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Received June 3, 2022
Revised September 14, 2022
Accepted January 31, 2023
- Acknowledgements
- The authors are grateful for the funding granted from the Ministry of Science and Technology, and technical support from the National Center for High-Performance Computing, Taiwan. The authors gratefully acknowledge the use of SQUID000200 of MOST111-2731-M-006-001 belonging to the Core Facility Center of National Cheng Kung University
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Catalytic hydrogenation of disinfection by-product bromate by cobalt and nickle prussian blue analogues with borohydride
Po-Hsin Mao1
Young-Kwon Park2
Yi-Feng Lin3†
Bui Xuan Thanh4
Duong Dinh Tuan5
Afshin Ebrahimi6
Grzegorz Lisak7 8
Thanit Tangcharoen9
Kun-Yi Andrew Lin1†
1Department of Environmental Engineering & Innovation and Development Center of Sustainable Agriculture, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung, Taiwan 2School of Environmental Engineering, University of Seoul, Seoul 02504, Korea 3Department of Chemical Engineering and R&D Center for Membrane Technology, Chung Yuan Christian University, 200 Chung Pei Rd., Chungli, Taoyuan, Taiwan 4Faculty of Environment and Natural Resources, Ho Chi Minh City University of Technology, VNU-HCM, 268 Ly Thuong Kiet, District 10, Ho Chi Minh City, 700000, Viet Nam 5International School, Thai Nguyen University, Thai Nguyen city, 250000, Viet Nam 6Environment Research Center and Department of Environmental Health Engineering Isfahan University of Medical Sciences Isfahan, Iran 7Residues and Resource Reclamation Centre, Nanyang Environment and Water Research Institute, Nanyang Technological University, Singapore 637141, Singapore 8School of Civil and Environmental Engineering, Nanyang Technological University, Singapore 639798, Singapore 9Department of Basic Science and Physical Education, Faculty of Science at Sriracha, Kasetsart University, Sriracha Campus, Chonburi, Thailand
yflin@cycu.edu.tw, linky@nchu.edu.tw
Korean Journal of Chemical Engineering, December 2023, 40(12), 2876-2885(10), 10.1007/s11814-023-1445-8
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Abstract
As disinfection is employed extensively, disinfection by-product bromate has become an emerging environmental issue due to its carcinogenic toxicity. For developing an effective alternative approach for reducing bromate,
cobalt and nickel-based Prussian Blue (PB) analogues are proposed here for incorporating a convenient reducing agent,
NaBH4 (i.e., a H2-rich reagent) for reducing bromate to bromide as cobalt and nickel are recognized as effective metals
for catalyzing hydrolysis of NaBH4, and PB exhibits versatile catalytic activity. While CoPB and NiPB are comprised of
the same crystalline structure, CoPB exhibits slightly higher specific surface area, more reductive surface, and more
superior electron transfer than NiPB, enabling CoPB to accelerate bromate reduction. CoPB also exhibits a higher
affinity towards NaBH4 than NiPB based on density functional theory calculations. Moreover, CoPB also exhibits a relatively low activation energy (i.e., 59.5 kJ/mol) of bromate reduction than NiPB (i.e., 63.2 kJ/mol). Furthermore, bromate reduction by CoPB and NiPB could be also considerably enhanced under acidic conditions, and CoPB and NiPB
could still effectively remove bromate even in the presence of nitrate, sulfate and phosphate. CoPB and NiPB are also
validated to be recyclable for reducing bromate, indicating that CoPB and NiPB are promising heterogeneous catalysts
for reducing bromate.
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53. K. Y. A. Lin, J. Y. Lin and H. L. Lien, Chemosphere, 172, 325 (2017).
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65. A.W.W.A.W.E.F. American Public Health Association, Standard Methods for the Examination of Water and Wastewater 22 nd ed., Method 4500-CN- A,B,C,D and E, in, Washington, DC, USA, 4 (2012).
