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- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received May 18, 2022
Revised November 8, 2022
Accepted November 13, 2022
- Acknowledgements
- The Korea National Research Foundation grant funded by the Korean government endorsed this work (No. 2018R1A6A1A030 24509 and 2021R1I1A1A0105510212). D.G.C. acknowledges the KAIX program (KAIST), Professors Hee-Seung Lee and YoungMin Rhee (Dept. of Chem., KAIST) for financial assistance during the fiscal years of 2020 and 2021, and International Joint Usage Project with ICR, Kyoto University (2019-115 and 2020-124).
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Microstructural and thermal investigation of the bioinspired and synthetic fire-retardant materials deposited on cotton using LBL process
1College of Mechatronic Engineering, Changwon National University, Changwon, Gyeongsangnam-do 51140, Korea 2National Engineering Technology Research Center of Flame-Retardant Materials, School of Materials Science & Engineering, Beijing Institute of Technology, Beijing, 100081, P. R. China 3Department of Chemistry, Molecular Logic Gate Laboratory, Korea Advanced Institute of Science and Technology (KAIST), Deajon 34141, Korea
bhkoo@changwon.ac.kr
Korean Journal of Chemical Engineering, April 2023, 40(4), 943-951(9), 10.1007/s11814-022-1346-2
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Abstract
A detailed comparison of the bio- and synthetic polymers based layer by layer (LBL) coatings on a singular cotton fabric substrate was carried out. The growth of the deposited layers and subsequent properties, that could
govern the fire protection of the substrate, were studied using low voltage-scanning electron microscope (LV-SEM) and
thermal analysis techniques. From the 2D and 3D microstructural evaluation, uniform layered structure, agglomerated/
precipitated structures and inter-fibers connecting layered-structure were explored, more thoroughly for chitosan and
alginate based (CHI-2, ALG-2) biopolymer coatings, whereas the microstructure of synthetic polymers-based coatings
ammonium polyphosphate and Polyvinyl Alcohol (APP-2 and PVA-2) showed only uniform layers. From the microthermal evaluation (TGA and MCC), a two-step degradation was recorded for all samples with a higher char residue
recorded for APP-2 (TGA, ~39.2%, at 600 o
C, MCC ~33.0% at 800 o
C) followed by CHI-2 (TGA, ~12.5% at 600 o
C,
MCC, ~8.92% at 800 o
C) suggesting superiority of the APP-2 based deposition over that of CHI-2. In addition, the
same pattern of dominance was found consistent with the peak heat release rate (PHRR) values and total heat release
(THR) values for APP~ (85.1 W/g, 6.53 KJ/g), and CHI-2~ (227.74 W/g, 17.17 KJ/g), respectively. However, from the
VFT analysis, both samples were found to have comparable properties, in terms of structural integrations, char residue, and flame resistance.
Keywords
References
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