannot be filtered is reduced by precipitating the carbon residue precursor from the pyrolysis oil undermild conditions. By emulsifying an aqueous solution of oxidant and the pyrolysis oil, the carbon residue precursor wasoxidized at the oil-water interface without oxidizing the pyrolysis oil. Enhancing intermolecular interaction by hydrophilic functional groups formed by oxidation induces the precipitation of carbon residue precursors. The precursorremoval was determined by the type and reaction time of oxidants. FeCl3 and H2O2 are efficient oxidants, and recycling those oxidant solutions can also remove the carbon residue precursor. The number of recycles with the precursorremoval effect was determined by the amount of oxidant remaining in the aqueous solution. Also, a short 15-minuteFeCl3 reaction can eliminate the precursor. Reducing the reaction time is expected to increase process efficiency, asunnecessary oxidation and energy consumption are decreased. Our research suggests the pretreatment of the pyrolysisoil to reduce the carbon residue content, thereby reducing the fouling during the subsequent pyrolysis oil refining.
Keywords
References
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35. R. E. Parker and N. S. Isaacs, Chem. Rev., 59, 737 (1959).
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42. G. S. Brown, L. L. Barton and B. M. Thomson, Waste Manage., 23,737 (2003).
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47. T. M. Florence, J. Inorg. Biochem., 22, 221 (1984).
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