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- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received May 12, 2022
Revised July 22, 2022
Accepted August 2, 2022
- Acknowledgements
- This research was financially supported by Environmental and Occupational Hazards Control Research Center, Shahid Beheshti University of Medical Sciences, under grant No. 22039
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Periodate activation by concurrent utilization of UV and US for the degradation of para-nitrophenol in water: A synergistic approach
Akbar Eslami1 2†
Fayyaz Mehdipour2
Rouzan Feizi3
Farshid Ghanbari4
Kun-Yi Andrew Lin5†
Amin Bagheri2
Soheila Madihi-Bidgoli4†
1Environmental and Occupational Hazards Control Research Center, Shahid Beheshti University of Medical Sciences, Tehran, Iran 2Department of Environmental Health Engineering, School of Public Health and Safety, Shahid Beheshti University of Medical Sciences, Tehran, Iran 3Behbahan Faculty of Medical Sciences, Behbahan, Iran 4Research Center for Environmental Contaminants (RCEC), Abadan University of Medical Sciences, Abadan, Iran 5Department of Environmental Engineering & Innovation and Development Center of Sustainable Agriculture & Research Center of Sustainable Energy and Nanotechnology, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung, Taiwan
akbar_eslami@yahoo.com, linky@nchu.edu.tw, S.madihibidgoli@abadanums.ac.ir
Korean Journal of Chemical Engineering, April 2023, 40(4), 882-891(10), 10.1007/s11814-022-1247-4
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Abstract
Para-nitrophenol (PNP) is a toxic compound widely used in various industries. The release of PNP into the
environment not only threatens human health but the ecosystem. Hence, the treatment of contaminated water is necessary. Periodate (PI) is a new oxidant which is used for the generation of free radicals. In the current work, PI was concurrently activated by ultraviolet (UV) and ultrasound (US) to eliminate PNP from aqueous solution. The effects of
operating parameters were studied and complete degradation of PNP was obtained in 30 min. The presence of ferrous
ions increased the PNP degradation rate. Scavenging experiments confirmed that HO•
and IO3
•
were corresponding
agents of the PNP degradation, which the latter had a bold role. The performance of PI/UV/US was examined on real
wastewater and the results showed that 70% of total phenol was removed during 60 min. The PNP degradation intermediate was recognized and a pathway of PNP degradation was proposed. Although PI/UV/US process is high energy
consuming, its excellent performance can be a rational reason for the scaling up the process.
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