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- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received December 20, 2022
Revised March 16, 2023
Accepted April 7, 2023
- Acknowledgements
- This work was supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea government (MOTIE) (20210310100020, Production of advanced biofuel from lignocellulosic biomass by a combination of fast pyrolysis and supercritical ethanol upgrading).
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Comparative study of enhanced catalytic properties of clay-derived SiO2 catalysts for biodiesel production from waste chicken fat
Iqra Riaz1
Obaid Ali Qamar1
Farrukh Jamil1†
Murid Hussain1†
Abrar Inayat2 3
Lisandra Rocha-Meneses2
Parveen Akhte4
Sara Musaddiq5
Muhammad Ramzan Abdul Karim6
YoungKwon Park7†
1Department of Chemical Engineering, COMSATS University Islamabad, Lahore Campus, Defence Road, Off Raiwind Road, Lahore 54000, Pakistan 2Biomass & Bioenergy Research Group, Center for Sustainable Energy and Power Systems Research, Research Institute of Sciences and Engineering, University of Sharjah, 27272 Sharjah, United Arab Emirates 3Department of Sustainable and Renewable Energy Engineering, University of Sharjah, 27272 Sharjah, United Arab Emirates 4Department of Chemistry, The University of Lahore, 1-km Defence Road, Off Raiwind Road, Lahore, Pakistan 5Department of Chemistry, The Women University Multan, Kutchery Campus, Multan 66000, Pakistan 6Faculty of Materials and Chemical Engineering, Ghulam Ishaq Khan Institute of Engineering Sciences and Technology, Topi, 23640, Pakistan 7School of Environmental Engineering, University of Seoul, Seoul 02504, Korea
fjamil@cuilahore.edu.pk, drmhussain@cuilahore.edu.pk, ykpark0426@gmail.com
Korean Journal of Chemical Engineering, November 2023, 40(11), 2683-2691(9), 10.1007/s11814-023-1467-2
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Abstract
The use of biodiesel is a proactive measure that can be implemented to reduce emissions of greenhouse
gases and other adverse environmental impacts. However, one of the major setbacks to biodiesel production is its relatively higher cost compared to petroleum diesel. The optimistic solution to this is valorization of biomasses like waste
chicken fat (WCF) and clay for deriving non-edible oil and catalyst respectively. Herein, we report the synthesis of clay
derived SiO2 catalyst impregnated with SrO, Bi2O3, CuO and CaO. The developed catalysts were characterized by FTIR,
XRD, and SEM. XRD studies confirmed the successful impregnation of active metallic oxide on SiO2 support. Further,
these catalysts were employed for biodiesel production from WCF, and SrO/SiO2 was found to be most effective and
efficient catalyst for biodiesel production from WCF. Hence, SrO/SiO2 was adapted to optimize the different transesterification reaction parameters such as methanol to oil ratio, catalyst loading, reaction temperature and time. The optimized conditions for maximum biodiesel yield 98.9% were found to be 65 o
C in 1 h with 12 : 1 methanol to oil ratio
and 1 wt% catalyst loading. The biodiesel produced was also analyzed by GC-MS. The obtained biodiesel yield shows
that clay can be a potential, and cost-effective, catalyst source to produce biodiesel from WCF
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50. F. Esmi, A. K. Dalai and Y. Hu, J. Clean. Prod., 136499 (2023).
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54. S. Musić, N. Filipović-Vinceković and L. Sekovanić, Brazilian J. Chem. Eng., 28, 89 (2011).
55. C. T. Ivan-Tan, A. Islam, R. Yunus and Y. H. Taufiq-Yap, J. Clean.Prod., 148, 441 (2017).
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58. H. R. Mahmoud, Fuel, 256, 115979 (2019).
59. F. Shahbazi, V. Mahdavi and J. Zolgharnein, J. Iran. Chem. Soc., 17, 333 (2020).
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