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- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received May 12, 2022
Revised July 7, 2022
Accepted July 13, 2022
- Acknowledgements
- The authors gratefully acknowledge the financial support of the Shahid Bahonar University of Kerman.
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Methylene blue adsorption by wheat straw-based adsorbents: Study of adsorption kinetics and isotherms
1Department of Chemistry, Shahid Bahonar University of Kerman, Kerman, Iran 2Young Research Society, Shahid Bahonar University of Kerman, Kerman, Iran
kalantari@uk.ac.ir
Korean Journal of Chemical Engineering, April 2023, 40(4), 873-881(9), 10.1007/s11814-022-1230-0
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Abstract
Dyes are one of the major toxic pollutants discharged in large quantities into the hydrosphere. Among various dye removal methods, adsorption has a distinct position. In this study, wheat straw was used as a low-cost and
renewable material to prepare two economical adsorbents through the facile production method. An adsorbent was
prepared by alkaline hydrolysis of wheat straw. Then, another adsorbent was synthesized by carboxymethylation of the
first adsorbent. The prepared adsorbents were characterized by various techniques, including Fourier transform infrared spectroscopy (FT-IR), field-emission scanning electron microscopy (FESEM), and X-ray diffraction (XRD). A series
of adsorption experiments were conducted in a batch adsorption system to study the effect of diverse parameters, such
as solution pH, the initial dye concentration, and contact time, on the adsorption performance. Adsorption models and
kinetic results indicated that the adsorption of methylene blue onto both adsorbents was more fitted to Langmuir isotherm and followed second-order kinetics. The maximum monolayer adsorption capacity of methylene blue on alkalinemodified wheat straw and carboxymethylated modified wheat straw reached 131.123 and 191.427 mg/g, respectively.
Regarding their low cost and suitable adsorption potential, they can be cost-effective and promising adsorbents for
wastewater treatment.
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50. A. H. Jawad, N. S. A. Mubarak and A. S. Abdulhameed, J. Polym.Environ., 28, 624 (2020).
51. M. Song, Z. Duan, R. Qin, X. Xu, S. Liu, S. Song, M. Zhang, Y. Li and J. Shi, Korean J. Chem. Eng., 36, 869 (2019).
52. H. Bai, J. Chen, X. Zhou and C. Hu, Korean J. Chem. Eng., 37, 1926(2020).
53. S. Rangabhashiyam, S. Lata and P. Balasubramanian, Surf. Interfaces,10, 197 (2018).
54. T.S. Chandra, S.N. Mudliar, S. Vidyashankar, S. Mukherji, R. Sarada,K. Krishnamurthi and V. S. Chauhan, Bioresour. Technol., 184, 395(2015).
55. A. A. Babaei, A. Khataee, E. Ahmadpour, M. Sheydaei, B. Kakavandi and Z. Alaee, Korean J. Chem. Eng., 33, 1352 (2016).
56. R. K. Ghosh, D. P. Ray, A. Tewari and I. Das, Int. J. Environ. Sci.Technol., 18, 2747 (2021).
57. R. Gong, Y. Liu, Y. Jiang and C. Li, African J. Biotechnol., 8, 7138(2009).
58. G. Li, W. Zhu, C. Zhang, S. Zhang, L. Liu, L. Zhu and W. Zhao,Bioresour. Technol., 206, 16 (2016).
59. A. Subratti, J. L. Vidal, L. J. Lalgee, F. M. Kerton and N. K. Jalsa,Sustain. Chem. Pharm., 21, 100421 (2021).
