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- In relation to this article, we declare that there is no conflict of interest.
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Received September 25, 2021
Revised November 7, 2021
Accepted November 11, 2021
- Acknowledgements
- The study was supported by The Youth Incubator for Science and Technology Program, managed by Youth Development Science and Technology Center-Ho Chi Minh Communist Youth Union and Department of Science and Technology of Ho Chi Minh City, the contract number is “37/2020/HĐ-KHCNT-VƯ” (30/12/ 2020).
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Nano-sized hematite-assembled carbon spheres for effectively adsorbing paracetamol in water: Important role of iron
1Institute of Fundamental and Applied Sciences, Duy Tan University, Ho Chi Minh City, 700000, Vietnam 2Faculty of Environmental and Chemical Engineering, Duy Tan University, Da Nang, 550000, Vietnam 3Faculty of Chemical & Food Technology, Ho Chi Minh City University of Technology and Education, Thu Duc, Ho Chi Minh City, 700000, Vietnam
trannguyenhai@duytan.edu.vn, trannguyenhai2512@gmail.com
Korean Journal of Chemical Engineering, December 2023, 40(12), 3029-3038(10), 10.1007/s11814-021-1013-z
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Abstract
This study developed a new -Fe2O3 (hematite) nanoparticles-loaded spherical biochar (H-SB) through the
direct pyrolysis of glucose-derived spherical hydrochar and FeCl3. The optimal impregnation ratio (hydrochar and
FeCl3) was 1/1.25 (wt/wt). H-SB was applied to remove paracetamol (PRC) from water. Results indicated that H-SB
exhibited a relatively low surface area (127 m2
/g) and total pore volume (0.089 cm3
/g). The presence of iron particles in
its surface was confirmed by scanning electron microscopy with energy dispersive spectroscopy. The dominant form of
iron nanoparticles (-Fe2O3) in its surface was confirmed by X-ray powder diffraction and Raman spectrum. The crystallite size of -Fe2O3 in H-SB was 27.4 nm. The saturation magnetization of H-SB was 6.729 emu/g. The analysis of
Fourier-transform infrared spectroscopy demonstrated that the C-O and O-H groups were mainly responsible for loading -Fe2O3 nanoparticles in its surface. The adsorption study indicated the amount of PRC adsorbed by H-SB slightly
decreased within solution pH from 2 to 11. The adsorption reached a fast saturation after 120 min. The Langmuir
maximum adsorption capacity of H-SB was 49.9 mg/g at 25 o
C and pH 7.0. Ion-dipole interaction and - interaction
played an important role in adsorption mechanisms, while hydrogen bonding and pore filling were minor. Therefore,
H-SB can serve as a promising material for treating PRC-contaminated water streams.
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