Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received November 22, 2022
Revised February 11, 2023
Accepted February 27, 2023
- Acknowledgements
- This research was financially supported by Environmental and Occupational Hazards Control Research Center, Shahid Beheshti University of Medical Sciences, under grant No. 22038
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Enhanced degradation of 2,4-dichlorphenoxyacetic acid herbicide by CaO2 activated by Fe(II) and ultrasound irradiation: Practical insight and mineralization
Abstract
CaO2 was activated by Fe(II) and ultrasound (US) irradiation to degrade 2,4-dichlorphenoxyacetic acid (2,4-
D) for the first time. Among transition metals (Fe, Cu, Mn and Co), Fe(II) had the best performance for the activation of
CaO2. The impact of pH, CaO2 and Fe(II) concentration was studied, and under optimal situation ~91% of 2,4-D was
degraded during 60 min reaction time. The quenching experiments showed that the hydroxyl radical was the main factor for the destruction of 2,4-D while superoxide anions had a minor role. The bicarbonate ions and acid humic exhibited a strong inhibitory effect on the performance of CaO2/US/Fe(II) process. Carbon and chlorine mineralization of 2,4-
D degradation was investigated; around 41% of C and 35% of Cl were mineralized during 60 min reaction time. The
function of CaO2/US/Fe(II) process was studied on real drainage and other organic pollutants, and the results showed
that the CaO2/US/Fe(II) process can be practical for water treatment. Finally, intermediates of 2,4-D degradation were
identified, a pathway was proposed, and the toxicity of intermediates was assessed by ECOSAR software.
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